聚偏氟乙烯基复合材料及其在储能器件中的应用

陆澎; 王欣雨; 梁环; 胡欣; 陆春华

doi:10.13801/j.cnki.fhclxb.20230509.001

聚偏氟乙烯基复合材料及其在储能器件中的应用

doi: 10.13801/j.cnki.fhclxb.20230509.001

陆澎^1,,
王欣雨¹,
梁环²,
胡欣^1, ,,
陆春华^1, ,

1.
南京工业大学　材料科学与工程学院，材料化学国家重点实验室，南京 211800
2.
南京工业大学　生物与制药工程学院，南京 211800

基金项目: 国家自然科学基金(22278205；21604037)；中石化委托项目(420106)

详细信息

通讯作者:
胡欣，博士，副教授，硕士生导师，研究方向为聚合物基介电储能材料　E-mail: xinhu@njtech.edu.cn

陆春华，博士，教授，博士生导师，研究方向为光谱的选择性吸收及能量转换利用　E-mail: chhlu@njtech.edu.cn

中图分类号: O631.1；O632.2；TB332
计量
- 文章访问数: 759
- HTML全文浏览量: 287
- PDF下载量: 47
- 被引次数: 0
出版历程
- 收稿日期: 2023-02-28
- 修回日期: 2023-04-14
- 录用日期: 2023-04-28
- 网络出版日期: 2023-05-09
- 刊出日期: 2023-09-15

Polyvinylidene fluoride-based composites and their application in energy storage devices

LU Peng^1
,,
WANG Xinyu¹,
LIANG Huan²,
HU Xin^{1
, ,},
LU Chunhua^{1
, ,}

1.
College of Materials Science and Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, China
2.
College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211800, China

Funds: National Natural Science Foundation of China (22278205; 21604037); Sinopec Ministry of Science; Technology Basic Prospective Research Project (420106)

摘要

摘要: 随着我国“双碳”战略的稳步实施，发展具有“三高一长一低一环”(即高能量密度、高功率密度、高安全性、长循环稳定性、低成本及环保)的电池、超级电容器等能量存储设备，对助力可再生能源的高效存储与稳定输出、推动我国电力系统绿色转型具有重要意义。聚偏氟乙烯(PVDF)基含氟聚合物由于具有良好的力学性能、电学性能及化学稳定性等，已被广泛地用于电池及超级电容器的电极粘结剂、隔膜以及电解质材料。随着储能器件的快速发展，对PVDF基含氟聚合物进行功能化复合以满足对于电池、超级电容器“三高一长一低一环”的需求，成为PVDF基聚合物复合材料的发展重点。本文系统介绍了PVDF基聚合物及其复合材料分别作为粘结剂、电解质和隔膜材料应用于电池及超级电容器的情况，比较了不同功能化复合改性方法对PVDF基聚合物材料性能提升的作用机制，对PVDF基复合材料应用于储能领域的发展前景和挑战进行了展望。
- 聚偏氟乙烯 /
- 复合材料 /
- 超级电容器 /
- 粘结剂 /
- 电解质 /
- 隔膜
Abstract: With the back ground of "double carbon" strategy in China, the development of energy storage devices with 'three high, one long, one low and one protection' (i.e. high energy density, high power density, high security, long cycle stability, low cost and environmental protection) is of great significance. Polyvinylidene fluoride (PVDF)-based fluoropolymers has been widely used as binder, separator and electrolyte materials for energy storage devices of batteries and supercapacitors due to their good mechanical property, electrical and chemical stability. With the rapid development of energy storage devices, functionalization of PVDF-based fluoropolymers to meet the needs of energy storage devices with 'three high, one long, one low and one protection' for energy storage device has gain increasing number of research interests. This paper comprehensively introduces the application of PVDF-based polymer nanocomposites as binder, electrolyte and separator materials in energy storage devices. The mechanism of different functional composite modifications to improve the performance of PVDF-based materials are compared and highlighted. The outlook of the PVDF-based materials applied in the field of energy storage is also discussed.
- polyvinylidene fluoride /
- composites /
- energy storage devices /
- binder /
- electrolyte /
- separator

HTML全文

图 1 聚偏氟乙烯(PVDF)的分子结构^[52]

Figure 1. Molecular structure of polyvinylidene fluoride (PVDF)^[52]

下载: 全尺寸图片幻灯片

图 2 硅电极材料的合成及工作机制：(a) 以偏氟乙烯(VDF)和四氟乙烯(TFE)为前驱体合成PVDF-b-PTFE的一般工艺；(b) 在电化学反应中使用嵌段共聚物粘合剂稳定硅电极的示意图^[10]

Figure 2. Synthesis and working mechanism of silicon electrode materials: (a) Synthesis of PVDF-b-PTFE using vinylidene fluoride (VDF) and tetrafluoroethylene (TFE) as precursors; (b) Schematic diagram of using block copolymer binder to stabilize silicon electrode in electrochemical reaction^[10]

