稀土改性对玄武岩纤维增强氰酸酯树脂复合材料性能的影响

Effect of rare earth modified basalt fiber on properties of basalt fiber reinforced cyanate resin composites

  • 摘要: 采用自制稀土改性剂改性玄武岩纤维(La-BF)布增强双酚A型二氰酸酯(BADCy)制备了La-BF/BADCy复合材料。采用SEM和FTIR分析了改性对BF表面产生的影响,TG分析研究了改性对BF/BADCy复合材料热稳定性的影响,使用电子万能试验机研究改性对不同质量分数的BF/BADCy弯曲性能的影响,通过阻抗分析仪分析了改性对La-BF/BADCy复合材料介电性能的影响。结果表明,改性减少了BF的表面缺陷,并引入了结晶状凸起,有利于提高BF/BADCy复合材料的界面性能;通过改性提高了BF/BADCy复合材料的热稳定性,初始分解温度提高了145℃;当BF的质量分数为12wt%时,改性使BF/BADCy复合材料弯曲模量提高到4.19 GPa,弯曲强度达到110 MPa以上。在1 MHz~3 GHz范围内,La-BF/BADCy复合材料的介电常数稳定在1.9左右。因此稀土改性是一种能够有效提高BF/BADCy复合材料弯曲性能、热稳定性及介电性能的表面改性方法。

     

    Abstract: The basalt fiber fabrics modified with self-made rare earth modifiers (La-BF) enhance the bisphenol-A dicyanate (BADCy). The influence of the modification on basalt fiber (BF) surface was analyzed by SEM and FTIR. The effect of the modification on the thermal stability of BF/BADCy composite was investigated by TG analysis. The modification of the BF/BADCy composites with different mass fractions were analyzed using an electronic universal testing machine. Influence of the flexural properties of the material, the influence of the modification on the dielectric properties of the BF/BADCy composites were analyzed by an impedance analyzer. The results show that the modification reduces the surface defects of the BF and introduces crystalline bulges, which is beneficial to improve the interface properties of the BF/BADCy composite. The modification increases the thermal decomposition temperature of the BF/BADCy composite, and the initial decomposition temperature is increased by 145℃. When the mass fraction of BF is 12wt%, the flexural modulus of the La-BF/BADCy composite is improved to 4.19 GPa and the flexural strength is over 110 MPa. In 1 MHz-3 GHz range, the dielectric constant of the La-BF/BADCy composite is around 1.9. Therefore, the rare earth modification can effectively improve the flexural properties, thermal stability and dielectric properties of BF/BADCy composites.

     

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