Micro-morphology and mechanical properties of organo-montmorillonite-modified Al2O3/polyurethane elastomer composites
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摘要: 以十八烷基三甲基氯化铵(OTAC)为插层剂,通过离子交换法改性钠基蒙脱土(MMT)制得有机蒙脱土(OMMT),采用硅烷偶联剂KH550改性纳米Al2O3得到表面修饰的KH-Al2O3;以聚丙二醇(PPG)、4,4’-二苯基甲烷二异氰酸酯(MDI)和1,4-丁二醇(BDO)为原料合成聚氨酯弹性体(PUE)基体,并将两种无机填料OMMT和KH-Al2O3以不同质量比且总质量分数保持3wt%掺杂至PUE基体中,采用预聚体法制备OMMT-改性Al2O3/PUE(OMMT-Al2O3/PUE)复合材料,用FTIR、XRD、SEM和TEM测试分析了复合材料的微观形貌和力学性能。结果表明:OMMT在2 922 cm-1和1 469 cm-1处出现—CH2吸收峰,表明OTAC分子链成功插入到MMT片层,且OMMT的层间距较MMT增加约0.7 nm; KH-Al2O3在2 924 cm-1和1 447 cm-1处出现了—CH2吸收峰,表明Al2O3表面成功接枝KH550; TEM图像可清晰看到OMMT的片层结构,改性后的OMMT和KH-Al2O3存在一定的相互作用,且同种分子内的相互作用减弱。OMMT-Al2O3/PUE复合材料中的OMMT与KH-Al2O3质量比适当时,OMMT和KH-Al2O3在PUE基体中分散性较好,OMMT在基体中以层状结构存在,且KH-Al2O3与基体形成新的化学键改变了原有晶型结构,出现了新的衍射峰。力学性能测试结果表明:当OMMT与Al2O3质量比为1∶1时,OMMT-Al2O3/PUE复合材料的拉伸强度、扯断伸长率及断裂拉伸强度分别为21.82 MPa、668%和19.98 MPa,比PUE基体分别提高了43.8%、29.2%和36.8%,与单一采用OMMT或KH-Al2O3改性PUE树脂相比,力学性能也明显得到改善。
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关键词:
- 聚氨酯弹性体 /
- 有机蒙脱土 /
- 十八烷基三甲基氯化铵 /
- Al2O3 /
- 力学性能
Abstract: Sodium montmorillonite (MMT) was modified by octadecyl trimethyl ammonium chloride (OTAC) via cation exchange to obtain organo-montmorillonite (OMMT), Al2O3 was modified by silane coupling agent KH550 to get KH-Al2O3. The polyurethane elastomer (PUE) was synthesized with 4,4'-diphenylmethane diisocyanate (MDI), polypropylene glycol (PPG) and 1,4-butanediol (BDO) as the raw materials, different mass ratio of OMMT to KH-Al2O3 with a fixed 3wt% content as the modifier, the OMMT-modified Al2O3/PUE(OMMT-Al2O3/PUE) composites were prepared by prepolymer method. The micro-morphology and mechanical properties of OMMT-Al2O3/PUE composites were measured. The results of FTIR, XRD and TEM show that the characteristic peaks of -CH2 (2 922 cm-1 and 1 469 cm-1) appear, indicating that new groups are introduced into the layers of MMT, and the interlayer spacing of OMMT is about 0.7 nm bigger than that of MMT. The characteristic peaks of -CH2 (2 924 cm-1 and 1 447 cm-1) appear, proving that KH550 is successfully grafted to the surface of Al2O3. The layer structure of OMMT can be clearly seen, and OMMT and KH-Al2O3 have good dispersion in the PUE matrix. SEM and XRD reveal that proper OMMT and KH-Al2O3 disperse evenly in the PUE matrix, and OMMT exists in the form of single layer in the OMMT-Al2O3/PUE composites. There is a certain interaction between OMMT and KH-Al2O3, and the interactions within the same molecule are reduced. The test results of mechanical properties of OMMT-Al2O3/PUE composites display that the maximum tensile strength, elongation at break and breaking tensile strength of OMMT-Al2O3/PUE composites are 21.82 MPa, 668% and 19.98 MPa, 43.8%, 29.2% and 36.8% higher than that of PUE matrix, respectively, when the mass ratio of OMMT to Al2O3 is 1:1. The mechanical properties of OMMT-Al2O3/PUE composites are significantly better than those of OMMT/PUE or Al2O3/PUE composite.
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