Oxidation resistance of Cu-Ag composite nanoparticles coated with terpineol molecules
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摘要: 用气-液两相稳定法制备了Cu-Ag复合纳米粉。并用XRD、 HRTEM、 DSC-TG、 红外光谱、 化学分析和氧含量分析等手段研究了粉体的相结构、 表面组成、 形貌、 粒度分布和氧化特性。结果表明, Cu-Ag复合纳米颗粒具有壳核结构, 核为纳米Cu-Ag, 壳为厚度10nm左右的松油醇(C10H18O)分子层和氧化层双层结构, 粉体的粒度分布为20~150nm。在空气中, 220℃包覆在Cu-Ag复合纳米粒子表面的松油醇分子开始氧化, 进而导致Cu-Ag复合纳米粒子在340℃左右迅速氧化, 680℃左右Cu-Ag复合纳米粒子完全氧化。 温度低于220℃时, 气-液两相稳定法制备的Cu-Ag复合纳米粉的抗氧化能力比气相稳定法制备的Cu-Ag复合纳米粉的抗氧化能力好。
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关键词:
- 松油醇 /
- 稳定化处理 /
- Cu-Ag复合纳米粉 /
- 壳核结构 /
- 氧化特性
Abstract: The Cu-Ag composite nanoparticles were prepared by a both gas and liquid phases stabilizing method. The structure and morphology and surface layer as well as oxidation resistance of the particles were studied using X-ray diffraction(XRD), high-resolution transmission electron microscopy(HRTEM), infrared spectrum analysis, chemical analysis, gas analysis, and differential thermal and thermogravimetry analysis. The results show that the particle size ranges from 20nm to 150nm. The surface of particles consists of a bi-layer including a terpineol(C10H18O) molecules layer and an oxide one; the bi-layer prevents the particles from further oxidation in air. The terpineol molecules are oxidized at about 220℃ in air. The Cu-Ag composite nanoparticles are violently oxidized at about 340℃ because the terpineol molecules of the surface of the particles are oxidized. At the temperature below 220℃, the oxidation resistance of the Cu-Ag composite nanoparticles prepared by the both gas and liquid phases stabilizing method is better than that by the gas phase stabilizing method.-
Key words:
- terpineol /
- stabilizing /
- Cu-Ag composite nanoparticles /
- core-shell structure /
- oxidation resistance
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