相变储湿纤维/石膏复合材料的制备及综合性能

Preparation and comprehensive performance of phase change and humidity storage fibers/gypsum composite

  • 摘要: 以抹灰石膏作为基体材料,将相变储湿纤维掺入抹灰石膏中,制备相变储湿纤维/石膏复合材料,对其基本性能、储湿调湿性能、相变调温性能和耐久性能进行测试与分析。利用FTIR和SEM研究相变储湿纤维/石膏复合材料的结构组成和微观形貌。结果表明:当相变储湿纤维掺量为40.0wt%时,相变储湿纤维/石膏复合材料具有最佳性能和良好耐久性能,其标准扩散度用水量为0.70、初凝时间为40 min、终凝时间为55 min、体积密度为1 005.56 kg·m-3、拉伸连接强度为0.10 MPa、抗压强度为2.55 MPa;在相对湿度40%~65%时的平衡含湿量为0.0395~0.0935 g·g-1;从35℃至20℃的降温时间为100 s,相变平台明显;经过循环试验,相变储湿纤维/石膏复合材料的吸放湿性能下降小于10%,相变调温性能下降小于5%。

     

    Abstract: With plastering gypsum as the matrix, phase change and humidity storage fibers were mixed with plastering gypsum to prepare phase change and humidity storage fibers/gypsum composite. Basic performance, humidity storage humidity controlling performance, phase change temperature controlling performance and durability performance of phase change and humidity storage fibers/gypsum composite were tested and analyzed. Structural composition and microstructure of phase change and humidity storage fibers/gypsum composite were analyzed by FTIR and SEM. The results show that phase change and humidity storage fibers with mass content of 40.0wt% can provide the best performance and good durability performance of phase change and humidity storage fibers/gypsum composite. The standard diffusion degree of water consumption is 0.70, initial setting time is 40 min, final setting time is 55 min, bulk density is 1 005.56 kg/m3, tensile connection strength is 0.10 MPa and compressive strength is 2.55 MPa. Equilibrium moisture content is 0.0395-0.0935 g·g-1 in relative humidity 40%-65%. Cooling time is 100 s form 35℃ to 20℃ with clear phase change platform. After the cycling test, the moisture absorption performance decline of phase change and humidity storage fibers/gypsum composite is less than 10%, phase change and temperature controlling performance decline is less than 5%.

     

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