下载: 全尺寸图片幻灯片

图 3 MnO₂与不同粘结剂电子转移的原理图^[39]

Figure 3. Schematic diagram of electron transfer between MnO₂ and different binders ^[39]

下载: 全尺寸图片幻灯片

图 4 杨梅状二氧化硅纳米颗粒(BSNPs)纳米粒子合成示意图^[20]

Figure 4. Schematic diagram of synthesis of bayberry silica nanoparticles (BSNPs) nanoparticles^[20]

TEOS—Tetraethyl orthosilicate; TEAH₃—Triethanolamine; CATB—Cetyltrimethylammonium bromide

下载: 全尺寸图片幻灯片

图 5 (a) 氧化石墨烯(rGO)-聚乙二醇(PEG)-NH₂的分子结构图；(b) 锂离子输运网络示意图^[21]

Figure 5. (a) Molecular structure diagram of graphene oxide (rGO)-polyethylene glycol (PEG)-NH₂; (b) Schematic diagram of lithium ion transport network^[21]

HFP—Hexafluoropropylene

下载: 全尺寸图片幻灯片

图 6 PVDF/Si₃N₄隔膜制备工艺示意图^[27]

Figure 6. Schematic diagram of PVDF/Si₃N₄ separator preparation process^[27]

下载: 全尺寸图片幻灯片

图 7 静电纺丝多层结构MnO₂/P(VDF-HFP)-聚间苯二甲酰间苯二甲酰胺(PMIA)隔膜的制备及其电池组装示意图^[34]

Figure 7. Preparation of electrospun multilayer MnO₂/P(VDF-HFP)-polyisophenyl-isophenamide (PMIA) separator and its battery assembly schematic diagram^[34]

下载: 全尺寸图片幻灯片

表 1 以PVDF及其共聚物为基体的复合材料在储能器件中的应用

Table 1. Application of composite materials based on PVDF and its copolymer in energy storage devices

Devices	Materials	Composite structure	Electrolyte uptake/%	Ionic conductivity/ (S·cm⁻¹)	Electrochemical window/V	Ionic transference number	Discharge capacity/ (mA·h·g⁻¹⁾ (at 1.0 C)	Ref.
Batteries	Binder	PVDF	—	—	4.2	—	185	[7]
		P(VDF-HFP)	—	—	3.4	—	123	[8]
		P(VDF-TrFE)	—	—	—	—	94.3	[9]
		PVDF-b-PTFE	—	—	7	—	1155	[10]
		PEO/PVDF	—	—	4.2	—	112	[11]
		PE-b-PEG/PVDF	—	—	4.0	—	110	[12]
		TX/PVDF	—	—	4.0	—	150.1	[13]
		CMC/PVDF	—	—	4.2	—	376	[14]
		PAA/PVDF	—	—	3.0	—	364	[15]
	Electrolyte	h-BN/PVDF	—	2.98×10⁻⁴	5.24	0.62	142.3	[16]
		P(VDF-TrFE-CTFE)/P(VDF-TrFE)	—	2.37×10⁻⁴	4.15	0.61	—	[17]
		TEGDME/MgBr₂/PVDF	—	1.2×10⁻⁶	—	0.55	—	[18]
		SiO₂/P(VDF-HFP)	—	1.3×10⁻⁴	5.5	—	140.0	[19]
		BSNPs/P(VDF-HFP)	324	3.29×10⁻⁴	—	0.63	178.6	[20]
		rGO-PEG-NH₂/P(VDF-HFP)	—	2.1×10⁻³	5.0	0.45	144.7	[21]
		LLZTO/PEO/P(VDF-HFP)	—	1.05×10⁻⁴	5.2	0.52	121.9	[22]
		LAGP/PEO/P(VDF-HFP)	380	3.27×10⁻³	4.9	0.34	118	[23]
		LMS/LiODFB/P(VDF-HFP)	—	2.51×10⁻⁴	4.8	0.80	132.4	[24]
	Separator	PVDF	257.4	1.2×10⁻³	5.0	—	141	[25]
		PEI-PVDF	520	2.3×10⁻³	5.0	—	125.4	[26]
		Si₃N₄/PVDF	437.2	4.1×10⁻³	5.4	—	80	[27]
		PP/PVDF	295	1.25×10⁻³	4.8	—	72.2	[28]
		Al₂O₃/PVDF	487	—	—	—	512	[29]
		LLZTO/PVDF	—	1.4×10⁻⁴	—	0.66	124	[30]
		PI/P(VDF-HFP)	350	1.46×10⁻³	5.2	—	—	[31]
		PI/P(VDF-HFP)	483.5	1.78×10⁻³	4.94	—	120.4	[32]
		PAN/PVDF-HFP	—	1.2×10⁻³	5.0	—	146	[33]
		MnO₂/PMIA/P (VDF-HFP)	—	2.27×10⁻³	5.01	—	140.2	[34]
		TiO₂/Cellulose/P (VDF-HFP)	403	1.68×10⁻³	4.5	—	205	[35]
		C-TiO₂/Cellulose/P (VDF-HFP)	210.3	1.49×10⁻³	5.2	—	157	[36]
Super- capacitors	Binder	PVDF	—	—	—	—	—	[37]
		PVDF	—	—	—	—	—	[38]
		Graphene/PVDF	—	—	—	—	—	[39]
		RGO/PVDF	—	—	—	—	—	[40]
	Electrolyte	PVA/BaTiO₃/PVDF	—	—	—	—	—	[41]
		SiO₂/PVDF	—	—	2.8	—	—	[42]
		GO/P(VDF-HFP)	342.4	4.23×10⁻⁴	—	—	—	[43]
		P(VDF-HFP)	250	14.4×10⁻³	2.9	—	—	[44]
		P(VDF-HFP)	—	2.07×10⁻⁴	5.0	0.22	—	[45]
	Separator	PVDF	200.2	—	2.5	—	—	[46]
		SiO₂/P(VDF-HFP)	202	0.847×10⁻³	4.3	—	124.4	[47]
		P(VDF-HFP)	112	0.60×10⁻³	4.6	0.30	—	[48]
		ZrO₂/P(VDF-HFP)	320	0.60×10⁻³	3.0	—	—	[49]
		PVDF	360	1.8×10⁻³	3.3	—	—	[50]
		PVDF	426	4.32×10⁻³	3.4	—	145	[51]
Notes: PEO—Polyethylene oxide; PE-b-PEG—Polyethylene-b-polyethylene glycol; CMC—Carboxyl methyl cellulose; CTFE—Chlorotrifluoroethylene; PAA —Polyacrylic acid; PEI—Polyetherimide; PVA—Polyvinyl alcohol.

