Research of ultra-high temperature ceramic matrix composites prepared by organic-inorganic transformation

PEI Yuchen; SUN Tongchen; LIU Wei; HAN Weijian; ZHAO Tong

doi:10.13801/j.cnki.fhclxb.20220922.006

Volume 39 Issue 9

Aug. 2022

Turn off MathJax

Article Contents

Article Navigation > Acta Materiae Compositae Sinica > 2022 > 39(9): 4319-4326

PEI Yuchen, SUN Tongchen, LIU Wei, et al. Research of ultra-high temperature ceramic matrix composites prepared by organic-inorganic transformation[J]. Acta Materiae Compositae Sinica, 2022, 39(9): 4319-4326. doi: 10.13801/j.cnki.fhclxb.20220922.006

Citation:

PEI Yuchen, SUN Tongchen, LIU Wei, et al. Research of ultra-high temperature ceramic matrix composites prepared by organic-inorganic transformation[J]. Acta Materiae Compositae Sinica, 2022, 39(9): 4319-4326. doi: 10.13801/j.cnki.fhclxb.20220922.006

Citation:

PDF( 4815 KB)

Research of ultra-high temperature ceramic matrix composites prepared by organic-inorganic transformation

doi: 10.13801/j.cnki.fhclxb.20220922.006

1.
Research Institute of Aerospace Special Materials and Processing Technology, Beijing 100074, China
2.
Institute of Chemistry, Chinese Academy of Science, Beijing 100190, China

Funds: National Natural Science Foundation of China(21803062)

Received Date: 2022-07-04
Accepted Date: 2022-09-20
Rev Recd Date: 2022-09-09

Available Online: 2022-09-26

Publish Date: 2022-08-22

Abstract

Abstract

Ultra-high temperature ceramic matrix (UHTC) composites play a key role for the application of thermal structures of high-speed launch vehicle due to their lightweight, high melting point, high specific strength/stiffness and excellent anti-oxidation/ablation resistance. It is known that UHTC composites consist of carbon fiber reinforcement and ultra-high temperature ceramic matrix, where reinforcement and ceramic matrix possess different physical and chemical properties. To make better performance of UHTC composites, it is quite necessary to think about how to incorporate carbon fiber with ceramic matrix effectively, where the advantages for both fiber and matrix should be taken into accounts. In order to provide a guidance for the fundamental research and engineering application of UHTC composites, in this paper, the synthesis of precursors and the performance of C/ZrC-SiC and C/HfTaC-ZrC-SiC composites are reviewed. And then the technical route for the fabrication of UHTC composites via organic-inorganic transformation is proposed. It is expected to overcome the main issues which encountered in the development of composite design and fabrication.
- ultra-high temperature,
- ceramic matrix composites,
- organic-inorganic transformation,
- aerodyna-mic heating,
- combustion environment
Long Abstrsct
Innovation Points

FullText(HTML)

References(39)

