跨尺度模拟硬化水泥净浆力学性能:微观物相的影响

Modeling the mechanical properties of cement paste: Effect of different phases

  • 摘要: 采用纳米压痕实验测量硬化水泥净浆中未水化物、水化产物和孔隙等微观物相的力学性能,并基于背散射电镜(BSE)图像的灰度分析计算各微观物相的含量。在得到各微观物相含量和力学性能的基础上,针对水泥净浆的弹性模量进行均一化建模,并讨论各微观物相及其模量的选取对跨尺度模拟硬化水泥净浆力学性能的影响。通过微米压痕的实测净浆模量验证模型及参数选取的可靠性。提出在硬化水泥净浆力学性能的多尺度模型中,需要选取12 GPa作为孔隙有效模量,并将水化产物划分为低密度的水化硅酸钙凝胶(LD-CSH)和高密度的水化硅酸钙凝胶(HD-CSH)两种物相,而不同种类的未水化物可被视作一种物相。在此基础上,使用Mori-Tanaka模型或自洽模型计算得到的净浆模量与实测净浆模量吻合。

     

    Abstract: The mechanical properties and the fractions of individual phases at microscale were measured by nanoindentation and back scattered electron (BSE) image analysis, and they can be used as the input in modeling the mechanical properties of cement paste. The mechanical properties of cement paste were measured by microindentation. The effect of individual phases on the effective modulus of hardened cement paste was quantified by comparing the measured and homogenized paste modulus. It is found that the effective modulus of pore needs to be set to 12 GPa as input for homogenization. Meanwhile, the high density hydrated calcium silicate gel (HD-CSH) and the low density hydrated calcium silicate gel (LD-CSH) need to be viewed as two different phases in modeling. Whereas, different clinkers can be regarded a single phase. The effective paste moduli calculated by both Mori-Tanaka scheme and self-consistent scheme agree well with the measured paste modulus.

     

/

返回文章
返回