可全生物降解PLA/PBAT/PHBV共混材料的结构与性能

余洁, 韩建, 朱斐超, 苏娟娟, 欧璐

余洁, 韩建, 朱斐超, 等. 可全生物降解PLA/PBAT/PHBV共混材料的结构与性能[J]. 复合材料学报, 2016, 33(8): 1608-1614. DOI: 10.13801/j.cnki.fhclxb.20151014.004
引用本文: 余洁, 韩建, 朱斐超, 等. 可全生物降解PLA/PBAT/PHBV共混材料的结构与性能[J]. 复合材料学报, 2016, 33(8): 1608-1614. DOI: 10.13801/j.cnki.fhclxb.20151014.004
YU Jie, HAN Jian, ZHU Feichao, et al. Structures and properties of fully biodegradable PLA/PBAT/PHBV blends[J]. Acta Materiae Compositae Sinica, 2016, 33(8): 1608-1614. DOI: 10.13801/j.cnki.fhclxb.20151014.004
Citation: YU Jie, HAN Jian, ZHU Feichao, et al. Structures and properties of fully biodegradable PLA/PBAT/PHBV blends[J]. Acta Materiae Compositae Sinica, 2016, 33(8): 1608-1614. DOI: 10.13801/j.cnki.fhclxb.20151014.004

可全生物降解PLA/PBAT/PHBV共混材料的结构与性能

基金项目: 浙江省重点科技创新团队项目(2011R50003)
详细信息
    通讯作者:

    韩建,教授,博士生导师,研究方向为产业用纺织材料。E-mail:hanjian8@zstu.edu.cn

  • 中图分类号: TB324

Structures and properties of fully biodegradable PLA/PBAT/PHBV blends

  • 摘要: 为了得到刚性与韧性平衡的聚乳酸(PLA)基可生物降解共混材料,通过熔融共混挤出法制备了不同质量比的PLA/己二酸-对苯二甲酸-丁二酯共聚物(PBAT)/聚(3-羟基丁酸-co-羟基戊酸共聚酯(PHBV)可全生物降解共混材料,采用SEM、TG、DSC、毛细管流变仪和万能材料试验机对PLA/PBAT/PHBV共混材料的形态结构、热性能、流变性能和力学性能进行了研究。结果表明:PLA/PBAT/PHBV共混材料的热失重起始分解温度相对纯PHBV提高了45 ℃,热稳定性提高;共混体系中各组分的玻璃化转变温度与单一体系相比几乎无变化,PLA/PBAT/PHBV共混体系为完全不相容体系,同时PBAT和PHBV的加入阻碍了PLA的冷结晶;PLA/PBAT/PHBV 共混体系的共混形态呈“海-岛”分布,PBAT和PHBV均匀地分散于PLA基体中,相界面分明;随着PBAT含量增加,PLA/PBAT/PHBV共混材料熔体的流动性增加,温度变化对黏度的影响变大;PLA/PBAT/PHBV质量比为70/20/10的共混材料可在保留纯PLA 60%拉伸应力的同时,拉伸应变提高到纯PLA的2.6倍,韧性得到改善。所得结论表明PLA/PBAT/PHBV质量比为70/20/10的共混材料的综合力学性能较纯PLA好。
    Abstract: In order to obtain poly(lactic acid) (PLA) matrix biodegradable blends whose stiffness is balanced with toughness, PLA/poly(butylenes adipate-co-terephthalate) (PBAT)/poly(3-hydroxybutyrate-co-hydroxyvalerate) (PHBV) fully biodegradable blends with different mass ratios were prepared by melting co-extrusion method. The morphology structures, thermal characteristics, rheological behavior and mechanical properties of PLA/PBAT/PHBV blends were investigated with SEM, TG, DSC, capillary rheometer and universal material testing machine. The results show that the initial decomposition temperature of PLA/PBAT/PHBV blends increases by 45 ℃ compared with pure PHBV, and the thermal stability of PLA/PBAT/PHBV blends is enhanced. Glass transition temperatures of each component in the blend system change little compared with the unitary system, which indicates that the PLA/PBAT/PHBV blend system is a complete incompatible system. At the same time, the cold crystallization of PLA is confined by the incorporation of PBAT and PHBV. The blend morphology of PLA/PBAT/PHBV blend system presents as a "sea-island" distribution, PBAT and PHBV distribute in PLA matrix evenly, and the interfaces between different phases are clear. When the content of PBAT increasing, the rheological of PLA/PBAT/PHBV blends melt is improved, and the effect of temperature on viscosity increases. The tensile strain of PLA/PBAT/PHBV blends with PLA/PBAT/PHBV mass ratio of 70/20/10 improves to 2.6 times of that of pure PLA, the toughness has been improved, and in the meanwhile, 60% tensile stress of pure PLA can be maintain. The conclusions obtained show that the comprehensive mechanical properties of PLA/PBAT/PHBV blends with PLA/PBAT/PHBV mass ratio of 70/20/10 is better than that of pure PLA.
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  • 被引次数: 26
出版历程
  • 收稿日期:  2015-07-19
  • 修回日期:  2015-09-12
  • 刊出日期:  2016-08-14

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