References

[1]	MERCIER R, MCCLINTON C. Hypersonic propulsion-transforming the future of flight[C]//Aiaa International Air & Space Symposium & Exposition: the Next 100 Years. Dayton, 2003.
[2]	蔡国飙, 徐大军. 高超声速飞行器技术[M]. 北京: 科学出版社, 2012. CAI Guobiao, XU Dajun. Hypersonic vehicle technology[M]. Beijing: Science Press, 2012(in Chinese).
[3]	BEHRENS B, MULLER M. Technologies for thermal protection systems applied on reusable launcher[J]. Acta Astronautica,2004,55(3-9):529-536. doi: 10.1016/j.actaastro.2004.05.034
[4]	VANWIE D M, DREWRY J R D G, KING D E, et al. The hypersonic environment: Required operating conditions and design challenges[J]. Journal of Materials Science,2004,39:5915-5924. doi: 10.1023/B:JMSC.0000041688.68135.8b
[5]	SAVINO R, FUMO M D S, PATERNA D, et al. Aerothermodynamic study of UHTC-based thermal protection systems[J]. Aerospace Science and Technology,2005,9:151-160. doi: 10.1016/j.ast.2004.12.003
[6]	ZHOU Z J, DU J, SONG S X, et al. Microstructural characterization of W/Cu functionally graded materials produced by a one-step resistance sintering method[J]. Journal of Alloys and Compounds,2007,428:146-150. doi: 10.1016/j.jallcom.2006.03.073
[7]	ROSENBERG S D, SCHOENMAN L. New generation of high-performance engines for space propulsion[J]. Journal of Propulsion and Power,1994,10:40-46. doi: 10.2514/3.23709
[8]	CHEN Z, WU W, CHENG H, et al. Microstructure and evolution of iridium coating on the C/C composites ablated by oxyacetylene torch[J]. Acta Astronautica,2010,66:682-687. doi: 10.1016/j.actaastro.2009.08.008
[9]	张立同, 成来飞. 连续纤维增韧陶瓷基复合材料可持续发展战略探讨[J]. 复合材料学报, 2007, 24(2): 1-6. ZHANG L T, CHENG L F, Discussion on strategies of sustainable development of continuous fiber reinforced ceramic matrix composites[J]. Acta Materiae Compositae Sinica, 2007, 24(2): 1-6(in Chinese).
[10]	PAUL A, JAYASEELAN D, VENUGOPAL S. UHTC compo-sites for hypersonic applications[J]. The American Ceramic Society Bulletin,2011,291:22-28.
[11]	ZHANG Q M. Research on CMC for aerospace applications[J]. Aerospace Materials & Technology,2011,6:1-3.
[12]	WANG Z G, LIANG J H, DING M, et al. A review on hypersonic airbreathing propulsion system[J]. Advances in Mechanics,2009,39:716-739.
[13]	JACKSON T A, EKLUND D R, FINK A J. High speed propulsion: Performance advantage of advanced materials[J]. Journal of Materials Science,2004,39:5905-5913. doi: 10.1023/B:JMSC.0000041687.37448.06
[14]	SQUIRE T H, MARSCHALL J. Material property requirements for analysis and design of UHTC components in hypersonic applications[J]. Journal of the European Ceramic Society,2010,30:2239-2251. doi: 10.1016/j.jeurceramsoc.2010.01.026
[15]	ZHU T, XU L, ZHANG X, et al. Densification, microstructure and mechanical properties of ZrB₂-SiC_w ceramic composites[J]. Journal of the European Ceramic Society,2009,29:2893-2901. doi: 10.1016/j.jeurceramsoc.2009.03.008
[16]	王海龙, 汪长安, 张锐, 等. 纳米SiC晶须和SiC颗粒混合增韧ZrB₂陶瓷性能[J]. 复合材料学报, 2009, 26:95-101. doi: 10.3321/j.issn:1000-3851.2009.04.017 WANG H L, WANG C A, ZHANG R, et al. Properties of ZrB₂ ceramics reinforced by SiC nanowhiskers and SiC particles[J]. Acta Materiae Compositae Sinica,2009,26:95-101(in Chinese). doi: 10.3321/j.issn:1000-3851.2009.04.017
[17]	ZHANG X, WANG Z, SUN X, et al. Effect of graphite flake on the mechanical properties of hot pressed ZrB₂-SiC ceramics[J]. Materials Letters,2008,62:4360-4362. doi: 10.1016/j.matlet.2008.07.027
[18]	SLIVESTRONI L, FABBRICHE D D, MELANDRI C, et al. Relationships between carbon fiber type and interfacial domain in ZrB₂-based ceramics[J]. Journal of the European Ceramic Society,2016,36:17-24. doi: 10.1016/j.jeurceramsoc.2015.09.026
[19]	SHIMADA S. A thermoanalytical study on the oxidation of ZrC and HfC powders with formation of carbon[J]. Solid State Ionics,2002,149:319-326. doi: 10.1016/S0167-2738(02)00180-7
[20]	LI Z Q, LI H J, ZHANG S Y, et al. Microstructures and ablation properties of C/C-SiC-ZrC composites prepared using C/C skeletons with various densities[J]. Ceramics International,2013,39:8173-8181. doi: 10.1016/j.ceramint.2013.03.093
[21]	BERKOWITZ-MATTUCK J B. High-temperature oxidation III. Zirconium and hafnium diborides[J]. Journal of the Electrochemical Society,1966,113:908-914. doi: 10.1149/1.2424154
