苎麻纤维/聚乳酸复合材料在不同pH环境下的水解行为
Hydrolysis behaviors of ramie fiber/polylactic acid composites under different pH conditions
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摘要: 以生物基树脂聚乳酸为基体, 以植物纤维苎麻为补强剂, 利用熔融共混法制备了苎麻纤维/聚乳酸(RF/PLA)复合材料, 考查了RF/PLA复合材料在不同pH环境下的水解行为, 并以力学性能测试、SEM、DSC和维卡软化温度检测为手段对其降解行为进行了评估。结果表明: RF/PLA复合材料在碱性(pH = 12.0)环境中的降解比在酸性(pH = 2.0)和中性(pH = 7.0)环境中的更快, 界面侵蚀空化是其性能劣化的主要原因。RF的加入提高了PLA的结晶度和维卡软化温度, 同时也加快了PLA的降解速度, 降解导致材料的力学强度下降。随着降解过程的加剧, RF/PLA复合材料的结晶度和维卡软化温度因材料内部产生缺陷而有所降低;而纯PLA树脂的结晶度却随碱液处理时间的延长而增加, 但其维卡软化温度没有发生明显的变化。Abstract: By using bio-based resin polylactic acid as matrix and plant fiber ramie as reinforcing agent, ramie fiber/polylactic acid (RF/PLA) composites were prepared by melting mixing method. The hydrolysis behaviors of RF/PLA composites in different pH environments were investigated and its degradable properties were evaluated by mechanical properties testing, SEM, DSC and Vicat softening temperature measurement. The results indicate that RF/PLA composites degrade faster in alkaline (pH=12.0) environment than in acid (pH=2.0) or neutral (pH=7.0) environments. The performance deterioration is mainly because the erosion and cavitation of the interface. The addition of RF improves the crystallinity and the Vicat softening temperature of PLA, and accelerates the degradation velocity of PLA. Then the degradation leads to the decline of the mechanical strength of the material. The crystallinity and Vicat softening temperature of RF/PLA composites show a gradual descending with the aggravating of degradation due to the generation of defect in the material. But the crystallinity of pure PLA resin increases and the Vicat softening temperature changes slightly along with the extension of alkali solution treatment time.