石墨烯/高分子功能复合材料制备与应用研究进展

朱世东; 赵乾臻; 王星海; 李金灵; 戚东涛; 孔鲁诗

doi:10.13801/j.cnki.fhclxb.20210713.001

石墨烯/高分子功能复合材料制备与应用研究进展

doi: 10.13801/j.cnki.fhclxb.20210713.001

1.
西安石油大学　材料科学与工程学院，西安 710065
2.
中国石油长庆油田分公司　第二输油处，庆阳 745000
3.
西安石油大学化学化工学院　陕西省油气田环境污染与储层保护重点实验室，西安 710065
4.
中国石油集团工程材料研究院有限公司石油管材及装备材料服役行为与结构安全国家重点实验室，西安 710077

基金项目: 国家自然科学基金(51974245；21808182)；陕西省重点研发项目(2020GY234)；西安市科技计划项目(2020KJRC0097；2020KJRC0098)；研究生创新与实践能力培养计划立项项目(YCS20113059)

详细信息

通讯作者:
朱世东，博士，副教授，硕士生导师，研究方向为新材料的研制　E-mail：zhusdxt@126.com

中图分类号: TB332；O613
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出版历程
- 收稿日期: 2021-05-06
- 修回日期: 2021-06-19
- 录用日期: 2021-07-05
- 网络出版日期: 2021-07-13
- 刊出日期: 2022-02-01

Research progress in preparation and application of graphene/polymer functional composite materials

1.
School of Materials Science and Engineering, Xi’an Shiyou University, Xi’an 710065, China
2.
CNPC The Second Oil Transfer Department of Changqing Oilfield Company, Qingyang 745000, China
3.
Shaanxi Province Key Laboratory of Environmental Pollution Control and Reservoir Protection Technology of Oilfields, College of Chemistry & Chemical Engineering, Xi’an Shiyou University, Xi'an 710065, China
4.
State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, CNPC Tubular Goods Research Institute, Xi’an 710077, China

摘要

摘要: 新型无机纳米材料与传统聚合物分子结合将极大地促进石墨烯的多功能性、高补强性与高分子的良好力学性、成熟工艺得以充分展现。本文简述了功能材料、纳米石墨烯、高分子的发展历程，分别对吸附材料的高分子来源(三种天然高分子、合成高分子)、催化材料在(合成、电)化学反应中的应用、分离材料的孔径特性(低渗透、纳滤、超滤、微滤)、生物医用材料的用途(组织工程、医用卫生、医用药材)进行了剖析，重点详述了多种石墨烯/高分子功能复合材料功能与效能，并对其制备方式与效能提高原因进行了简析，同时对导电材料、智能(或传导)材料及磁性材料和液晶材料等进行了概述，以期为新型石墨烯/高分子功能复合材料的研制与应用提供借鉴。最后，对石墨烯/高分子功能复合材料在普及率和工业化上存在的问题等进行了思考，并做出了展望。
- 石墨烯 /
- 高分子 /
- 功能材料 /
- 催化活性 /
- 吸附特征
Abstract: The combination of the new-type inorganic nanomaterials with the traditional polymer molecules will greatly promote the fully demonstrate of the versatility and high reinforcing property of the graphene, as well as the good mechanical properties and mature technology of the polymer. The development of the functional materials, nano-graphene and the polymer was briefly described in this paper. The polymer source of adsorption materials (three kinds of natural polymer, synthetic polymer), the application of catalytic materials in (synthetic, electric-) chemical reactions, the pore size characteristics of separation materials (low permeability, nanofiltration, ultrafiltration, microfiltration), and the use (tissue engineering, medical health, and medical materials) of biomedical materials were briefly analyzed. The functions and efficiency of various graphene/polymer functional composites were focused on, and their preparation methods and the reasons for the improvement of efficiency were simply stated. At the same time, the conductive materials, intelligent (or conduction) materials and magnetic materials and liquid crystal materials were summarized. It is expected to provide reference for the development and application of novel graphene/polymer functional composites. Last but not the least, the problems existing in the popularization rate and industrialization of graphene/polymer functional composites were also considered and prospected.
- graphene /
- polymer /
- functional materials /
- catalytic activity /
- adsorption characteristics

HTML全文

图 1 构建3D氧化石墨烯生物聚合物凝胶的方法(a)、氧化石墨烯浓缩液(左)和氧化石墨烯生物聚合物凝胶照片(b)、GO在新劈裂的云母上的AFM图像(c)、冻干氧化石墨烯海绵(d)、氧化石墨烯-BSA凝胶(e)、氧化石墨烯-CS凝胶(f)、氧化石墨烯-DNA凝胶(g)的FE-SEM图像^[28]

Figure 1. Approach for constructing the 3D GO-biopolymers gel (a), photograph of GO concentrated solution (left) and GO-biopolymer gels (b), AFM image for GO on freshly cleaved mica (c), FE-SEM images of the lyophilized GO sponge (d), GO-BSA gel (e), GO-CS gel (f) and GO-DNA gel (g)^[28]

下载: 全尺寸图片幻灯片

图 2 典型柔性有机太阳能电池(FOSC)结构、能带与弯曲循环性能^[85]

Figure 2. Structure, band, bending cycle properties of flexible organic solar cell (FOSC)^[85]

P3HT : PCBM—Poly 3-hexylthiophene : [6,6]-phenyl-C61-butyric acid methyl ester; TFSA-GR—Bis(trifluoromethanesulfonyl) amides doped graphene; GQDs—Graphene quantum dots; PCE—Power conversion efficiency

下载: 全尺寸图片幻灯片

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