Progress of silicon-based anode for lithium-ion batteries with metal-organic frameworks
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摘要: 近年来，金属-有机骨架(MOFs)及其衍生物由于具有高孔隙率、可修饰的官能团、可控的化学成分等优点，在改善硅负极体积膨胀和导电性等方面取得了很大进展。通过讨论MOFs及其衍生物在锂离子电池硅负极的最新研究成果，重点阐述了以MOFs为基体的硅负极的结构设计，提出了影响其电化学性能的相关因素。最后，针对MOFs及其衍生物在电化学应用中的研究瓶颈和可能的发展方向提出看法。Abstract: Recent years, metal-organic frameworks (MOFs) and their derived nanostructures have made great progress in improving the volumetric expansion and the electronic conductivity of silicon anodes due to their high porosity, modifiable functional groups and controlled chemical components. Through discussing the latest research findings of MOFs and its derivatives in silicon anodes of lithium-ion batteries, the structural design of silicon anodes with MOFs as matrices was emphasized, and the related factors affecting its electrochemical properties were put forward. Finally, the research bottlenecks and possible development directions of MOFs and its derivatives in electrochemical properties were proposed.
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图 3 在不同电流密度下Si@ZIF-8-700N复合材料的放电容量(电池在试验前以50 mA·g−1的电流密度循环10次)和在200 mA·g−1下Si@ZIF-8-700N复合材料的循环性能[40]
Figure 3. Discharge capacity of Si@ZIF-8-700N composite at various current densities (cells were cycled for 10 times at a current density of 50 mA·g−1 before test) and long cycle performance of Si@ZIF-8-700N composite at 200 mA·g−1[40]
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