TiO2/废弃涤纶无纺布的制备及光催化自清洁性能

Preparation and photocatalytic self-cleaning properties of TiO2/recycled polyethylene terephthalate nonwoven fabric

  • 摘要: 以废弃涤纶(PET)无纺布为研究对象,清洗干净后对其进行碱刻蚀,并接枝钛酸四丁酯(TBT)水解形成TiO2/PET无纺布。利用SEM对其形貌进行观察发现,当TBT含量为6wt%时纤维表面形成较均匀的TiO2粒子。研究了碱刻蚀温度及TBT浓度对PET及TiO2/PET无纺布断裂强度的影响。结果表明,随着碱刻蚀温度的升高,PET无纺布碱减量增大,力学性能变差,而TiO2的形成一定程度上提高了PET无纺布的断裂强度,使60℃和80℃碱刻蚀后的TiO2/PET断裂强度相当;随TBT含量增多,TiO2/PET无纺布的断裂强度呈先增大后减小的趋势,且最大强度所对应的TBT浓度随着温度的升高逐渐增大。为研究TiO2/PET无纺布的光催化自清洁性能,以甲基橙溶液作降解物,在30 W紫外灯下对TiO2/PET无纺布处理一定时间后利用测色仪测其表观色深。结果表明,80℃碱刻蚀后接枝6wt% TBT的TiO2/PET无纺布光降解性能最好,5 h后光降解率可达89.05%,经5次循环测试后,TiO2/PET无纺布的光降解率仅下降1.43%,说明其负载牢度较好。这主要得益于该碱刻蚀温度及TBT含量制得的TiO2/PET无纺布的纤维具有较高比表面积且形成较为均匀的TiO2粒子。

     

    Abstract: The TiO2/polyethylene terephthalate (PET) nonwoven was prepared by TiO2-loaded on the recycled PET nonwoven fabric. The PET nonwoven fabric was firstly treated by alkali etching and the TiO2 was obtained by hydrolysis reaction of tetrabutyl titanate (TBT). The uniform TiO2 particles can be observed through SEM when the TBT content is 6wt%. The influence of the alkali etching temperature and TBT content on the mechanical property of PET and TiO2/PET nonwoven fabric was investigated. The results show that the alkali reduction increases and the tenacity of PET nonwoven fabric gradually decreases with the increasing of alkali etching temperature. The tenacity of the nonwoven fabric by etching at 60℃ and 80℃ is comparable at the same TBT content, because the formation of the loaded TiO2 improves the mechanical properties of the TiO2/PET nonwoven fabric. The tenacity of TiO2/PET nonwoven fabric increases firstly and then decreases with TBT content increasing. The TBT content that corresponding to the maximum tenacity increases with the increase of temperature. In order to character the photocatalytic self-cleaning properties of TiO2/PET nonwoven fabric, methyl orange solution was used as a degradation substance, TiO2/PET nonwoven fabric was treated under ultraviolet light with 30 W, and the apparent depth of color was tested using a colorimeter. The results show that the photo degradation performance is the best when the alkali etching temperature is 80℃ and TBT content is 6wt%, the degradation of methyl orange solution is 89.05% and this ratio just decreases 1.43% after five cycles. The results are all attribute to the higher special surface area and the formation of uniform TiO2 on the PET fiber surface at 80℃ and 6wt% TBT.

     

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