A review of the effect of ceramic wastes on mechanical properties and mechanisms of cementitious composites
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摘要: 废弃陶瓷作为一种固体废弃物，质地坚硬，主要化学组成为SiO2和Al2O3。这些特点使得废弃陶瓷经简单的物理处理后具有部分替代天然砂石骨料和作为掺合料的潜力。将废弃陶瓷应用于水泥基复合材料的生产中，可缓解天然砂石过度开采、水泥生产过程的高能耗与污染以及废弃陶瓷堆积所造成环境污染等问题。本文首先分析了各类废弃陶瓷的物理化学性质；而后，从废弃陶瓷在水泥基复合材料中的不同应用形式方面入手，综合评述了废弃陶瓷粗、细骨料以及废弃陶瓷粉对水泥基复合材料基本力学性能影响，揭示了废弃陶瓷对水泥基复合材料力学性能的影响机制；最后，讨论并给出了废弃陶瓷在水泥基复合材料中，尤其在绿色超高性能混凝土和高力学保持性能的耐高温混凝土，进一步应用和研究的建议。Abstract: As one of the solid wastes, ceramic wastes have a hard texture, and their main chemical composition are SiO2 and Al2O3. These characteristics make properly treated ceramic wastes have the potential to replace natural sand, gravel aggregates and act as admixtures. Application of ceramic wastes into cementitious composites will contribute to alleviate the problems of environmental pollution caused by the overexploitation of natural sand and gravel, high energy consumption and pollution in cement production, and the accumulation of ceramic wastes. This paper first briefly describes the physical and chemical properties of various types of ceramic wastes. Then, from the different application forms of ceramic wastes in cementitious composites, this paper comprehensively reviews the research status of the effect of ceramic waste aggregates and ceramic waste powders on the basic mechanical properties of cementitious composites, reveals the influencing mechanisms of ceramic wastes on the basic mechanical properties of cementitious composites. Finally, suggestions for further application and research of cementitious composites with ceramic wastes, especially in green and ultra-high-performance concrete and mechanical property retention after high temperature refractory concrete, are put forward based on the problems existing in the current research.
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图 4 废弃陶瓷粗骨料对水泥基复合材料力学性能增强机制：(a) 天然骨料与废弃陶瓷粗骨料压碎指标[20, 38-41]；(b) 水泥浆体和不同种类粗骨料的ITZ模型[80]；(c) 废弃陶瓷粗骨料内养护机制[47]；(d) 不同骨料与水泥基体间ITZ水化产物成分分析[93]
Figure 4. The enhancement mechanism of ceramic waste coarse aggregates on the mechanical property of cementitious composites: (a) crushing values of natural aggregate and ceramic waste coarse aggregate[20, 38-41]; (b) the ITZ model of cement matrix and different kinds of coarse aggregate[80]; (c) internal curing mechanisms of ceramic waste coarse aggregate[47];(d) analysis of hydration product composition in the ITZ of different aggregates and cement matrix [93]
图 5 废弃陶瓷细骨料对水泥基复合材料力学性能增强机制：(a) 降低ITZ宽度 [18]；(b) 降低孔隙率[19]；(c) 增强骨料和水泥基体的粘结 [40]；(d) 改善 ITZ [103]
Figure 5. Enhancement mechanisms of ceramic wastes fine aggregates on mechanical property of cementitious composites: (a) decrease the ITZ thickness [19]; (b) decrease the porosity [19]; (c) enhance the bonding of aggregate with cement matrix[40]; (d) improve the ITZ [103]
图 6 废弃陶瓷粉对水泥基复合材料的增强机制：(a)废弃陶瓷粉填充效应[118]； (b) 降低Ca(OH)2含量[18] ; (c) 提升水化程度[18]; (d) 降低ITZ宽度[18];(e) 降低孔隙率[18]
Figure 6. Enhancement mechanisms of ceramic waste powder on mechanical property of cementitious composites : (a) the filling effect of ceramic waste powder[118]; (b) decrease the content of Ca(OH)2[18]; (c) enhance the hydration degree[18]; (d) decrease the ITZ width[18]; (e) decrease porosity[18]
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