Micro-characterization and mechanical properties of pseudo-boehmite stone-coated graphene oxide/epoxy resin-cyanate composites

CHEN Yufei; LIU Yulong; ZHAO Hui; TENG Chengjun; CHEN Simin

doi:10.13801/j.cnki.fhclxb.20201116.005

Volume 38 Issue 9

Sep. 2021

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CHEN Yufei, LIU Yulong, ZHAO Hui, et al. Micro-characterization and mechanical properties of pseudo-boehmite stone-coated graphene oxide/epoxy resin-cyanate composites[J]. Acta Materiae Compositae Sinica, 2021, 38(9): 2862-2868. doi: 10.13801/j.cnki.fhclxb.20201116.005

Citation:

CHEN Yufei, LIU Yulong, ZHAO Hui, et al. Micro-characterization and mechanical properties of pseudo-boehmite stone-coated graphene oxide/epoxy resin-cyanate composites[J]. Acta Materiae Compositae Sinica, 2021, 38(9): 2862-2868. doi: 10.13801/j.cnki.fhclxb.20201116.005

Citation:

CHEN Yufei, LIU Yulong, ZHAO Hui, et al. Micro-characterization and mechanical properties of pseudo-boehmite stone-coated graphene oxide/epoxy resin-cyanate composites[J]. Acta Materiae Compositae Sinica, 2021, 38(9): 2862-2868. doi: 10.13801/j.cnki.fhclxb.20201116.005

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Micro-characterization and mechanical properties of pseudo-boehmite stone-coated graphene oxide/epoxy resin-cyanate composites

doi: 10.13801/j.cnki.fhclxb.20201116.005

CHEN Yufei^{1, 2
,
,},
LIU Yulong^2
,,
ZHAO Hui^2
,,
TENG Chengjun^3
,,
CHEN Simin^2
,

1.
Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China
2.
School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China
3.
Center for Disease Prevention and Control, Xiangfang District, Harbin 150000, China

Received Date: 2020-09-17
Accepted Date: 2020-11-12
Rev Recd Date: 2020-10-23

Available Online: 2020-11-16

Publish Date: 2021-09-01

Abstract

Abstract

Graphite oxide (GO) was prepared by using a modified layer of graphite powder as the raw material, and pseudoboehmite (AlOOH) nanoparticles were grown on the surface of GO by a sol-gel method to obtain pseudo-boehmite stone-coated graphene oxide (GO@AlOOH). The matrix (E51-BCE) was synthesized from epoxy resin (E51) and bisphenol A cyanate (BCE), and GO@AlOOH as reinforcement to prepare the GO@AlOOH modified epoxy resin-cyanate composites (GO@AlOOH/E51-BCE) composites. Infrared analysis and X-ray characterization of GO coating materials shows that AlOOH and GO particles have a particular interaction, and there are certain hydroxyl groups on the surface of the material after coating. The composite samples were characterized by SEM showing that the addition of GO@AlOOH significantly changes the fracture surface of the resin and improves the performance. When the doping amount is 0.6wt%, the bending strength, bending modulus and impact strength of the composite material reach the maximum, which are 158.23 MPa, 2.37 GPa and 46.96 kJ/m², respectively. The composite material has excellent mechanical properties and specific development potential.
- bisphenol A cyanate resin,
- graphene oxide,
- pseudo-boehmite stone,
- sol-gel method,
- mechanical properties
Long Abstrsct
Innovation Points

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References(20)