下载: 导出CSV

参考文献(94)

[1]	NITTA N, WU F X, LEE J T, et al. Li-ion battery materials: Present and future[J]. Materials Today,2015,18(5):252-264. doi: 10.1016/j.mattod.2014.10.040
[2]	PING Y, JIN-RAN S U. Technology and application progress of lithium ion battery[J]. Chinese Journal of Power Sources,2009,33(11):1037-1039.
[3]	XIE H, TANG Z, LI Z, et al. PVDF-HFP composite polymer electrolyte with excellent electrochemical properties for Li-ion batteries[J]. Journal of Solid State Electrochemistry,2008,12(11):1497-1502. doi: 10.1007/s10008-008-0511-9
[4]	BURKE A. Ultracapacitors: Why, how, and where is the technology[J]. Journal of Power Sources,2000,91(1):37-50. doi: 10.1016/S0378-7753(00)00485-7
[5]	YOO M, FRANK C W, MORI S, et al. Effect of poly(vinylidene fluoride) binder crystallinity and graphite structure on the mechanical strength of the composite anode in a lithium ion battery[J]. Polymer,2003,44(15):4197-4204. doi: 10.1016/S0032-3861(03)00364-1
[6]	HE J Y, LIU J Q, LI J, et al. Enhanced ionic conductivity and electrochemical capacity of lithium ion battery based on PVDF-HFP/HDPE membrane[J]. Materials Letters,2016,170:126-129. doi: 10.1016/j.matlet.2016.02.010
[7]	LOGHAVI M M, BAHADORIKHALILI S, LARI N, et al. The effect of crystalline microstructure of PVDF binder on mechanical and electrochemical performance of lithium-ion batteries cathode[J]. Zeitschrift für Physikalische Chemie,2020,234(3):381-397.
[8]	DONG Y Z, ZHAO Y M, CHEN Y H, et al. Optimized carbon-coated LiFePO₄ cathode material for lithium-ion batteries[J]. Materials Chemistry and Physics,2009,115(1):245-250. doi: 10.1016/j.matchemphys.2008.11.063
[9]	GöREN A, COSTA C M, SILVA M M, et al. Influence of fluoropolymer binders on the electrochemical performance of C-LiFePO₄ based cathodes[J]. Solid State Ionics,2016,295:57-64. doi: 10.1016/j.ssi.2016.07.012
[10]	WANG X, LIU S, ZHANG Y, et al. Highly elastic block copolymer binders for silicon anodes in lithium-ion batteries[J]. ACS Applied Materials & Interfaces,2020,12(34):38132-38139.
[11]	LIANG X H, WU X, WANG Y T, et al. Study on preparation and performance of PEO-PVDF composite binder for lithium ion batteries[J]. International Journal of Electrochemical Science,2020,15(9):8471-8478.
[12]	ZHENG M, FU X, WANG Y, et al. Poly(vinylidene fluoride)-based blends as new binders for lithium-ion batteries[J]. ChemElectroChem,2018,5(16):2288-2294. doi: 10.1002/celc.201800553
[13]	LIU S, ZHONG H, ZHANG C, et al. Improving the processability and cycling stability of nano-LiFePO₄ cathode by using PVDF/TX binary binder[J]. Composite Interfaces,2019,26(11):1013-1024. doi: 10.1080/09276440.2019.1578574
[14]	TOIGO C, SINGH M, GMEINER B, et al. A method to measure the swelling of water-soluble PVDF binder system and its electrochemical performance for lithium ion batteries[J]. Journal of The Electrochemical Society,2020,167(2):020514. doi: 10.1149/1945-7111/ab68c2
[15]	NAGULAPATI V M, LEE J H, KIM H S, et al. Novel hybrid binder mixture tailored to enhance the electrochemical performance of SbTe bi-metallic anode for sodium ion batteries[J]. Journal of Electroanalytical Chemistry,2020,865(7):114160.
[16]	ZHAO Y, QIN Y, DA X, et al. High lithium salt content PVDF-based solid-state composite polymer electrolyte enhanced by h-BN nanosheets[J]. ChemSusChem,2022,15(24):e202201554.
[17]	HUANG Y, ZENG J, LI S, et al. Conformational regulation of dielectric poly(vinylidene fluoride)-based solid-state electrolytes for efficient lithium salt dissociation and lithium-ion transportation[J]. Advanced Energy Materials,2023,13(15):2203888. doi: 10.1002/aenm.202203888
[18]	MESALLAM M, KAMAR E M, SHARMA N, et al. Synthesis and characterization of polyvinylidene fluoride/magnesium bromide polymer electrolyte for magnesium battery application[J]. Physica Scripta,2020,95(11):115805. doi: 10.1088/1402-4896/abbcf4
[19]	SONG S, TAN X, ZHAI Y, et al. Ultrathin, compacted gel polymer electrolytes enable high-energy and stable-cycling 4 V lithium-metal batteries[J]. ChemElectroChem,2020,7(17):3656-3662. doi: 10.1002/celc.202000955
