Abstract:
To enhance the hardness of ZrO
2 matrix composites, TiC
0.7N
0.3/ZrO
2 composites were fabricated by hot pressing method, and the effects of TiC
0.7N
0.3 particle reinforcing phase on the phase composition, microstructure and mechanical properties of the composites were investigated. The results show that the addition of TiC
0.7N
0.3 has the effect to stabilize tetragonal ZrO
2 (t-ZrO
2), and can improve the t-ZrO
2 content in TiC
0.7N
0.3/ZrO
2 composites, thus improve the fracture toughness. With the hot pressing temperature and TiC
0.7N
0.3 content increasing, the hardness of composites increases. When hot pressing at 1 400 ℃, TiC
0.7N
0.3 decomposes partially, and the released N can react with reduced ZrO
2 to form ZrN, which increases the hardness of composites. The relative density of 35wt% TiC
0.7N
0.3/ZrO
2 composites after hot pressing at 1 400 ℃ exceeds 99.9% and Vickers hardness reaches 17 GPa. While the fracture toughness of composites is higher after hot pressing at 1 300 ℃, which is 6.48 MPa·m
1/2. The conclusions provide references for microstructure controlling and improvement TiC
0.7N
0.3/ZrO
2 composite properties.