Preparation of graphene oxide supported non-woven fabric composite membrane and its photothermal conversion performance

LI Chengxin; GAO Zhuwei; LIU Zhongxin; CHU Zhen; GAO Ruitong; WANG Shihao; HAN Xintong

doi:10.13801/j.cnki.fhclxb.20210304.001

Volume 38 Issue 12

Dec. 2021

Turn off MathJax

Article Contents

Article Navigation > Acta Materiae Compositae Sinica > 2021 > 38(12): 4255-4264

LI Chengxin, GAO Zhuwei, LIU Zhongxin, et al. Preparation of graphene oxide supported non-woven fabric composite membrane and its photothermal conversion performance[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4255-4264. doi: 10.13801/j.cnki.fhclxb.20210304.001

Citation:

LI Chengxin, GAO Zhuwei, LIU Zhongxin, et al. Preparation of graphene oxide supported non-woven fabric composite membrane and its photothermal conversion performance[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4255-4264. doi: 10.13801/j.cnki.fhclxb.20210304.001

Citation:

PDF( 4031 KB)

Preparation of graphene oxide supported non-woven fabric composite membrane and its photothermal conversion performance

doi: 10.13801/j.cnki.fhclxb.20210304.001

1.
School of Chemical Engineering and Technology, Hainan University, Haikou 570228, China
2.
Jiangsu Key Laboratory of Green Process Equipment, Changzhou 213000, China

Received Date: 2020-12-14
Accepted Date: 2021-02-10

Available Online: 2021-03-04

Publish Date: 2021-12-01

Abstract

Abstract

Graphene oxide (GO) is a photothermal conversion material with good performance, which is widely used in seawater desalination, photoelectric conversion and solar energy utilization. In order to test the photothermal evaporation characteristics of GO supported non-woven fabric film (GO film) and polyvinyl alcohol-graphene oxide non-woven fabric composite film (PVA-GO composite film), GO was prepared by an improved Hummers method, and non-woven fabrics of cellulose and polyester were selected, and GO membranes and PVA-GO composite membranes were prepared by immersion-ultrasonic method. Ultraviolet-visible-near infrared spectrometer was used to analyze the light absorption properties of GO film and PVA-GO composite film, and the amount of evaporated water of GO film and PVA-GO composite film was measured by electronic balance. Because PVA has hydrophilicity and increases the water absorption of the membrane, the addition of PVA will increase the amount of evaporated water. The surface characteristics of GO membrane and PVA-GO composite membrane were analyzed by SEM. It is found that the GO membrane without PVA has a fibrous filament structure, and the fibers are clearly visible. After adding PVA, the fiber is wrapped by PVA, indicating that the light absorption capacity of the film is enhanced. When 6wt% PVA is added, the non-woven fibers are completely wrapped by PVA. When using a xenon lamp to conduct water evaporation experiments on the two films, the evaporation rate of the GO film reaches 1.67 kg/(m²·h), and the evaporation rate of the PVA-GO composite film reaches 1.85 kg/(m²·h). In addition, the layered structure of GO appears in the GO film, and the ultraviolet-visible-near-infrared spectroscopy shows a good light absorption ability, and it has a good photothermal conversion ability in the photothermal evaporation experiment. The PVA-GO composite film has better photothermal conversion performance and light absorption when the PVA mass concentration is 4wt%.
- Hummers method,
- graphene oxide,
- polyvinyl alcohol,
- non-woven composite film,
- photothermal conversion performance
Long Abstrsct
Innovation Points

FullText(HTML)

References(31)