[20]	GUO J, HOU H B, CHENG J M, et al. Microporous bayberry-like nano-silica fillers enabling superior performance gel polymer electrolyte for lithium metal batteries[J]. Journal of Materials Science: Materials in Electronics,2021,32(5):1-13.
[21]	XU P, CHEN H, ZHOU X, et al. Gel polymer electrolyte based on PVDF-HFP matrix composited with rGO-PEG-NH₂ for high-performance lithium ion battery[J]. Journal of Membrane Science,2021,617:118660. doi: 10.1016/j.memsci.2020.118660
[22]	HUANG J, HUANG Y, ZHANG Z, et al. Li_6.7La₃Zr_1.7Ta_0.3O₁₂ reinforced PEO/PVDF-HFP based composite solid electrolyte for all solid-state lithium metal battery[J]. Energy & Fuels,2020,34(11):15011-15018.
[23]	LIU Q, LIU Y, JIAO X, et al. Enhanced ionic conductivity and interface stability of hybrid solid-state polymer electrolyte for rechargeable lithium metal batteries[J]. Energy Storage Materials,2019,23:105-111. doi: 10.1016/j.ensm.2019.05.023
[24]	TAO S, LI J, HU R, et al. 3Li₂S-2MoS₂ filled composite polymer PVDF-HFP/LiODFB electrolyte with excellent interface performance for lithium metal batteries[J]. Applied Surface Science,2021,536(30):147794.
[25]	TABANI Z, MAGHSOUDI H, ZONOUZ A F. High electrochemical stability of polyvinylidene fluoride (PVDF) porous membranes using phase inversion methods for lithium-ion batteries[J]. Journal of Solid State Electrochemistry,2021,25(2):651-657. doi: 10.1007/s10008-020-04842-5
[26]	崔巍巍, 孟庆朋, 王振宇, 等. 大倍率高耐热聚醚酰亚胺-聚偏氟乙烯芯壳纳米纤维锂离子电池隔膜[J]. 复合材料学报, 2019, 36(1):69-76. doi: 10.13801/j.cnki.fhclxb.20180503.001 CUI Weiwei, MENG Qingpeng, WANG Zhenyu, et al. Large power and high heat resistance polyetherimide polyvinylidene fluoride core-shell nanofiber lithium ion battery separator[J]. Acta Materiae Compositae Sinica,2019,36(1):69-76(in Chinese). doi: 10.13801/j.cnki.fhclxb.20180503.001
[27]	MA X, QIAO F, QIAN M, et al. Facile fabrication of flexible electrodes with poly(vinylidene fluoride)/Si₃N₄ composite separator prepared by electrospinning for sodium-ion batteries[J]. Scripta Materialia,2021,190:153-157. doi: 10.1016/j.scriptamat.2020.08.053
[28]	JANAKIRAMAN S, KHALIFA M, BISWAL R, et al. High performance electrospun nanofiber coated polypropylene membrane as a separator for sodium ion batteries[J]. Journal of Power Sources,2020,460:228060. doi: 10.1016/j.jpowsour.2020.228060
[29]	徐玲倩, 陈关喜, 吴清洲, 等. Al₂O₃/PVDF无纺布锂离子电池隔膜的制备及性能表征[J]. 材料科学与工程学报, 2019, 37(5):689-696. XU Lingqing, CHEN Guanxi, WU Qingzhou, et al. Preparation and characterization of Al₂O₃/PVDF non-woven lithium ion battery separator[J]. Journal of Materials Science and Engineering,2019,37(5):689-696(in Chinese).
[30]	HUO H, LI X, CHEN Y, et al. Bifunctional composite separator with a solid-state-battery strategy for dendrite-free lithium metal batteries[J]. Energy Storage Materials,2020,29:361-366. doi: 10.1016/j.ensm.2019.12.022
[31]	CHEN W, LIU Y, MA Y, et al. Improved performance of PVDF-HFP/PI nanofiber membrane for lithium ion battery separator prepared by a bicomponent cross-electrospinning method[J]. Materials Letters,2014,133:67-70. doi: 10.1016/j.matlet.2014.06.163
[32]	CAI M, YUAN D, ZHANG X, et al. Lithium ion battery separator with improved performance via side-by-side bicomponent electrospinning of PVDF-HFP/PI followed by 3D thermal crosslinking[J]. Journal of Power Sources,2020,461:228123. doi: 10.1016/j.jpowsour.2020.228123
[33]	LIU Q, JIANG W, LU W, et al. Anisotropic semi-aligned PAN@PVDF-HFP separator for Li-ion batteries[J]. Nanotechnology,2020,31(43):435701. doi: 10.1088/1361-6528/aba303
[34]	ZHAO H, DENG N, KANG W, et al. Designing of multilevel-nanofibers-based organic–inorganic hybrid gel electrolyte enabling an innovative lithium-ion battery with superior ionic transport capability and advanced security[J]. Chemical Engineering Journal,2020,390:124571. doi: 10.1016/j.cej.2020.124571
[35]	ASGHAR M R, ANWAR M T, XIA G, et al. Cellulose/poly(vinylidene fluoride hexafluoropropylene) composite membrane with titania nanoparticles for lithium-ion batteries[J]. Materials Chemistry and Physics,2020,252:123122. doi: 10.1016/j.matchemphys.2020.123122
[36]	LI L, LI H, WANG Y, et al. Poly(vinylidenefluoride-hexafluoropropylene)/cellulose/carboxylic TiO₂ composite separator with high temperature resistance for lithium-ion batteries[J]. Ionics,2020,26(9):4489-4497. doi: 10.1007/s11581-020-03587-5
