4种生物胶与麦秸秆制备复合材料性能比较

Comparison on properties of composites prepared by four kinds of biological glues and wheat straw

  • 摘要: 为比较生物胶(海藻酸钠、瓜尔胶、淀粉胶、植物蛋白胶)与麦秸秆制备麦秸秆/生物胶复合材料的力学性能和吸湿性能,分析了4种生物胶和麦秸秆的红外光谱,测试了麦秸秆/生物胶复合材料的力学性能和吸湿性能,观察了它们的微观结构。结果表明:4种生物胶均有-OH和-CH伸缩振动吸收峰,植物蛋白胶有-NH2伸缩振动吸收峰和-O-吸收峰。植物蛋白胶制备的复合材料力学性能较好,吸湿率较小,其拉伸强度比海藻酸钠、瓜尔胶、淀粉胶制备的复合材料分别高436%、93%、416%,弯曲强度分别高922%、49%、963%,弹性模量分别高714%、678%、254%,平衡吸湿率分别小42%、17%、16%。麦秸秆/植物蛋白胶和麦秸秆/瓜尔胶复合材料中麦秸秆被基体包裹较好,植物蛋白胶-麦秸秆和瓜尔胶-麦秸秆两相界面模糊,两者结合较好;而麦秸秆/海藻酸钠和麦秸秆/淀粉胶复合材料两相界面空穴和缺陷较多,麦秸秆与基体之间存在明显界面,与麦秸秆结合较差。麦秸秆/植物蛋白胶复合材料在力学性能方面与塑料基复合材料相当,而吸湿性能有待提高。

     

    Abstract: In order to compare mechanical properties and moisture absorption properties of wheat straw/biological glue composites prepared by the biological glues (sodium alginate, guar gum, starch gum, plant protein adhesive) and wheat straw, infrared spectra of four kinds of biological glues and wheat straw were analyzed, mechanical properties and moisture absorption properties of wheat straw/biological glue composites were tested, and their microstructure were observed. The results show that four kinds of biological glues have stretching vibration absorption peaks of -CH and -OH, plant protein adhesive has stretching vibration absorption peak of -NH2 and absorption peak of -O-. The mechanical properties of the composites prepared by plant protein adhesive are good, and moisture absorption rate is small. The tensile strength of composites prepared by plant protein glue is 436%, 93%, 416% higher than that of composites prepared by sodium alginate, guar gum and starch gum, the bending strength is 922%, 49%, 963% higher, the elastic modulus is 714%, 678%, 254% higher, and the absorption rate is 42%, 17%, 16% smaller, respectively. Wheat straw are wrapped preferably by matrix in wheat straw/plant protein adhesive and wheat straw/guar gum composites, and the two phase interface between plant protein adhesive-wheat straw and guar gum-wheat straw are fuzzy, which combine well. However, wheat straw/sodium alginate and wheat straw/starch gum composites have more holes and flaws in the two phase interface. The interface between wheat straw and matrix is obvious, the combination with wheat straw is worse. Wheat straw/plant protein adhesive composites are equivalent to the plastic-based composites in mechanical properties, but the moisture absorption property needs to be improved.

     

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