Structure and properties of in-situ modified monodisperse SiO2/natural rubber composite by coupling agent Si747
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摘要: 采用偶联剂Si747在液相体系中分别对自制单分散白炭黑(SiO2)和市售沉淀法白炭黑(SiO2)表面进行改性,利用乳液共混技术制备SiO2/天然橡胶(NR)复合材料。利用橡胶加工分析仪、DMA、SEM等测试手段对偶联剂Si747改性SiO2/NR复合材料的结构和性能进行表征。结果表明,在硫化特性方面,与未改性SiO2相比,偶联剂Si747改性SiO2/NR复合材料的焦烧时间和工艺正硫化时间均缩短,促进了橡胶的硫化过程,其中改性前后单分散SiO2/NR硫化胶的焦烧时间和工艺正硫化时间均比沉淀法SiO2/NR硫化胶长;与未改性单分散SiO2/NR硫化胶相比,改性单分散SiO2/NR硫化胶的拉伸强度提高了17.4%,回弹性和耐磨性分别提高了9.5%和32.6%,压缩生热降低了24.3%;与改性沉淀法SiO2/NR硫化胶相比,改性单分散SiO2/NR硫化胶的Payne效应最低,填料的分散性更高,填料网络结构更弱;改性单分散SiO2/NR硫化胶抗湿滑性略低于改性沉淀法SiO2/NR硫化胶,但滚动阻力更低,更节省能源。Abstract: The monodisperse and precipitated silica (SiO2) were modified by coupling agent Si747 in liquid phase and the SiO2/natural rubber (NR) composites were prepared by latex compounding technology. The structure and properties of Si747-modified SiO2/NR composites were characterized by rubber process analyzer, DMA and SEM. The results show that in terms of the vulcanization characteristics, compared with the unmodified SiO2, the scorch time and the positive vulcanization time of the composites obtained by using coupling agent Si747 modified SiO2 and NR are shortened, which promoted the vulcanization process of rubber. The scorch time and the positive vulcanization time of the monodisperse SiO2/NR vulcanizates were longer than that of the precipitated SiO2/NR vulcanizates before and after SiO2 modification; Considering the physical and mechanical properties, compared with unmodified SiO2/NR vulcanizate, the tensile strength of the modified monodisperse SiO2/NR vulcanizate is increased by 17.4%. The resilience and wear resistance are improved by 9.5% and 32.6%, respectively. The heat-build up is reduced by 24.3%. In terms of dynamic viscoelasticity, the modified monodisperse SiO2/NR vulcanizate has the lower Payne effect, the better dispersibility of the filler and the weaker filler network compared with the modified precipitated SiO2/NR vulcanizate. In terms of dynamic mechanical properties, the performance in wet-slip resistance of modified monodisperse SiO2/NR vulcanizate is slightly lower than that of the modified precipitated SiO2/NR vulcanizate, but the rolling resistance is much better than the latter and saves more energy.
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Key words:
- coupling agent Si747 /
- in-situ modification /
- monodisperse SiO2 /
- precipitated SiO2 /
- natural rubber
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