[37]	LIN T Q, CHEN I W, LIU F X, et al. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage[J]. Science,2015,350(6267):1508-1513. doi: 10.1126/science.aab3798
[38]	ZHU Z T, TANG S H, YUAN J W, et al. Effects of various binders on supercapacitor performances[J]. International Journal of Electrochemical Science,2016,11(10):8270-8279.
[39]	DONG J Y, WANG Z Y, KANG X H. The synthesis of graphene/PVDF composite binder and its application in high performance MnO₂ supercapacitors[J]. Colloids and Surfaces A—Physicochemical and Engineering Aspects,2016,489:282-288.
[40]	SONG D H, KIM J Y, AN J Y, et al. Graphene-based supercapacitor performance enhancement by an immersion precipitation of poly(vinylidene fluoride) binder[J]. Materials Research Express,2019,6(10):105616. doi: 10.1088/2053-1591/ab3cee
[41]	AVAL L F, GHORANNEVISS M, POUR G B. Graphite nanoparticles paper supercapacitor based on gel electrolyte[J]. Materials for Renewable and Sustainable Energy,2018,7(4):29. doi: 10.1007/s40243-018-0136-6
[42]	ORTEGA P F R, TRIGUEIRO J P C, SILVA G G, et al. Improving supercapacitor capacitance by using a novel gel nanocomposite polymer electrolyte based on nanostructured SiO₂, PVDF and imidazolium ionic liquid[J]. Electrochi-mica Acta,2016,188:809-817. doi: 10.1016/j.electacta.2015.12.056
[43]	AHMAD A L, FAROOQUI U R, HAMID N A. Effect of graphene oxide (GO) on poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) polymer electrolyte membrane[J]. Polymer,2018,142:330-336. doi: 10.1016/j.polymer.2018.03.052
[44]	YANG C Y, SUN M Q, WANG X, et al. A novel flexible supercapacitor based on cross-linked PVDF-HFP porous organogel electrolyte and carbon nanotube paper@PI-conjugated polymer film electrodes[J]. ACS Sustainable Chemistry& Engineering,2015,3(9):2067-2076.
[45]	SHALU, SINGH V K, SINGH R K. Development of ion conducting polymer gel electrolyte membranes based on polymer PVDF-HFP, BMIMTFSI ionic liquid and the Li-salt with improved electrical, thermal and structural properties[J]. Journal of Materials Chemistry C,2015,3(28):7305-7318. doi: 10.1039/C5TC00940E
[46]	ARTHI R, JAIKUMAR V, MURALIDHARAN P. Development of electrospun PVdF polymer membrane as separator for supercapacitor applications[J]. Energy Sources Part A: Recovery, Utilization and Environmental Effects,2019,44(1):1-15.
[47]	WANG H, GAO H P. A sandwich-like composite nonwoven separator for Li-ion batteries[J]. Electrochimica Acta,2016,215:525-534. doi: 10.1016/j.electacta.2016.08.039
[48]	YANG Y Q, CHANG Z, LI M X, et al. A sodium ion conducting gel polymer electrolyte[J]. Solid State Ionics,2014,269:1-7.
[49]	YADAV N, MISHRA K, HASHMI S A. Nanofiller-incorporated porous polymer electrolyte for electrochemical energy storage devices[J]. High Performance Polymers,2018,30(8):957-970. doi: 10.1177/0954008318774392
[50]	HE T S, JIA R, LANG X S, et al. Preparation and electrochemical performance of PVdF ultrafine porous fiber separator-cum-electrolyte for supercapacitor[J]. Journal of the Electrochemical Society,2017,164(13):E379-E384. doi: 10.1149/2.0631713jes
[51]	RAGHAVAN P, ZHAO X, MANUEL J, et al. Electrochemical studies on polymer electrolytes based on poly(vinylidene fluoride-co-hexafluoropropylene) membranes prepared by electrospinning and phase inversion-A comparative study[J]. Materials Research Bulletin,2010,45(3):362-366. doi: 10.1016/j.materresbull.2009.12.001
[52]	赵世怀, 张翠翠, 杨紫博, 等. PVDF/PVA复合膜的制备与性能研究[J]. 化工新型材料, 2018, 46(5):60-63. ZHAO Shihuai, ZHANG Cuicui, YANG Zibo, et al. Preparation and properties of PVDF/PVA composite membranes[J]. New Chemical Materials,2018,46(5):60-63(in Chinese).
[53]	MALEKI H, DENG G P, KERZHNER-HALLER I, et al. Thermal stability studies of binder materials in anodes for lithium-ion batteries[J]. Journal of the Electrochemical Society,2000,147(12):4470-4475. doi: 10.1149/1.1394088
[54]	EOM J Y, CAO L. Effect of anode binders on low-temperature performance of automotive lithium-ion batteries[J]. Journal of Power Sources,2019,441(2):227178.
[55]	ROTH E P, DOUGHTY D H, FRANKLIN J. DSC investigation of exothermic reactions occurring at elevated temperatures in lithium-ion anodes containing PVDF-based binders[J]. Journal of Power Sources,2004,134(2):222-234. doi: 10.1016/j.jpowsour.2004.03.074
