纳米CaCO3对水泥-石灰石粉浆体流变作用

Rheological properties of cement-ground limestone paste with nano-CaCO3

  • 摘要: 试验采用Rheolab QC型旋转黏度计测试了掺纳米CaCO3的水泥-石灰石粉浆体的流变曲线,应用Herschel-Bulkley流变模型对其剪切应力-速度(τ-γ)曲线进行拟合,得到浆体的动态屈服应力、稠度系数和流变指数,并用触变环面积表征浆体的触变性。结果表明:随石灰石粉掺量的增加,水泥-石灰石粉浆体的动态屈服应力逐渐减小,稠度系数增大,触变性先增大后减小;纳米CaCO3未改变水泥-石灰石粉浆体的流变类型都呈现出剪切稀化行为;随纳米CaCO3掺量的增加,水泥-石灰石粉浆体动态屈服应力和稠度逐渐增大,触变性减小,纳米CaCO3使水泥-石灰石粉浆体流变性能变差,但使其稳定性增强。

     

    Abstract: The rheological curves of the cement-ground limestone paste were determined by Rheolab QC rotation viscometer. Dynamic yield stress, consistency coefficient and rheological index of the paste were obtained by fitting the measured τ-γ curves based on Herschel-Bulkley model and thixotropy was characterized by the area of thixotropic hysteresis loop. The results indicate that:with the increase of ground limestone content, dynamic yield stress decreases gradually, consistency coefficient increases, while thixotropy increases and then decreases. The addition of nano-CaCO3 has little effect on the rheological type of the cement-ground limestone paste and they both present a shear thinning behavior. With the increase of nano-CaCO3 content, dynamic yield stress and consistency coefficient increase gradually, while thixotropy decreases. The addition of nano-CaCO3 results in a poor rheological properties of the cement-ground limestone pastes but enhances its stability.

     

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