原位合成TiB2/ZL205A复合材料的组织及流动性

Microstructure and fluidity of In-situ TiB2/ZL205A composites

  • 摘要: 采用原位合成法制备了TiB2/ZL205A复合材料,对所合成复合材料的物相、TiB2颗粒形貌及分布、流动性进行了研究。结果表明:TiB2/ZL205A复合材料主要由α-Al、Al2Cu和TiB2组成,TiB2颗粒呈多边形或卵圆形,平均颗粒尺寸500 nm左右,大部分沿晶界分布,少量分布在晶粒内部。TiB2/ZL205A复合材料的流动性与浇铸温度及TiB2质量分数的关系均可用指数阻尼模型进行描述。当浇铸温度由710℃提高到750℃时,7wt% TiB2/ZL205A复合材料的流动性提高了30.4%;当浇铸温度在750℃以上时,7wt% TiB2/ZL205A复合材料的流动性随浇铸温度的提高而提高的速率降低。与基体合金相比,在730℃浇铸时,3wt% TiB2/ZL205A复合材料的流动性降低了21.8%,7wt% TiB2/ZL205A复合材料的流动性降低了36.4%。

     

    Abstract: The in-situ TiB2/ZL205A composites were prepared by the method of mixed salt reaction in aluminum alloy melt. The phases, morphology and distribution of TiB2 particles and the fluidity of the fabricated composites were studied. The results show that the main phases of the TiB2/ZL205A composites are α-Al, Al2Cu and TiB2. The TiB2 particles with an average size of 500 nm and the shape of polygon or ovoid distribute mostly along the grains boundary and a few in the grains. The two relationships, that is the fluidity and casting temperature and the fluidity and mass fraction of Ti2B particles, can all be described by the exponential damping model. When the casting temperature raises from 710℃ to 750℃, the fluidity of 7wt%TiB2/ZL205A composites increases by 30.4%. When the casting temperature increases above 750℃, the increasing rate of the 7wt%TiB2/ZL205A composites fluidity is decreased with the increasing of casting temperature. Compared with the matrix alloy, the fluidity of 3wt%TiB2/ZL205A composites decreases by 21.8%, and the fluidity of 7wt%TiB2/ZL205A composites decreases by 36.4%.

     

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