References

[1]	YU S, ZHANG Y, DUAN H, et al. The impact of surface chemistry on the performance of localized solar-driven evaporation system[J]. Scientific Reports,2015,5(1):13600-13610. doi: 10.1038/srep13600
[2]	LIU Y, YU S, FENG R, BERNARD A, et al. A bioinspired, reusable, paper-based system for high-performance large-scale evaporation[J]. Advanced Materials,2015,27(17):2768-2774. doi: 10.1002/adma.201500135
[3]	LI C, JIANG D, HUO B, et al. Scalable and robust bilayer polymer foams for highly efficient and stable solar desalination[J]. Nano Energy,2019,60:841-849. doi: 10.1016/j.nanoen.2019.03.087
[4]	赵建玲, 马晨雨, 李建强, 等. 基于全光谱太阳光利用的光热转换材料研究进展[J]. 材料工程, 2019, 47(6):11-19. ZHAO J L, MA C Y, LI J Q, et al. Research progress of photothermal conversion materials based on the utilization of full-spectrum sunlight[J]. Materials Engineering,2019,47(6):11-19(in Chinese).
[5]	邓尧, 黄肖容, 邬晓龄. 氧化石墨烯复合材料的研究进展[J]. 材料导报, 2012, 26(8):84-87. DENG Y, HUANG X R, WU X L. Research progress of graphene oxide composite materials[J]. Materials Review,2012,26(8):84-87(in Chinese).
[6]	STANKOVICH S, DIKIN D A, DOMMETT G H B, et al. Graphene-based composite materials[J]. Nature,2006,442(7100):282-286. doi: 10.1038/nature04969
[7]	BALANDIN A A, GHOSH S, BAO W, et al. Superior thermal conductivity of single-layer grapheme[J]. Nano Letters,2008,8(3):902-907. doi: 10.1021/nl0731872
[8]	王刚. 石墨烯复合材料的制备及其光热转换性能研究[D]. 武汉: 湖北大学, 2018. WANG G. Study on the preparation of graphene composites and its light-to-heat conversion properties[D]. Wuhan: Hubei University, 2018(in Chinese).
[9]	程珙. 石墨烯的制备及其在光驱动产蒸汽中的应用研究[D]. 哈尔滨: 哈尔滨工业大学, 2017. CHENG G. Research on the preparation of graphene and its application in light-driven steam production[D]. Harbin: Harbin Institute of Technology, 2017(in Chinese).
[10]	CHURONG M, YAN J, HUANG Y C, et al. The optical duality of tellurium nanoparticles for broadband solar energy harvesting and efficient photothermal conversion[J]. Science Advances,2018,4(8):9886-9894.
[11]	TOMOYA I, TAKAHIRO O, KYOSUKE S, et al. Fabrication of silica-coated gold nanorods and investigation of their property of photothermal conversion[J]. Biochemical and Biophysical Research Communications,2017,484(2):318-322. doi: 10.1016/j.bbrc.2017.01.112
[12]	WANG Y, WANG C, SONG X, et al. A facile nanocomposite strategy to fabricate a rG0-MWCNT photothermal layer for efficient water evaporation[J]. Journal of Materials Chemistry A,2018,6(3):963-971. doi: 10.1039/C7TA08972D
[13]	LIU X, HOU B, WANG G, et al. Black titanialgraphene oxide nanocomposite membranes with excellent photothermal property for solar steam generation[J]. Journal of Materials Research,2018,33(6):674-684. doi: 10.1557/jmr.2018.25
[14]	BATTISTA L, MECOZZI L, COPPOLA S, et al. Graphene and carbon black nano-composite polymer absorbers for a pyro-electric solar energy harvesting device based on LiNb03 crystals[J]. Applied Energy,2014,136:357-362. doi: 10.1016/j.apenergy.2014.09.035
[15]	REINA A, JIA X, HO J, et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition[J]. Nano Letters,2009,9(1):30-35. doi: 10.1021/nl801827v
[16]	HU X Z, XU W C, ZHOU L, et al. Tailoring graphene oxide-based aerogels for efficient solar steam generation under One Sun[J]. Advanced Materials,2017,29(5):1604031-1604036. doi: 10.1002/adma.201604031
