氧化钒-氧化石墨烯复合薄膜的制备及其光电特性

Preparation and optoelectronic properties of vanadium oxide-graphene oxide composite films

  • 摘要: 基于溶胶凝胶法,采用旋涂和喷涂相结合的工艺,制备了氧化钒(VOx,1≤x≤2.5)-氧化石墨烯(GO)复合薄膜。利用SEM、XRD、椭偏仪、紫外可见分光光度计、FTIR及高阻仪对所制薄膜的形貌、晶相、光学及电学性能进行了系统的表征测试。结果表明,加入GO之后,VOx-GO复合薄膜的电阻率由108.78 Ω·cm下降至68.64 Ω·cm,而薄膜的电阻温度系数(TCR)则由-1.98% K-1提高至-2.60% K-1。此外,VOx-GO复合薄膜还具有更高的光吸收率和工作稳定性。说明GO的加入增强了VOx薄膜作为非制冷红外探测器热敏材料的综合性能。本研究为探索基于VOx的新型红外热敏材料提供了参考,同时也对非制冷红外探测器的发展有促进作用。

     

    Abstract: Vanadium oxide (VOx, 1 ≤ x ≤ 2.5)-graphene oxide (GO) composite films were prepared by the combination of spin-coating of VOx sol-gel and spray-coating of GO dispersion.The physical morphologies, crystallinities, optical and electrical properties of the as-prepared films were systematically characterized by SEM, XRD, ellipsometry, UV-visible spectrometer, FTIR and high resistance meter. The results indicate that the resistivity of the composite film decreases from 108.78 Ω·cm for the pristine VOx film to 68.64 Ω·cm after GO addition, while the temperature coefficient of resistance(TCR) increases from -1.98%K-1 to -2.60%K-1. In addition, VOx-GO composite film exhibits a higher light absorption. These suggest that the GO addition can significantly improve the performance of VOx films as thermistor materials. The results present in this work not only provide valuable information for the exploration of novel VOx-based infrared thermistor materials, but also promote the development of uncooled infrared detectors.

     

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