[56]	ZHENG X, BOMMIER C, LUO W, et al. Sodium metal anodes for room-temperature sodium-ion batteries: Applications, challenges and solutions[J]. Energy Storage Materials,2019,16:6-23. doi: 10.1016/j.ensm.2018.04.014
[57]	PARULEKAR S, SHOLAPURE S, HOLMUKHE R, et al. Study of PVDF Based Electrode Structure in Supercapacitors[J]. International Journal of Engineering and Technology,2018,7(4):313-315.
[58]	WANG B, JI J, LI K. Crystal nuclei templated nanostructured membranes prepared by solvent crystallization and polymer migration[J]. Nature Communications,2016,7(1):12804. doi: 10.1038/ncomms12804
[59]	ARMAND M, TARASCON J M. Building better batteries[J]. Nature,2008,451(7179):652-657. doi: 10.1038/451652a
[60]	ZHOU Q, MA J, DONG S, et al. Intermolecular chemistry in solid polymer electrolytes for high-energy-density lithium batteries[J]. Advanced Materials,2019,31(50):1902029. doi: 10.1002/adma.201902029
[61]	ZHOU D, SHANMUKARAJ D, TKACHEVA A, et al. Polymer electrolytes for lithium-based batteries: Advances and prospects[J]. Chem,2019,5(9):2326-2352. doi: 10.1016/j.chempr.2019.05.009
[62]	LONG L, WANG S, XIAO M, et al. Polymer electrolytes for lithium polymer batteries[J]. Journal of Materials Chemistry A,2016,4(26):10038-10069. doi: 10.1039/C6TA02621D
[63]	LIU S, LIU W, BA D, et al. Filler-integrated composite polymer electrolyte for solid-state lithium batteries[J]. Advanced Materials,2023,35(2):2110423. doi: 10.1002/adma.202110423
[64]	CHEN S, WANG J, ZHANG Z, et al. In-situ preparation of poly(ethylene oxide)/Li₃PS₄ hybrid polymer electrolyte with good nanofiller distribution for rechargeable solid-state lithium batteries[J]. Journal of Power Sources,2018,387:72-80. doi: 10.1016/j.jpowsour.2018.03.016
[65]	CHEN S, WEN K, FAN J, et al. Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes[J]. Journal of Materials Chemistry A,2018,6(25):11631-11663. doi: 10.1039/C8TA03358G
[66]	SINGH R, JANAKIRAMAN S, KHALIFA M, et al. A high thermally stable polyacrylonitrile (PAN)-based gel polymer electrolyte for rechargeable Mg-ion battery[J]. Journal of Materials Science: Materials in Electronics,2020,31(24):22912-22925. doi: 10.1007/s10854-020-04818-1
[67]	JEEDI V R, NARSAIAH E L, YALLA M, et al. Structural and electrical studies of PMMA and PVDF based blend polymer electrolyte[J]. Sn Applied Sciences,2020,2(12):2093. doi: 10.1007/s42452-020-03868-8
[68]	RAJEH A, RAGAB H M, ABUTALIB M M. Co doped ZnO reinforced PEMA/PMMA composite: Structural, thermal, dielectric and electrical properties for electrochemical applications[J]. Journal of Molecular Structure,2020,1217(7):128447.
[69]	LEE Y Y, LIU Y L. Crosslinked electrospun poly(vinylidene difluoride) fiber mat as a matrix of gel polymer electrolyte for fast-charging lithium-ion battery[J]. Electrochimica Acta,2017,258:1329-1335. doi: 10.1016/j.electacta.2017.11.191
[70]	SHAN Y, LI L, CHEN X, et al. Gentle haulers of lithium-ion–nanomolybdenum carbide fillers in solid polymer electrolyte[J]. ACS Energy Letters,2022,7(7):2289-2296. doi: 10.1021/acsenergylett.2c00849
[71]	JIA H, ONISHI H, VON ASPERN N, et al. A propylene carbonate based gel polymer electrolyte for extended cycle life and improved safety performance of lithium ion batteries[J]. Journal of Power Sources,2018,397:343-351. doi: 10.1016/j.jpowsour.2018.07.039
[72]	ZHANG Y, WANG X, FENG W, et al. Effects of the shapes of BaTiO₃ nanofillers on PEO-based electrolytes for all-solid-state lithium-ion batteries[J]. Ionics,2019,25(4):1471-1480. doi: 10.1007/s11581-018-2706-0
[73]	MA W T, KUMAR S R, HSU C T, et al. Magnetic field-assisted alignment of graphene oxide nanosheets in a polymer matrix to enhance ionic conduction[J]. Journal of Membrane Science,2018,563:259-269. doi: 10.1016/j.memsci.2018.05.062
[74]	LUO J, FANG C C, WU N L. High polarity poly(vinylidene difluoride) thin coating for dendrite-free and high-performance lithium metal anodes[J]. Advanced Energy Materials,2017,8(6):1701482.
[75]	WAQAS M, ALI S, LV W, et al. High-performance PE-BN/PVDF-HFP bilayer separator for lithium-ion batteries[J]. Advanced Materials Interfaces,2019,6(1):1801330. doi: 10.1002/admi.201801330
