木质素基复合材料的直写式3D打印及其功能应用

姜波; 郭新宇; 焦欢; 金永灿

doi:10.13801/j.cnki.fhclxb.20221205.002

木质素基复合材料的直写式3D打印及其功能应用

doi: 10.13801/j.cnki.fhclxb.20221205.002

姜波^{1, 2, ,},
郭新宇¹,
焦欢¹,
金永灿¹

1.
南京林业大学　江苏省林业资源高效加工利用协同创新中心，林产化学与材料国际创新高地，南京 210037
2.
植物纤维功能材料国家林业和草原局重点实验室，福州 350108

基金项目: 国家自然科学基金(32201500；32271797)；江苏省自然科学基金(BK20220431)；江苏省高等学校自然科学研究基金(21KJB220001)；国家林业和草原局植物纤维功能材料重点实验室开放基金(2022KFJJ05)

详细信息

通讯作者:
姜波，博士，副教授，硕士生导师，研究方向为生物质化学与材料　E-mail: bjiang@njfu.edu.cn

中图分类号: O636.2
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- 被引次数: 0
出版历程
- 收稿日期: 2022-10-25
- 修回日期: 2022-11-21
- 录用日期: 2022-11-26
- 网络出版日期: 2022-12-05
- 刊出日期: 2023-04-15

Direct ink writing of lignin-based composites and their applications

JIANG Bo^{1, 2
, ,},
GUO Xinyu¹,
JIAO Huan¹,
JIN Yongcan¹

1.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037, China
2.
National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials, Fuzhou 350108, China

Funds: National Natural Science Foundation of China (32201500; 32271797); Natural Science Foundation of Jiangsu Province (BK20220431); Natural Science Foundation of the Jiangsu Higher Education Institutions of China (21KJB220001); Open-Ended Fund of National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials (2022KFJJ05)

摘要

摘要: 作为自然界最丰富的可再生芳香族生物质资源，木质素近年来在能源、环境、医学等领域受到广泛关注。其中，采用3D打印技术构建具有特定结构和功能的木质素基复合材料是提升木质素附加值的重要途径之一，同时可有效避免木质素化学结构复杂多变、多分散性高、刚性大等在传统材料制备过程中带来的负面影响。本文围绕木质素基复合材料的直写式3D打印，重点综述了近年来木质素基复合材料在直写式3D打印方面的研究成果与进展。首先介绍了木质素的结构特性及直写式3D打印技术；然后系统总结了木质素流变学特性与其打印性能之间的构-效关系；最后讨论了3D打印的木质素基复合材料在能源、环境等领域的应用现状及其面临的挑战，并展望了木质素基复合材料在直写式3D打印方面的发展方向。
- 木质素基复合材料 /
- 直写式3D打印技术 /
- 流变学行为 /
- 可打印性 /
- 功能应用
Abstract: As the most abundant renewable aromatic biopolymer in nature, lignin recently has received extensive attention in the fields of energy, environment, and medicine. In particular, the use of 3D printing technology to construct lignin-based composites with tunable and desired structures and functions is one of the important ways to pro-mote the high-value utilization of lignin, which can also avoid the negative effects during traditional material preparation that caused by the diverse chemical structure, high polydispersity in molecular weight, and rigid structure of lignin. This paper focuses on the direct ink writing of lignin-based composites, mainly with the achievements and recent progress critically reviewed. Firstly, the structural features of lignin and the technology of direct ink writing are briefly summarized. Subsequently, the structure-rheology behavior relationship during 3D printing of lignin-based composites is discussed. Finally, the functional applications of 3D printed lignin-based composites in engineering, energy, and environment, as well as the potential problems and challenges, are summarized. Further, the main points towards future directions on lignin composites based on direct in writing are also highlighted.
- lignin composites /
- direct ink writing /
- rheological behavior /
- printability /
- applications

HTML全文

图 1 木质素的分子结构模型：(a) 针叶材木质素；(b) 阔叶材木质素；(c) 草类木质素；(d) 阔叶材和草类木质素中阿魏酸酯连接形式；(e) 草类木质素中阿魏酸酯与阿拉伯木聚糖的连接形式；(f) 草类木质素中麦黄酮结构^[9]

Figure 1. Molecular structure model of lignin: (a) Softwood lignin; (b) Hardwood lignin; (c) Grass lignin; (d) Ferulate in hardwoods and grasses lignin; (e) Ferulate on araxyl in grasses; (f) Tricin in grasses^[9]

A—β-ether (β-O-4); B—Phenylcoumaran (β-5); C—Resinol (β-β); C′— Tetrahydrofuran (β-β); D—Dibenzodioxocin (5-5/4-O-β); E—Biphenyl ether (5-O-4); F—Spirodienone (β-1); X—Cinnamyl alcohol endgroup; pC—p-coumarate; pB—p-hydroxybenzoate; FA—Ferulate; Ac—Acetate; T—Tricin; H—p-hydroxyphenyl unit; G—Guaiacyl unit; S—Syringyl unit

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图 2 直写式3D打印过程及其特点^[16-18]

Figure 2. Process and features of direct ink writing^[16-18]

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图 3 木质素/聚氧乙烯-聚氧丙烯-聚氧乙烯三嵌段共聚物(F127)“墨水”的流变学特性和可打印性^[31]

Figure 3. Rheological behavior and printability of lignin/poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) (F127) ink^[31]

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图 4 木质素/g-C₃N₄/碳纳米管(CNT)“墨水”的流变学特性和可打印性

Figure 4. Rheological behavior and printability of lignin/g-C₃N₄/carbon nanotube (CNT) ink^[38]

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图 5 垂直打印过程“墨水”挤出速率和针头上升速率对打印形状的影响^[39]

Figure 5. Effects of feed rate and retraction rate on pillar morphology during vertical 3D printing^[39]

ΔA₁—A downward movement of the piston to a required amount; ΔA₂—An upward movement of pistion to its initial position; z—Moving direction of pistion; t—Time

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图 6 水溶性木质素/石墨烯的流变学特性^[37]：(a) 黏度；(b) 模量

Figure 6. Rheological behavior and printability of water-soluble lignin/graphene ink^[37]: (a) Viscosity; (b) Moduli

GO—Graphene oxide

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图 7 木质素基垂直阵列催化剂用于光电水裂解制氢^[38]

Figure 7. Lignin-based arrays catalyst for photoelectrochemical hydrogen evolution^[38]

VB—Valence band; CB—Conduction band

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图 8 3D打印木质素/石墨烯(GO)碳材料的电性能^[37]

Figure 8. Electrical properties of 3D printed lignin/graphene(GO)-based carbon materials^[37]

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图 9 3D打印木质素基活性碳的染料吸附性能^[31]

Figure 9. Dye adsorption property of lignin-based active carbon constructed by 3D printing^[31]

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