BN纤维对石墨烯微片/聚丙烯复合材料导热绝缘性能的影响

Effect of BN fiber on thermal conductivity and insulation properties of graphene nanoplatelets/polypropylene composites

  • 摘要: 采用熔融共混法制备BN纤维-石墨烯微片/聚丙烯(BN纤维-GNP/PP)高导热绝缘复合材料,结合有限元模拟、SEM、XRD、导热导电测试结果,探究了BN纤维含量和长度对BN纤维-GNP/PP复合材料导热绝缘性能的影响。结果表明:BN纤维-GNP/PP复合材料中BN纤维含量和长度的增加可增大GNP分布范围,增大BN纤维与GNP的接触概率;在GNP含量为7wt%、100 μm BN纤维含量为20wt%时BN纤维-GNP/PP复合材料的热导率较PP提高了4.2倍,同时电绝缘性略有提高。模拟结果表明,高含量100 μm BN纤维的加入使BN纤维-GNP/PP复合材料导热网络的构建趋于完整,局部热通量较低的区域减少。片状GNP与纤维状BN二相填料的"协同效应",使GNP和BN纤维分别作为"岛"和"桥"形成了一种特殊的"双网络"结构,BN纤维作为高导热"桥"阻隔了相邻GNP间导电通路的形成,从而提高了BN纤维-GNP/PP复合材料的导热绝缘性能。

     

    Abstract: The BN fiber-graphene nanoplatelets/polypropylene (BN fiber-GNP/PP) high thermal conductivity electrical insulation composite was prepared by melt blending. The effects of BN fiber content and length on the thermal insulation properties of BN fiber-GNP/PP composites were investigated by finite element simulation, SEM, XRD and thermal conductivity test results. The results show that the increase of BN fiber content and length in BN fiber-GNP/PP composites can increase the range of GNP distribution and the contact probability of BN fiber with GNP. At 7wt% GNP content, the addition of 100 μm BN fiber at 20wt% makes the thermal conductivity of BN fiber-GNP/PP composites 4.2 times higher than PP, while the electrical insulation is slightly improved. The simulation results show that the addition of high content of 100 μm BN fiber tends to complete the thermal network of BN fiber-GNP/PP composites and reduce the area of local heat flux. Under the influence of the "synergistic effect" of flake GNP and fibrous BN two-phase filler, GNP and BN fibers form a special "dual network" structure as "islands" and "bridges", respectively. The BN fiber acts as a high thermal conductivity "bridge" to block the formation of conductive pathways between adjacent GNP. The thermal insulation properties of the BN fiber-GNP/PP composite are improved.

     

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