[76]	YANG F, SUN W, BAI Y, et al. Rational design of sandwich-like "Gel-Liquid-Gel" electrolytes for dendrite-free lithium metal batteries[J]. Industrial & Engineering Chemistry Research,2020,59(32):14207-14216.
[77]	NUNES-PEREIRA J, COSTA C M, LANCEROS-MENDEZ S. Polymer composites and blends for battery separators: State of the art, challenges and future trends[J]. Journal of Power Sources,2015,281(4):378-398.
[78]	YANG X, ZHANG F, ZHANG L, et al. A high-performance graphene oxide-doped ion gel as gel polymer electrolyte for all-solid-state supercapacitor applications[J]. Advanced Functional Materials,2013,23(26):3353-3360. doi: 10.1002/adfm.201203556
[79]	GSAIZ P, LOPES A C, BARKER S E, et al. Ionic liquids for the control of the morphology in poly(vinylidene fluoride-co-hexafluoropropylene) membranes[J]. Materials & Design,2018,155(29):325-333.
[80]	BARBOSA J C, DIAS J P, LANCEROS-MENDEZ S, et al. Recent advances in poly(vinylidene fluoride) and its copolymers for lithium-ion battery separators[J]. Membranes,2018,8(3):45. doi: 10.3390/membranes8030045
[81]	LIN W, WANG F, WANG H, et al. Thermal-stable separators: Design principles and strategies towards safe lithium-ion battery operations[J]. ChemSusChem,2022,15(24):e202201464.
[82]	RAGHAVENDRA K V G, VINOTH R, ZEB K, et al. An intuitive review of supercapacitors with recent progress and novel device applications[J]. Journal of Energy Storage,2020,31(9):101652.
[83]	郑怡磊, 吴于松, 许远远, 等. 高性能锂离子电池隔膜的研究进展[J]. 有机氟工业, 2018, 181(4):21-26. ZHENG Yilei, WU Yusong, XU Yuanyuan, et al. Research progress of high-performance lithium-ion battery separator[J]. Organic-Fluorine Industry,2018,181(4):21-26(in Chinese).
[84]	COSTA C M, SILVA M M, LANCEROS-MENDEZ S. Battery separators based on vinylidene fluoride (VDF) polymers and copolymers for lithium ion battery applications[J]. RSC Advances,2013,3(29):11404-11417. doi: 10.1039/c3ra40732b
[85]	WANG S X, YAP C C, HE J, et al. Electrospinning: A facile technique for fabricating functional nanofibers for environmental applications[J]. Nanotechnology Reviews,2016,5(1):51-73.
[86]	WU Y S, YANG C C, LUO S P, et al. PVDF-HFP/PET/PVDF-HFP composite membrane for lithium-ion power batteries[J]. International Journal of Hydrogen Energy,2017,42(10):6862-6875. doi: 10.1016/j.ijhydene.2016.11.201
[87]	ALI S, TAN C, WAQAS M, et al. Highly efficient PVDF-HFP/colloidal alumina composite separator for high-temperature lithium-ion batteries[J]. Advanced Materials Interfaces,2018,5(5):1701147. doi: 10.1002/admi.201701147
[88]	SZUBZDA B, SZMAJA A, OZIMEK M, et al. Polymer membranes as separators for supercapacitors[J]. Applied Physics A-Materials Science & Processing,2014,117(4):1801-1809.
[89]	WANG J A, LIN S C, WANG Y S, et al. Bi-functional water-born polyurethane-potassium poly(acrylate) designed for carbon-based electrodes of quasi solid-state supercapacitors: Establishing ionic tunnels and acting as a binder[J]. Journal of Power Sources,2019,413(21):77-85.
[90]	HASHIM M A, SA'ADU L, BAHARUDDIN M B, et al. Using PVA, methacrylate and lauroyl chitosan as separator in supercapacitors[J]. Journal of Materials Science Research, 2013, 3(1): 25-29.
[91]	NA R Q, ZHANG X R, HUO P F, et al. High performance disulfonated poly(arylene ether sulfone)/poly(ethylene oxide) composite membrane used as a novel separator for supercapacitor with neutral electrolyte and activated carbon electrodes[J]. High Performance Polymers,2017,29(8):984-993. doi: 10.1177/0954008316666386
[92]	KARABELLI D, LEPRETRE J C, ALLOIN F, et al. Poly(vinylidene fluoride)-based macroporous separators for supercapacitors[J]. Electrochimica Acta,2011,57(1):98-103.
[93]	JABBARNIA A, KHAN W S, GHAZINEZAMI A, et al. Investigating the thermal, mechanical, and electrochemical properties of PVdF/PVP nanofibrous membranes for supercapacitor applications[J]. Journal of Applied Polymer Science,2016,133(30):43707.
[94]	JAKRIYA S P, SYED A M, PILLAI S K, et al. High-performance poly(vinylidene fluoride-co-hexafluoropropylene) based electrospun polyelectrolyte mat for lithium-ion battery[J]. Materials Express,2018,8(1):77-84. doi: 10.1166/mex.2018.1405

