Research progress of bacterial cellulose and its composites for electrochemical energy storage and sensing
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摘要: 细菌纤维素(Bacterial cellulose，BC)来源丰富，是一种绿色环保的可再生材料。BC具有优异的物理化学特性，被认为是具有多样性应用潜力的生物聚合物材料，随着能源和生态环境的持续恶化，对于开发先进储能技术亟待实现，BC在电化学储能、传感及能源转换领域展现出广阔的应用前景，受到诸多关注。本文对BC做了简要介绍，以BC及其复合材料在电化学储能及传感领域的种类、不同处理及改性手段对BC结构与性能的影响为线索，系统地对BC在电化学储能及传感领域的应用进展进行了概述，对其在新型电子器件及能源转换领域的发展也有所涉及，最后对BC在电化学储能及传感材料的研究进展及发展方向进行了总结和展望。Abstract: Bacterial cellulose (BC) is a green and renewable material with abundant sources. BC has outstanding physical and chemical properties and is considered to be a biopolymer material with diverse application potential. With the continuous deterioration of energy and ecological environment, it is urgent to develop advanced energy storage technology. BC shows broad application prospects in the fields of electrochemical energy storage, sensing and energy conversion, and has gained a lot of attention. In this review, BC is briefly introduced. Based on the types of BC and its composites in the field of electrochemical energy storage and sensing, as well as the effects of different treatments and modification methods on the structure and properties of BC, the application progress of BC in the field of electrochemical energy storage and sensing is systematically summarized. In addition, in terms of the composite matrix and reinforcement concept, the construction process of BC and its composites was systematically introduced. The application status of BC in the field of electrochemical energy storage and sensing is mainly reviewed, and the strengths and weaknesses of its application are analyzed and summarized. Meantime, the different applications of BC in new electronic devices and energy conversion are also involved. Finally, the existing challenges and prospects of BC in electrochemical energy storage and sensing are summarized.
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Key words:
- bacterial cellulose /
- composite /
- energy storage /
- sensing /
- application progress
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图 1 细菌纤维素(BC)主要处理方法及改性手段
Figure 1. Main processing methods and modification methods of bacterial cellulose (BC)
图 2 BC在电化学储能及传感领域的不同应用
Figure 2. Different applications of BC in the field of electrochemical energy storage and sensing
图 6 聚乙烯醇/海藻酸钠/BC/羧基化改性碳纳米管(PVA/SA/BC/MCC)水凝胶作为应变传感器 ：(a)拉伸前后组装成压阻应变传感器的水凝胶示意图；(b)拉伸应变范围为10%至80%的相对电阻变化(ΔR/R0)(插图显示了拉伸过程中的压阻应变传感器的不同状态)；(c)在60%和150%应变下重复拉伸/释放循环的传感器的相对电阻变化[75]
Figure 6. Polyvinyl alcohol/Sodium alginate/BC/Carboxylated modified carbon nanotubes (PVA/SA/BC/MCC) hydrogels as strain sensors: (a) Schematic of hydrogels assembled into piezoresistive strain sensors before and after stretching; (b) Relative resistance changes (ΔR/R0) within the stretching strain range of 10% to 80% (Illustrations showing different states of the piezoresistive strain sensors during stretching); (c) Relative resistance changes of the sensors during repeated stretching/releasing cycles at 60% and 150% strain[75]
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