References

[1]	张立颖, 于国良, 孙东洲, 等. 氰酸酯树脂改性的研究进展[J]. 化学与黏合, 2018, 40(4):298-302. ZHANG Liying, YU Guoliang, SUN Dongzhou, et al. Research progress of cyanate ester resin modification[J]. Chemistry and Adhesion,2018,40(4):298-302(in Chinese).
[2]	闫福胜, 梁国正, 秦华宇, 等. 双酚A型氰酸酯树脂的性能[J]. 高分子材料科学与工程, 2000, 16(4):170-172. doi: 10.3321/j.issn:1000-7555.2000.04.048 YAN Fusheng, LIANG Guozheng, QIN Huayu, et al. Properties of bisphenol-A dicyanate resin[J]. Polymer Materials Science and Engineering,2000,16(4):170-172(in Chinese). doi: 10.3321/j.issn:1000-7555.2000.04.048
[3]	TIAN Na, HUANG Hongwei, HE Ying, et, al. Mediator-free direct Zscheme photocatalytic system: BiVO₄/g-C₃N₄ organic-inorganic hybrid photocatalyst with highly efficient visible-light-induced photocatalytic activity[J]. Dalton Transactions,2015,44(9):4297. doi: 10.1039/C4DT03905J
[4]	秦滢杰, 韩建平, 陈书华. 一种氰酸酯-环氧树脂作为卫星结构件复合材料基体的评价[J]. 复合材料学报, 2018, 35(3):528-536. QIN Yingjie, HAN Jianping, CHEN Shuhua. Evaluation of a cyanate ester-epoxy resin as the matrix of composites used for structural components of satellites[J]. Acta Materiae Compositae Sinica,2018,35(3):528-536(in Chinese).
[5]	陶凌云. 热固性树脂改性氰酸酯树脂的研究进展[J]. 绝缘材料, 2019, 52(12):10-13. TAO Lingyun. Research progress of cyanate ester resin modified by thermosetting resin[J]. Insulating Materials,2019,52(12):10-13(in Chinese).
[6]	陈宇飞, 武耘仲, 郭红缘, 等. 功能化石墨烯改性双马来酰亚胺复合材料的微观表征及性能[J]. 化工学报, 2018, 69(10):4456-4463. CHEN Yufei, WU Yunzhong, GUO Hongyuan, et al. Micro characteristic and properties of bismaleimide modified by functionalized graphene composites[J]. Journal of Chemical Industry,2018,69(10):4456-4463(in Chinese).
[7]	叶国锐, 晏义伍, 曹海琳. 氧化石墨烯改性玄武岩纤维及其增强环氧树脂复合材料性能[J]. 复合材料学报, 2014, 31(6):1402-1408. YE Guorui, YAN Yiwu, CAO Hailin. Basalt fiber modified with graphene oxide and properties of its reinforced epoxy composite[J]. Acta Materiae Compositae Sinica,2014,31(6):1402-1408(in Chinese).
[8]	ZAMORATEGUI A, MARTÍNEZ J M, TANAKA S. Maximum solid loading dispersion of pseudo-boehmite nanofiber[J]. Journal of the Australian Ceramic Society,2015,51(2):40-46.
[9]	张欣, 陈建章, 唐安山, 等. 拟薄水铝石胶溶过程研究[J]. 人工晶体学报, 2018, 47(11):2393-2397. doi: 10.3969/j.issn.1000-985X.2018.11.029 ZHANG Xin, CHEN Jianzhang, TANG Anshan, et al. Study on the gelation process of pseudo boehmite[J]. Journal of Synyhetic Crystals,2018,47(11):2393-2397(in Chinese). doi: 10.3969/j.issn.1000-985X.2018.11.029
[10]	REN Fang, ZHU Guangming, REN Penggang, et al. In situ polymerization of graphene oxide and cyanate ester–epoxy with enhanced mechanical and thermal properties[J]. Applied Surface Science,2014,316:549-557. doi: 10.1016/j.apsusc.2014.07.159
[11]	RAMEZANZADEH B, HAERI Z, RAMEZANZADEH M. A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO₂-GO); fabrication of SiO₂-GO/epoxy composite coating with superior barrier and corrosion protection performance[J]. Chemical Engineering Journal,2016,303:511-528. doi: 10.1016/j.cej.2016.06.028
[12]	杨建召, 孙红娟, 彭同江, 等. 不同氧化程度氧化石墨烯氨气敏感性能及机理[J]. 精细化工, 2019, 36(3):380-386+436. YANG Jianzhao, SUN Hongjuan, PENG Tongjiang, et al. Sensitivity and mechanism of graphene oxide ammonia gas with different oxidation degree[J]. Fine Chemicals,2019,36(3):380-386+436(in Chinese).
[13]	国家质量技术监督局. 塑料试样状态调节和实验的标准环境: GB/T 2918—1998[S]. 北京: 中国标准出版社, 1998. Nation Bureau of Technical Supervision. Standard environment for state regulation and testing of plastic samples: GB/T 2918—1998[S]. Beijing: China Standard Press, 1998(in Chinese).
[14]	国家质量监督检验检疫总局. 树脂浇铸体性能实验方法: GB/T 2567—2008[S]. 北京: 中国标准出版社, 2008. General Administration of Quality Supervision, Inspection and Quarantine. Test methods for properties of resin casting boby: GB/T 2567—2008[S]. Beijing: China Standard Press, 2008(in Chinese).
[15]	SHI Tao, GUO Xingzhong, YANG Hui. Preparation and characterization of boehmite (γ-AlOOH) sol[J]. Rare Metal Materials and Engineering,2008,37(S2):73-75.
[16]	朱强, 周峰. 醇铝水解法制备高纯拟薄水铝石工艺实践[J]. 山东冶金, 2019, 41(6):76-77. ZHU Qiang, ZHOU Feng. Preparation of high purity grade pseudo-boehmite by aluminium alkoxide hydrolysis[J]. Shandong Metallurgy,2019,41(6):76-77(in Chinese).
[17]	李波. α-氧化铝的X射线定量分析[J]. 理化检验: 物理分册, 2008, 44(2):79-81. LI Bo. X-ray quantitative analysis of alpha-alumina[J]. PTAC Part A: Phys Test,2008,44(2):79-81(in Chinese).
[18]	商宇飞, 孙晶川, 李齐方. 低介电笼型倍半硅氧烷改性氰酸酯-环氧树脂复合材料[J]. 功能材料, 2008(11):1817-1820. doi: 10.3321/j.issn:1001-9731.2008.11.015 SHANG Yufei, SUN Jingchuan, LI Qifang. Cyanate ester epoxy composite modified by low dielectric cage silsesquioxane[J]. Functional Materials,2008(11):1817-1820(in Chinese). doi: 10.3321/j.issn:1001-9731.2008.11.015
[19]	王文一. 无机纳米粒子/聚合物复合材料研究[D]. 北京化工大学, 2007. WANG Wenyi. Study on inorganic nano particles/polymer composites[D]. Beijing University of Chemical Technology, 2007(in Chinese).
[20]	于倩倩, 陈刚, 郑志才, 等. 酸化石墨烯改性环氧树脂及其碳纤维复合材料力学性能研究[J]. 玻璃钢/复合材料, 2018(5):33-40. YU Qianqian, CHEN Gang, ZHENG Zhicai, et al. Study on the mechanical properties of graphene modified epoxy resin and carbon fiber composite[J]. Fiber Reinforced Plastics/Composites,2018(5):33-40(in Chinese).