施引文献

资源附件(0)

访问统计

点击查看大图

图(7) / 表(1)

计量

文章访问数: 759
HTML全文浏览量: 287
PDF下载量: 47
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

聚偏氟乙烯基复合材料及其在储能器件中的应用

doi: 10.13801/j.cnki.fhclxb.20230509.001

通讯作者:
胡欣，博士，副教授，硕士生导师，研究方向为聚合物基介电储能材料　E-mail: xinhu@njtech.edu.cn

陆春华，博士，教授，博士生导师，研究方向为光谱的选择性吸收及能量转换利用　E-mail: chhlu@njtech.edu.cn

计量

Polyvinylidene fluoride-based composites and their application in energy storage devices

计量

目录

留言板

聚偏氟乙烯基复合材料及其在储能器件中的应用

doi: 10.13801/j.cnki.fhclxb.20230509.001

通讯作者: 胡欣，博士，副教授，硕士生导师，研究方向为聚合物基介电储能材料 E-mail: xinhu@njtech.edu.cn 陆春华，博士，教授，博士生导师，研究方向为光谱的选择性吸收及能量转换利用 E-mail: chhlu@njtech.edu.cn

计量

出版历程

Polyvinylidene fluoride-based composites and their application in energy storage devices

计量

出版历程

目录

通讯作者:
胡欣，博士，副教授，硕士生导师，研究方向为聚合物基介电储能材料　E-mail: xinhu@njtech.edu.cn

陆春华，博士，教授，博士生导师，研究方向为光谱的选择性吸收及能量转换利用　E-mail: chhlu@njtech.edu.cn