聚乙二醇改性相变微胶囊制备MicroPCMs-WF/HDPE复合材料物理力学性能

Physical and mechanical properties of WF/HDPE composites filled with microencapsulated phase change materials (MicroPCMs) modified by polyethylene glycol

  • 摘要: 以正十二烷醇(DA)为芯材,密胺树脂(MF)和聚乙二醇改性密胺(PMF)树脂为壁材制备了相变微胶囊(MicroPCMs),并分别添加到木粉/高密度聚乙烯(WF/HDPE)复合材料中,获得了具有相变蓄热能力的MicroPCMs-WF/HDPE复合材料。采用SEM、FTIR和纳米压痕等方法对MicroPCMs的表面形态、力学性能进行了分析与表征,同时对MicroPCMs-WF/HDPE复合材料的物理力学及热性能进行了测试。结果表明:经聚乙二醇改性后,改性微胶囊(PMF-MicroPCMs)的弹性模量和硬度较未改性微胶囊(MF-MicroPCMs)分别增加了13.9%和30.0%;MicroPCMs-WF/HDPE复合材料的熔融温度区间(22.2~28.7℃)满足人体舒适温度范围,较纯WF/HDPE复合材料温度变化速率明显减缓;相比纯WF/HDPE复合材料,MicroPCMs-WF/HDPE复合材料的吸湿性、冲击强度和表面硬度增加,弯曲和拉伸性能下降;PMF-MicroPCMs-WF/HDPE复合材料的性能均优于MF-MicroPCMs-WF/HDPE复合材料,且达到了木塑装饰板材的力学性能标准要求。

     

    Abstract: Dodecyl alcohol (DA) was coated with melamine-formaldehyde (MF) and polyethylene glycol modified melamine-formaldehyde (PMF) resin to prepare microencapsulated phase change materials (MicroPCMs). They were respectively added into wood flour/high-density polyethylene (WF/HDPE) composites to obtain MicroPCMs-WF/HDPE composites with thermal energy storage capacity. The surface morphology and mechanical properties of MicroPCMs were characterized by SEM, FTIR and nanoindentor etc. The physical and mechanical and thermal properties of MicroPCMs-WF/HDPE composites were investigated. The results show that the elastic modulus and hardness of modified microcapsules (PMF-MicropCMs) increase by 13.9% and 30.0% compared to unmodified microcapsules (MF-MicroPCMs) after polyethylene glycol modification, respectively. The melting temperature range (22.2-28.7℃) of MicroPCMs-WF/HDPE composites fits the human comfortable temperature range, and the temperature change speed is lower than pure WF/HDPE composites. The incorporation of MicroPCMs has a negative effect on flexural and tensile properties of WF/HDPE composites but favor the moisture absorption performance, impact strength and surface hardness; All properties of PMF-MicroPCMs-WF/HDPE composites are better than those of MF-MicroPCMs-WF/HDPE composites. All the mechanical properties meet the requirements for wood plastic decorative boards.

     

/

返回文章
返回