基于反蛋白石结构的功能型材料制备及其在水处理领域的研究进展

李菁; 唐新军; 黄勇

基于反蛋白石结构的功能型材料制备及其在水处理领域的研究进展

李菁^{1, 2},
唐新军¹,
黄勇^{1, 2, ,}

1.
新疆工程学院　机电工程学院, 乌鲁木齐 830023
2.
新疆工程学院　激光智能制造与再制造工程技术研究中心, 乌鲁木齐 830023

基金项目: 新疆维吾尔自治区重点研发计划项目(2022B01036)

详细信息

通讯作者:
黄勇，博士，副教授，硕士生导师，研究方向为表面工程　E-mail: lishi182@163.com

中图分类号: TB34; TB332
计量
- 文章访问数: 48
- HTML全文浏览量: 33
- 被引次数: 0
出版历程
- 收稿日期: 2024-01-05
- 修回日期: 2024-02-11
- 录用日期: 2024-03-01
- 网络出版日期: 2024-04-09

Research progress in the preparation and application of functional materials based on inverse opal structure in water treatment fields

LI Jing^{1, 2},
TANG Xinjun¹,
HUANG Yong^{1, 2
, ,}

1.
School of Electrical and Mechanical Engineering, Xinjiang Institute of Engineering, Urumqi 830023, China
2.
Laser Intelligent Manufacturing and Remanufacturing Engineering Technology Research Center, Xinjiang Institute of Engineering, Urumqi 830023, China

Funds: Xinjiang Uygur Autonomous Region Key Research and Development Project (No. 2022B01036)

摘要

摘要: 反蛋白结构(IO)是光子晶体的一种典型的空间结构构型。IO除了具有相互连通、高度规整有序的均孔结构外，还具有光子晶体的慢光效应、多次散射效应和放大光子吸收、发射的特性等。近年来，对IO的应用包括均孔膜、光子墨水、电池电极、传感器等。本文首先简述了IO的构建策略，分为“三步法”和“两步法”。进而详细总结了IO在水处理领域的研究进展，包括过滤筛分、高效吸附、催化降解、水质检测四个方面。最后，对IO材料在水处理领域中现有的局限性和未来的发展趋势进行了阐述和展望。
- 光子晶体 /
- 反蛋白石结构 /
- 多孔材料 /
- 水处理 /
- 研究进展
Abstract: The inverse opal structure (IO) is a typical spatial structure of photonic crystals. In addition to the interconnected, highly regular, and orderly homoporous structure, IO also has the properties of photonic crystals, including the slow light effect, multiple scattering effects, amplified photon absorption and emission characteristics. In recent years, applications for IO have included homoporous membranes, photonic inks, battery electrodes, sensors, etc. In this paper, we first briefly describe the construction strategy of IO, which is divided into the "three-step method" and "two-step method". Then, the research progress of IO in water treatment fields was summarized in detail, including filtration and screening, efficient adsorption, catalytic degradation, and water quality detection. Finally, the existing limitations and future development trends of IO materials in water treatment fields were elaborated and prospected.
- Colloidal crystals /
- Inverse opal structure (IO) /
- Porous materials /
- Water treatment /
- Research progress

HTML全文

图 1 反蛋白石(IO)的“蜂巢”结构^[14]

Figure 1. The "honeycomb" structure of inverse opal (IO)^[14]

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图 2 用不同粒径的胶体粒子制备的反蛋白石膜^[15]

Figure 2. Inverse opal films prepared from colloidal particles of different particle sizes^[15]

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图 3 反蛋白石结构、光子禁带和光学性能^[26,27]

Figure 3. Inverse opal structure, PhotonicBand-Gap and optical properties^[26,27]

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图 4 (a)三步法；(b)两步法制备反蛋白石结构的示意图

Figure 4. Preparation of inverse opal films by (a) the three-step method and (a) the two-step method

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图 5 单分散微球自组装的常见方法^[72]

Figure 5. Common methods for self-assembly of monodisperse microspheres^[72]

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图 6 液体在反蛋白石结构中的传输过程示意图^[41]

Figure 6. Schematic diagram of liquid transport in inverse opal structure^[41]

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图 7 示踪剂在反蛋白结构中的运动行为^[100]：(a)在一个大孔内；(b)在2~3个大孔内

Figure 7. Movement behavior of tracers in inverse opal structure^[100]: (a) in one large hole (b) in 2~3 large holes

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图 8 (a) 胶体晶体模板中SiO₂颗粒直径与IO膜中“较小”孔径之间的关系; (b) 使用375，440和835 nm SiO₂颗粒制备的IO膜的纯水通量^[30]

Figure 8. (a) the relationship between the diameter of SiO₂ particles in the colloidal crystal template and the "smaller" pore size in the IO film; (b) Deionized water fluxes for membranes fabricated using 375, 440 and 835 nm silica particles^[30].

