不同剂量γ辐照对玻璃纤维/环氧树脂热性能的影响

Effects of different γ irradiation dosages on thermal properties of glass fiber/epoxy resin composite

  • 摘要: 玻璃纤维增强树脂(GF/EP)因其良好的热绝缘性能和优异的力学性能,在高能物理和核物理实验领域作为支撑材料得到应用。高能物理和核物理实验会对支撑材料产生大量的γ和中子辐射,同时要求其保持热性能的稳定。本文对20 kGy、100 kGy和200 kGy剂量的γ辐照下GF/EP的各项热学性能进行测试研究,包括热膨胀性能、导热性和热降解性能,并对辐照前后GF/EP的微观形貌进行观察。结果发现,辐照后,GF/EP的微观形貌发生变化,基体树脂产生碎片化,辐照后线膨胀范围缩小,线膨胀系数略有降低;导热系数降低,降低幅度随辐照剂量的增大而减小;热分解温度基本保持不变,最快热分解温度略有降低,γ辐照过程中同时发生辐照交联和辐照降解反应,但总体热学性能保持稳定,在使用温度范围内保持良好的稳定性。

     

    Abstract: Glass fiber reinforced epoxy resin(GF/EP) is used as support material for high energy physics and nuclear physics experiments due to its excellent thermal insulation and mechanical performance. High-energy physics and nuclear physics experiments produce large amounts of γ and neutron irradiation to the support material, while requiring GF/EP maintaining thermal stability as the support material. In this paper, the thermal properties including thermal expansion, thermal conductivity and thermal degradation of GF/EP under the γ irradiation of 20 kGy, 100 kGy and 200 kGy dosages were studied. The microstructure of GF/EP was observed before and after irradiation. The obtained results show that after irradiation, the microstructure of GF/EP changes, the matrix resin is fragmented, and the linear expansion range is narrowed with coefficient decreasing slightly. The thermal conductivity declines and the downward rate decreases with the increase of irradiation dosage, the thermal decomposition temperature is kept constant with the fastest thermal decomposition temperature droping slightly, the irradiation cross-linking and the irradiation degradation reaction occur simultaneously during the γ irradiation process, the overall thermal performance is stable with good stability within operating temperature range.

     

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