SiCW含量对SiCW/Si3N4复合陶瓷力学及高温微波性能影响

Effect of SiCW content on mechanical and high temperature microwave properties of SiCW/Si3N4 composite ceramics

  • 摘要: 以α-Si3N4粉、β-SiCW为原料,Al2O3、Y2O3为烧结助剂,采用凝胶注模工艺制备了SiCW/Si3N4复合陶瓷材料,烧结温度为1 650℃,保温1.5 h。研究了SiCW加入含量对SiCW/Si3N4复合陶瓷的微观结构、力学及常温/高温微波吸收性能的影响。结果表明:随着SiCW含量的增加,SiCW/Si3N4复合陶瓷的抗弯强度和断裂韧性都有先増后减的趋势,当含量为10wt%时,抗弯强度达到最大值505 MPa,断裂韧性达9.515 MPa·m1/2。常温介电常数在SiCW含量为10wt%时,实部达最大值12,在12 GHz最大吸收值为-21 dB。高温介电常数随着SiCW含量的增加有先增后减的趋势,在含量为10wt%时,实部达到最大值12.5。相比于纯Si3N4陶瓷,当SiCW含量为10wt%时,SiCW/Si3N4复合陶瓷在11.7 GHz左右最大吸收可达-27 dB,有效吸收频带(小于-5 dB)为11.2~12.3 GHz。

     

    Abstract: The SiCW/Si3N4 composite ceramics were prepared by gel-casting using α-Si3N4 powder and β-SiCW as the raw materials and Al2O3 and Y2O3 as the sintering aids at 1 650℃ and kept 1.5 h. The effects of the content variation of SiCW on the microstructure, mechanical and room/high temperature microwave absorbing properties of the SiCW/Si3N4 composite ceramics were investigated. The results show that the flexural strength and fracture toughness of the SiCW/Si3N4 composite ceramics have a trend of decrease after an initial increase with increasing SiCW content. It possesses the most excellent flexural strength and fracture toughness (505 MPa and 9.515 MPa·m1/2) when the content is 10wt%. The real part of the dielectric constant at room temperature reaches the maximum 12 with the 10wt% SiCW. The maximum absorption is -21 dB at 12 GHz. And the high temperature permittivity has a trend of decrease after an initial increase with increasing SiCW content. The real permittivity reaches 12.5 when the content is 10wt%. Compared with the pure Si3N4 ceramic, when the SiCW content is 10wt%, the lowest reflectivity of the SiCW/Si3N4 composite ceramic reduces to -27 dB at around 11.7 GHz, and the effective absorption band (less than -5 dB) ranges from 11.2 to 12.3 GHz.

     

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