Template synthesis flake like polypyrrole and montmorillonite/polypyrrole composites by vapor-liquor phase polymerization
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摘要: 以FeCl3为氧化剂,与钠基蒙脱土(MMT)以不同比例进行离子交换后所得悬浮液与吡咯(Py)单体进行气液相聚合,制备出蒙脱土/聚吡咯(MMT/PPy)复合材料。XRD、FTIR和SEM分析表明,Py单体在MMT的片层间发生了聚合反应,MMT的层间距随PPy含量增加不断变大。MMT/PPy复合材料呈现出 MMT和PPy的红外特征吸收峰,但某些吸收峰出现蓝移。SEM 观察显示MMT/PPy呈片状形态特征。当其中的MMT去除后,PPy仍为片状结构,与纯 PPy的球粒形貌不同。电导率测试表明,MMT/PPy复合材料的电导率随PPy含量增加而提高,至40.9 wt% PPy含量时,MMT/PPy的电导率已达到PPy 的电导率水平(10-1S/cm),含54.3 wt% PPy的MMT/PPy电导率甚至略高于PPy。Abstract: A serial montmorillonite (MMT)/polypyrrole (PPy) composites (MMT/PPy) were prepared by vapor-liquor phase polymerization of pyrrole vapor with Fe3+ impregnated MMT suspension. It was found that the polymerization of pyrrole took place within the silicate layers of MMT. XRD of MMT/PPy composites showed that the basal spacing of MMT layers increased with increasing the PPy content. FTIR of MMT/PPy exhibited both characteristic adsorption peaks of MMT and PPy,while some peaks appeared blue shift. The obtained MMT/PPy displayed flake like morphology. Even after etching of MMT from MMT/PPy by HF,the resultant PPy still displayed a flake-like morphology,which was very different from the inherent globular PPy obtained by the same method. The conductivity of MMT/PPy became higher with increment of the PPy content. When the PPy content reached 40.9 wt%,the composite possessed almost the same conductivity as PPy. Furthermore,the composite containing 54.3 wt% PPy even showed a higher conductivity than PPy. This phenomenon might be attributed to the special morphology of the PPy in composite,which was caused by in situ polymerization within a confined space of MMT layers.
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Key words:
- polypyrrole /
- montmorillonite /
- nano composite /
- intercalation /
- vapor-liquor phase polymerization
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