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图 9 (a)具有嵌套结构的IO膜^[103]；(b)具有二级结构的IO膜^[104]

Figure 9. (a) IO membrane with embedded structure ^[103]; (b) IO membranes with secondary structures ^[104]

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图 10 (a)二元有序蛋白石模板及由其制备的IO膜^[83]；(b)具有“漏勺状”孔结构的IO膜^[105]

Figure 10. (a) binary ordered opal templates and IO membranes^[83]; (d) IO membranes with a "colander-like" pore structure^[105]

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图 11 (a)基于电化学制备的铜反蛋白石膜^[108]；(b)具有双疏性质的反蛋白石结构膜^[78]

Figure 11. (a) Copper IO membranes based on electrochemistry ^[108]; (b) IO membranes with hydrophobic and oleophobic properties ^[78]

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图 12 基于反蛋白石结构的一体式过滤器^[34]

Figure 12. One-piece filter based on inverse opal structure^[34]

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图 13 (a) BPQDs-IO TiO₂的构筑和光催化性能^[115]；(b) 引入嵌段聚合物制备TiO₂ 3D分级介孔IO结构及对染料的催化降解性能^[17]

Figure 13. (a) Construction and photocatalytic performance of BPQDs-IO TiO₂^[115]; (c) Preparation of TiO₂ 3D hierarchical mesoporous IO structure by introducing block polymers and its catalytic degradation performance of dyes ^[17]

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图 14 (a)nano GO表面功能化TiO₂ IO^[37]；(b) HHS-Si/TiO₂的构筑策略和催化性能^[35]

Figure 14. (a) nano GO surface-functionalized TiO2 IO^[37]; (d) Construction strategy and catalytic performance of HHS-Si/TiO₂^[35]

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图 15 反蛋白石结构的S型异质结——Ag/ZnO/CeO₂ IO的构建策略及对染料的催化降解性能^[113]

Figure 15. Construction strategy and catalytic degradation performance of dyes of S-type heterojunction-Ag/ZnO/CeO₂ IO^[113];

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图 16 (a) 漆酶固定的反蛋白石水凝胶(LAC@MPEGDA@CS@IOH)的制备^[24]；(b) ZnO/AB-PVDF IO的制备策略及光催化性能的增强^[112]

Figure 16. (a) Preparation of LAC@MPEGDA@CS@IOH hydrogels and their catalytic degradation performance of bisphenol contaminants^[24]; (c) Preparation strategy and photocatalytic performance of ZnO/AB-PVDF IO^[112]

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图 17 (a)合成反蛋白石金属有机框架(IO MOF)的通用策略和对硝基苯酚的水解速率^[20]；(b)基于多巴胺层原位生长Ag NPs的IO膜^[18]

Figure 17. (a) General strategy for the synthesis of inverse opal metal-organic frameworks (IO MOFs) and hydrolysis of p-nitrophenol ^[20]; (b) IO membranes based on PDA layer-based in-situ growth of Ag NPs^[18]

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图 18 CuPc-PACA HIOBs水凝胶反蛋白石珠的制备^[114]

Figure 18. Preparation of CuPc-PACA HIOBs Hydrogel Inverse Opal Beads^[114]

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图 19 (a) 用于水中Hg(Ⅱ)浓度可视化检测的反蛋白石聚合光子晶体 (IOPPC) ^[40]；(b) 用于Cr(VI)检测的壳聚糖反蛋白石颗粒(IOP)^[119]；(c) 用于于水中乙醇浓度检测的新型聚醚砜/聚丙烯酸反蛋白石光子晶体^[121]

Figure 19. (a) Inverse opal polymeric photonic crystals (IOPPCs) for visual detection of Hg(II) concentrations in water ^[40]; (b) Chitosan inverse opal particles (IOPs) for Cr(VI) detection^[119]; (c) Novel polyethersulfone/polyacrylic acid inverse opal photonic crystals for the detection of ethanol concentration in water^[121]

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