Preparation and properties of carbon fiber-nylon 6 mixed braid fabric composites
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摘要: 为了探究合适的碳纤维表面处理方法,改善碳纤维-尼龙6织物复合材料界面结合效果,提高复合材料的力学性能,通过混编的方式制备碳纤维-尼龙6预制件,将预制件浸泡在不同浓度的醇溶尼龙无水乙醇溶液中,最后将预制件通过热压成型,制备碳纤维织物-尼龙6复合材料。采用万能拉伸试验机、SEM、TGA、DSC、XRD分析碳纤维-尼龙6复合材料的力学性能、微观形貌、耐热性能、结晶度及晶型变化。结果表明:将预制件在浓度为1wt%的尼龙溶液处理后,并采用1℃/min的降温速率制备的碳纤维-尼龙6织物复合材料力学性能最佳,抗拉强度、弹性模量、弯曲强度、弯曲模量、冲击强度分别为449.32 MPa、5.32 GPa、657.67 MPa、44.08 GPa、138.42 kJ/m2。纤维拔出后,单根碳纤维表面附着部分尼龙基体,碳纤维与尼龙基体形成了良好的界面层。碳纤维-尼龙6织物复合材料的起始分解温度较尼龙6纤维提高了13℃,耐热性有所增强,尼龙6树脂主要以α晶型存在,结晶较为完善。Abstract: To explore the suitable surface treatment method of carbon fiber and improve the interface bonding effect of carbon fiber fabric reinforced nylon 6 composites, carbon fiber-nylon 6 preforms were prepared by mixing braid, and the preform was socked in different concentrations of alcohol-soluble nylon anhydrous ethanol solution, and finally the carbon fiber fabric-nylon 6 composite was prepared by hot pressing. The mechanical properties, microstructure, heat resistance, crystallinity and crystal form of the carbon fiber fabric-nylon 6 composite were analyzed by universal tensile testing machine, SEM, TGA, DSC and XRD. The results indicate that when preforms are socked at 1wt% alcohol-soluble nylon anhydrous ethanol solution, the carbon fiber fabric-nylon 6 composites have the best mechanical properties, the tensile strength, elastic modulus, bending strength, flexural modulus and impact strength are 449.32 MPa, 5.32 GPa, 657.67 MPa, 44.08 GPa and 138.42 kJ/m2, respectively. After the fiber is pulled out, a part of the nylon matrix is adhered to the surface of the single carbon fiber, and the carbon fiber and the nylon matrix form a good interface layer. Compared with nylon 6 fiber, the initial decomposition temperature of carbon fiber fabric-nylon 6 composite material is increased by 13℃, and the heat resistance is enhanced. The nylon 6 resin mainly exists in α crystal form, and the crystallization is perfect.
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Key words:
- carbon fiber /
- nylon 6 /
- mixed braid fabric /
- surface treatment /
- hot press forming /
- composites
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