[17]	ITO Y, TANABE Y. HAN JH, et al. Multifunctional porous graphene fof high-efficiency steam generation by heat localization[J]. Advanced Materials,2015,27(29):4302-4307. doi: 10.1002/adma.201501832
[18]	YANG J, PANG Y, HUANG W, et al. Functionalized graphene enables highly efficient solar thermal steam generation[J]. ACS Nano,2017,11(6):5510-5518. doi: 10.1021/acsnano.7b00367
[19]	HE S, ZHANG F, CHENG S, et al. Synthesis of sodium acrylate and acrylamide copolymer/GO hydrogels and their effective adsorption for Pb²⁺and Cd²⁺[J]. Acs Sustamable Chemistry & Engineering,2016,4(7):3948-3959.
[20]	LI X Q, XU W C, TANG M Y, et al. Graphene oxide-based efficient and scalable solar desalination under one sun with a confined 2D water path[J]. Proceedings of the Nation all Academy of Sciences of the United States of America,2016,113(49):13953-13958.
[21]	王敏, 陈爱侠, 陈贝. 壳聚糖/氧化石墨烯复合材料对Cr(VI)吸附性能研究口[J]. 环境保护科学, 2018, 44(2):51-56. WANG Min, CHEN Aixia, CHEN Bei. Research on the adsorption performance of chitosan/graphene oxide compo-sites for Cr(VI)[J]. Environmental Protection Science,2018,44(2):51-56(in Chinese).
[22]	PERESIN M S, HABIBI Y, ZOPPE J O, et al. Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: Manufacture and characterization[J]. Biomacromolecules,2010,11(3):674-810. doi: 10.1021/bm901254n
[23]	陈艳华, 朱丽霞. PVA/氧化石墨烯纳米复合纤维制备及性能研究[J]. 浙江纺织服装职业技术学院学报, 2016(4):15-19. CHEN Y H, ZHU L X. Preparation and properties of PVA/graphene oxide nanocomposite fiber[J]. Journal of Zhejiang Textile and Clothing Vocational and Technical College,2016(4):15-19(in Chinese).
[24]	TRUONG Y B, MARDEL J, GAO Y M, et al. Functional cross-linked electrospun polyvinyl alcohol membranes and their potential applications[J]. Macromolecular Materials and Engineering,2017,302(8):1700024-1700033. doi: 10.1002/mame.201700024
[25]	LEE S S, LEE D M, JEONG H S, et al. Composite microgels created by complexation between polyvinyl alcohol and graphene oxide in compressed double-emulsion drops[J]. Small,2019,19(3):812.
[26]	YONG J, YU S S, LE S, et al. Highly flexible and washable nonwoven photothermal cloth for efficient and practical solar steam generation[J]. Journal of Materials Chemistry A,2018,6:7942-7949. doi: 10.1039/C8TA00187A
[27]	胡希丽, 田伟明, 朱士凤, 等. 聚乙烯醇氧化石墨烯导电棉织物的制备[J]. 棉纺织技术, 2016, 44(4):28-32. HU X L, TIAN W M, ZHU S F, et al. Preparation of polyvinyl alcohol graphene oxide conductive cotton fabric[J]. Cotton Textile Technology,2016,44(4):28-32(in Chinese).
[28]	LIU Y, CHEN J, GUO D, et al. Floatable, self-cleaning, and carbon-black-based superhydrophobic gauze for the solar evaporation enhancement at the air-water interface[J]. ACS Applied Materials & Interfaces,2015,7(24):13645-13652.
[29]	GHASEMI H, NI G, MARCONNET A M, et al. Solar steam generation by heat localization[J]. Nature Communication,2014,5:4449-4456. doi: 10.1038/ncomms5449
[30]	CHEN Q, PEI Z, XU Y, et al. A durable monolithic polymer foam for efficient solar steam generation[J]. Chemical Science,2018,9(3):623-628. doi: 10.1039/C7SC02967E
[31]	CHANG C, TAO P, FU B, et al. Three-dimensional porous solar-driven interfacial evaporator for high-efficiency steam generation under low solar flux.[J]. ACS Omega,2019,4(2):3546-3555. doi: 10.1021/acsomega.8b03573