[22]	HU P, ZHANG X H, HAN J C, et al. Effect of various addi-tives on the oxidation behavior of ZrB₂-based ultra-high-temperature ceramics at 1800°C[J]. Journal of the Ameri-can Ceramic Society,2010,93:345-349. doi: 10.1111/j.1551-2916.2009.03420.x
[23]	成来飞, 张立同, 梅辉, 等. 化学气相渗透工艺制备陶瓷基复合材料[J]. 上海大学学报, 2014, 20:15-32. CHENG L F, ZHANG L T, MEI H, et al. Manufacturing of CMCs by chemical vapor infiltration process[J]. Journal of Shanghai University,2014,20:15-32(in Chinese).
[24]	WANG Y G, ZHU X J, ZHANG L T, et al. C/C-SiC-ZrC composites fabricated by reactive melt infiltration with Si_0.87Zr_0.13 alloy[J]. Ceramics International,2012,38:4337-4343. doi: 10.1016/j.ceramint.2012.02.016
[25]	ZHAO D, ZHANG C G, HU H F, et al. Preparation and characterization of three-dimensional carbon fiber reinforced zirconium carbide composite by precursor infiltration and pyrolysis process[J]. Ceramics International,2001,37:2089-2093.
[26]	YAN B, CHEN Z F, LI C, et al. Ablation morphology and microstructure of 3D or thogonal C_f/SiC composites prepared by PIP[J]. Science and Engineering of Composite Materials,2008,15:71-77. doi: 10.1515/SECM.2008.15.1.71
[27]	KRUT D P, BORZOV M V, LEMENOVSKII D A, et al. Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride[J]. Russian Chemical Bulletin International Edition,2005,54:247-251. doi: 10.1007/s11172-005-0244-1
[28]	SACKS M D, WANG C A, YANG Z, et al. Carbothermal reduction synthesis of nanocrystalline zirconium carbide and hafnium carbide powders using solution-derived precursors[J]. Journal of Materials Science,2004,39:6057-6066. doi: 10.1023/B:JMSC.0000041702.76858.a7
[29]	曹淑伟, 谢征芳, 王军, 等. 聚锆碳硅烷陶瓷先驱体的制备与表征[J]. 高分子学报, 2008(6):621-625. doi: 10.3321/j.issn:1000-3304.2008.06.018 CAO S W, XIE Z F, WANG J, et al. Synthesis and characterization of polyzirconocarbosilane precursor[J]. Acta Polymerica Sinica,2008(6):621-625(in Chinese). doi: 10.3321/j.issn:1000-3304.2008.06.018
[30]	孔玮佳, 于守泉, 戈敏, 等. 碳化锆陶瓷有机前驱体的热解过程[J]. 过程工程学报, 2019, 19:624-630. doi: 10.12034/j.issn.1009-606X.218299 KONG W J, YU S Q, GE M, et al. Pyrolysis of an organic polymeric precursor of zirconium carbide ceramics[J]. The Chinese Journal of Process Engineering,2019,19:624-630(in Chinese). doi: 10.12034/j.issn.1009-606X.218299
[31]	LI Q G, DONG S M, WANG Z, et al. Microstructures and mechanical properties of 4-directional, C_f/ZrC-SiC composites using ZrC precursor and polycarbosilane[J]. Materials Science and Engineering B,2013,178:1186-1190. doi: 10.1016/j.mseb.2013.07.001
[32]	HU H F, WANG Q K, CHEN Z H, et al. Preparation and characterization of C/SiC-ZrB₂ composites by precursor infiltration and pyrolysis process[J]. Ceramics International,2010,36:1011-1016. doi: 10.1016/j.ceramint.2009.11.015
[33]	CAI T, QIU W F, LIU D, et al. Synthesis of soluble polyyne polymers containing zirconium and silicon and corresponding conversion to nanosized ZrC/SiC composite ceramics[J]. Dalton Trans,2013,42:4285-4290. doi: 10.1039/c2dt32428h
[34]	CAI T, QIU W F, LIU D, et al. Synthesis, characterization, and microstructure of hafnium boride-based composite ceramics via preceramic method[J]. Journal of the Ameri-can Ceramic Society,2013,96:1999-2004. doi: 10.1111/jace.12270
[35]	LU Y, YE L, HAN W J, et al. Synthesis, characterization and microstructure of tantalum carbide-based ceramics by liquid polymeric precursor method[J]. Ceramics International,2015,41:12475-12479. doi: 10.1016/j.ceramint.2015.06.023
[36]	CAI T, QIU W, LIU D, et al. Synthesis of ZrC-SiC powders by a preceramic solution route[J]. Journal of the American Ceramic Society,2013,96:3023-3026. doi: 10.1111/jace.12551
[37]	LIU D, QIU W, CAI T, et al. Synthesis, characterization, and microstructure of ZrC/SiC composite ceramic via liquid precursor conversion method[J]. Journal of the American Ceramic Society,2014,97:1242-1247. doi: 10.1111/jace.12876
[38]	孙同臣, 于新民, 王涛, 等. 锆组元改性C_f/SiC的制备及烧蚀性能[J]. 宇航材料工艺, 2015, 45(4):35-39. doi: 10.3969/j.issn.1007-2330.2015.04.008 SUN T C, YU X M, WANG T, et al. Preparation and anti-ablation property of C_f/SiC composites modified by zirconium element[J]. Aerospace Materials & Technology,2015,45(4):35-39(in Chinese). doi: 10.3969/j.issn.1007-2330.2015.04.008
[39]	刘伟, 宋环君, 于艺, 等. PIP法制备C/ZrC-SiC复合材料工艺与性能研究[J]. 宇航材料工艺, 2019(4):41-44. LIU W, SONG H J, YU Y, et al. Process and properties of C/ZrC-SiC composites prepared by precursor infiltration and pyrolysis[J]. Aerospace Materials & Technology,2019(4):41-44(in Chinese).