IMPACT STRENGTH AND FRACTURE MECHANISM OF POLY(BUTYLENE TEREPHTHALATE)/THERMOPLASTIC POLYAMIDE ELASTOMERS ALLOYS
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摘要: 聚对苯二甲酸丁二酯(PBT ) 与在PBT 中添加了热塑性聚酰胺系弹性体(TPA E) 的PBT合金相比, 前者的抗冲击强度低, 后者的抗冲击强度高, 通过偏光显微镜和扫描电镜的观察, 在U型缺口前部区域内的塑性束缚下, PBT 呈脆性破坏; PBT 的合金因塑性区域内的空穴化和空穴的变形及空穴之间区域的颈缩和纤维化, 有效的吸收了冲击能量, 使塑性束缚得到缓解, 促进了平面应变状态向平面应力状态转变, 最终呈半韧性或韧性破坏。Abstract: Poly(butylene terephthalate)(PBT) showed low impact strength values. Whereas the addition of thermoplastic polyamide elastomers(TPAE) and compatibilizers alloys showed high impact strength values. Polarization optical microscope(POM) and scanning electron microscope(SEM) observations of the fracture surfaces and deformed regions beneath the fracture surfaces revealed that the fracture process of PBT was brittle which was originated from plastic constraint at the notch tip. The fracture of alloys was also caused by plastic constraint at the notch tip. However, the plastic deformation zone at the notch tip was composed of many voids and partially elongated fibrils, and this absorbed impact energy. The plastic deformation was enhanced by the transition of the stress state from plane strain to plane stress. The final fracture occurred from the notch tip connecting voids in the plastic deformation zone.
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Key words:
- poly(butylene terephthalate)
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