基于MXene电磁屏蔽材料的研究

梅婷; 冉娅; 蔡雄睿; 孟诗云; 李晓丹

doi:10.13801/j.cnki.fhclxb.20231019.005

基于MXene电磁屏蔽材料的研究

doi: 10.13801/j.cnki.fhclxb.20231019.005

重庆工商大学　环境与资源学院，催化与环境新材料重庆市重点实验室，重庆 400067

基金项目: 国家自然科学基金项目(42172321；51403025)；重庆市自然科学基金面上项目(CSTB2023NSCQ-MSX0474)；重庆市技术创新与应用发展专项面上项目(cstc2019jscx-msxmX0050)；重庆市教委科学技术研究项目(KJZDK202200807；KJQN202100830)；重庆工商大学青年项目(1952015)

详细信息

通讯作者:
李晓丹，博士，教授，研究方向为功能复合材料　E-mail: 12345 ruby@163.com

中图分类号: TB34；TB332
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- 文章访问数: 318
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- PDF下载量: 17
- 被引次数: 0
出版历程
- 收稿日期: 2023-08-19
- 修回日期: 2023-09-24
- 录用日期: 2023-10-11
- 网络出版日期: 2023-10-20
- 刊出日期: 2024-05-15

Research on electromagnetic shielding materials based on MXene

Chongqing Key Laboratory of Catalysis and New Environmental Materials, College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China

Funds: National Natural Science Foundation of China (42172321; 51403025); Chongqing Natural Science Foundation Upper Level Project (CSTB2023NSCQ-MSX0474); Chongqing Municipal Technological Innovation and Application Development Special Top-level Project (cstc2019jscx-msxmX0050); Scientific and Technological Research Project of Chongqing Municipal Education Commission (KJZDK202200807; KJQN202100830); Chongqing Business University Youth Programme (1952015)

摘要

摘要: 电子设备的电磁辐射问题日益严重，开发高性能电磁屏蔽材料是现实的迫切需求。MXene由于其独特的层状结构、丰富的表面基团、优异的力学性能和突出的导电性，被认为在电磁屏蔽方面具有潜在的应用前景。为获得轻质、高效、稳定的电磁屏蔽材料，多种改性方法被用于提高MXene材料的电磁屏蔽效能，如通过定量控制MXene层状结构构建三维多孔、多层和插层等多种形态，通过氧化、掺杂、热处理和接枝等手段调控MXene表面终止基团及将MXene与其他材料杂化组装获得其他性能等。本文从结构设计、表面改性、复合杂化三方面综述了近几年国内外对MXene材料改性的研究进展，并对其提高电磁屏蔽效能进行了比较。
- MXene /
- 电磁屏蔽 /
- 结构设计 /
- 表面改性 /
- 复合杂化
Abstract: To develop high-performance shielding materials is currently emergency and important to erase the electromagnetic radiation concern. MXene is considered to have potential applications in electromagnetic shielding due to its unique layered structure, abundant surface groups, excellent mechanical properties and outstanding electrical conductivity. In order to obtain lightweight, efficient and stable electromagnetic shielding materials, various modification methods have been used to improve the electromagnetic shielding efficacy of MXene materials, such as constructing various morphologies such as three-dimensional porous, multilayer and intercalated layers by quantitatively controlling the MXene layered structure, modulating the termination groups on the surface of MXene by means of oxidization, doping, heat treatment, and grafting, as well as hybridizing and assembling MXene with other materials to obtain other properties, etc. In this paper, the research progress on the modification of MXene materials at home and abroad in recent years is summarized from the aspects of structural design, surface modification, and composite hybridization, and compares their improvement in electromagnetic shielding effectiveness.
- MXene /
- electromagnetic shielding /
- structural design /
- surface modification /
- composite hybridization

HTML全文

图 1 疏水性和柔性MXene泡沫的制造示意图^[15]

Figure 1. Schematic of the fabrication of hydrophobic and flexible MXene foam^[15]

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图 2 用于制备MXene基复合膜的逐层旋喷(SSLbL)工艺的示意图^[18]

CNT—Carbon nanotube; DI H₂O—Deionised water

Figure 2. Schematic of the spin spray layer by layer (SSLbL) process for the preparation of MXene-based composite films^[18]

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图 3 微型超级电容器(MSCs)的制造工艺示意图^[21]

PVA—Polyvinyl alcohol

Figure 3. Schematic of the fabrication process for micro-supercapacitors (MSCs)^[21]

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图 4 基于组装的Ag-MXene杂化三元纳米结构电磁屏蔽机制示意图^[28]

EM—Electromagnetic; WAX—Paraffinic

Figure 4. Schematic diagram of electromagnetic shielding mechanism of Ag-MXene hybridized ternary nanostructures based on assembled^[28]

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图 5 掺氮Ti₃C₂T_x的合成工艺^[32]

Figure 5. Synthesis process of nitrogen-doped Ti₃C₂T_x^[32]

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图 6 Ti₃C₂T_x MXene退火后表面改性示意图^[35]

Figure 6. Schematic representation of Ti₃C₂T_x MXene surface modification after annealing^[35]

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图 7 MXene接枝氧化石墨烯(MXene-g-GO)的制备^[40]

mMXene—Monolayer MXene sheet; mGO—Graphene oxide

Figure 7. Preparation of MXene-grafted graphene oxide (MXene-g-GO)^[40]

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图 8 (a) Ti₃C₂T_x MXene/碳纤维织物(CF_f)/热塑性聚氨酯(TPU)复合材料制备工艺示意图；(b) 电流体动力雾化(EHDA)沉积示意图；(c) 碳纤维(CF)面料表面的化学反应^[47]

LbL—Layer by layer; EMI—Electromagnetic interference

Figure 8. (a) Schematic diagram of the Ti₃C₂T_x MXene/carbon fibre fabric (CF_f)/thermoplastic polyurethane (TPU) composite preparation process; (b) Schematic of electrohydrodynamic atomisation (EHDA) deposition; (c) Chemical reactions on the surface of carbon fibre (CF) fabrics^[47]

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图 9 Ti₃C₂T_x薄片连续导电路径的分层多孔聚酰亚胺(PI)/Ti₃C₂T_x复合薄膜的制备工艺^[50]

T—Temperature

Figure 9. Preparation of hierarchical porous polyimide (PI)/Ti₃C₂T_x composite films with continuous conductive paths in Ti₃C₂T_x sheets^[50]

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图 10 纳米片银纳米线(AgNW)-复合透明导电薄膜(TCF)的制备工艺(a)和以聚氨酯(PU)为衬底制备的MXene-AgNW复合TCF的照片(b) (在弯曲或扭转下仍能导电)^[62]

Figure 10. Preparation process of nanosheet silver nanowires (AgNW)-composite transparent conductive film (TCF) (a) and photographs of MXene-AgNW composite TCF prepared on polyurethane (PU) substrate (b) (Conductive under bending or twisting)^[62]

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图 11 Fe₃O₄@Ti₃C₂T_x/石墨烯泡沫(GF)/聚二甲基硅氧烷(PDMS)复合材料的制备工艺示意图^[66]

CVD—Chemical vapour deposition; NPs—Nanoparticle

Figure 11. Schematic of the preparation process of Fe₃O₄@Ti₃C₂T_x/graphene foam (GF)/polydimethylsiloxane (PDMS) composites^[66]

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