Abstract:
Porous TiB
2-TiC composites were produced by self-propagating high-temperature synthesis method, with Ti, B
4C and SiC whiskers(SiC
w) as raw materials. The effects of SiC
w content on phases, microstructures, porosity and compressive strength of TiB
2-TiC composites were studied. The results show that the composites are mainly composed of poor boron phases TiB and Ti
3B
4, TiC and a little TiB
2 when there is no SiC
w added. After adding SiC
w into 5Ti+B
4C system, the poor boron phases TiB and Ti
3B
4 decrease and even disappear, while the content of rich boron phase TiB
2 and TiC increase. With the increasing of SiC
w content, the porosity of composites gradually increases from 38.46% to 52.78%. When the content of SiC
w is less than 1.0, the compressive strength of porous TiB
2-TiC composites improves significantly with the increasing of SiC
w content and reaches to the maximum value of 56.04 MPa when the content of SiC
w is 1.0. A part of Ti is consumed by reacting with SiC
w to form TiC, Ti
3SiC
2 and TiSi
2 phases, so less Ti is remaining to react with B
4C. This promotes the formation of rich boron phase TiB
2 and TiC. Moreover some of the granular TiC or lamellar Ti
3SiC
2 grow around the surface of SiC
w, which is beneficial to improve the bonding strength of SiC
w and TiB
2-TiC matrix, and the effect of SiC
w reinforcement.