Preparation of modified MXene material and its adsorption performance for Sr<sup>2+</sup>

ZHANG Pengli; WU Liya; YANG Zongzheng; WU Zhiguo; CAO Jingguo

doi:10.13801/j.cnki.fhclxb.20221222.001

Volume 40 Issue 10

Oct. 2023

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ZHANG Pengli, WU Liya, YANG Zongzheng, et al. Preparation of modified MXene material and its adsorption performance for Sr2+[J]. Acta Materiae Compositae Sinica, 2023, 40(10): 5678-5691. doi: 10.13801/j.cnki.fhclxb.20221222.001

Citation:

ZHANG Pengli, WU Liya, YANG Zongzheng, et al. Preparation of modified MXene material and its adsorption performance for Sr²⁺[J]. Acta Materiae Compositae Sinica, 2023, 40(10): 5678-5691. doi: 10.13801/j.cnki.fhclxb.20221222.001

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Preparation of modified MXene material and its adsorption performance for Sr²⁺

doi: 10.13801/j.cnki.fhclxb.20221222.001

College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China

Funds: The Foundation of Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization (BCERE201902); Sub Project of National Science and Technology Major Projects (2017 ZX07107-001); Scientific Research Program of Tianjin Municipal Education Commission (Natural Science) (2019 KJ225)

Received Date: 2022-10-21
Accepted Date: 2022-12-10
Rev Recd Date: 2022-11-29

Available Online: 2022-12-26

Publish Date: 2023-10-15

Abstract

Abstract

Ti₃CNT_x/TMAOH was prepared when tetramethylammonium hydroxide (TMAOH) was selected as the intercalating agent. Adsorption performance of Ti₃CNT_x/TMAOH on Sr²⁺ in simulated radioactive wastewater was evaluated. The synthesized Ti₃CNT_x/TMAOH was characterized by SEM-EDS, XRD, BET and FTIR. In the batch experiment, the effects of the dosage of adsorbent Ti₃CNT_x/TMAOH, time, pH and competitive ions on Sr²⁺ removal were investigated. The results show that the removal rate of Sr²⁺ is 99.28% when the dosage is 1.0 g·L⁻¹, pH is 6, and the time is 10 min. The inhibition order of competitive ions is Ca²⁺$ \text{ > > } $Mg²⁺$ \text{ > } $K⁺$ \text{ > } $Na⁺$ \text{ > } $Cs⁺. After four adsorption-desorption cycles, the Sr²⁺ removal rate is 69.56%. The adsorption is consistent with the pseudo-second-order kinetic. The adsorption isotherm data conforms to the Redlich-Peterson (R-P) model. 93.80% and 68.49% Sr²⁺ can be removed in tap water and lake water, respectively. Sr²⁺ is adsorbed by Ti₃CNT_x/TMAOH via ion exchange, surface chelation, electrostatic adsorption and interlayer interception.
- MXene,
- tetramethylammonium hydroxide,
- modified materials,
- adsorption,
- Sr²⁺
Long Abstrsct
Innovation Points

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References(39)

References

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