Fabrication and microwave absorbing properties of CCB@Fe<sub>3</sub>O<sub>4</sub>/ NR absorbing films

SHEN Yongqian; ZHANG Fan; ZHU Jian; LONG Jian; GAO Feng; DU Xueyan

doi:10.13801/j.cnki.fhclxb.20230109.002

Volume 40 Issue 9

Sep. 2023

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SHEN Yongqian, ZHANG Fan, ZHU Jian, et al. Fabrication and microwave absorbing properties of CCB@Fe3O4/ NR absorbing films[J]. Acta Materiae Compositae Sinica, 2023, 40(9): 5145-5157. doi: 10.13801/j.cnki.fhclxb.20230109.002

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SHEN Yongqian, ZHANG Fan, ZHU Jian, et al. Fabrication and microwave absorbing properties of CCB@Fe₃O₄/ NR absorbing films[J]. Acta Materiae Compositae Sinica, 2023, 40(9): 5145-5157. doi: 10.13801/j.cnki.fhclxb.20230109.002

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Fabrication and microwave absorbing properties of CCB@Fe₃O₄/ NR absorbing films

doi: 10.13801/j.cnki.fhclxb.20230109.002

1.
College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2.
Shouhang Hi-Tech Energy Technology CO., LTD., Jiuquan 735000, China

Funds: China Postdoctoral Science Foundation (2022 MD713777); Natural Science Foundation of Gansu Province (21 JR7 RA223); National Natural Science Foundation of China-Joint Fund Project (U22 A20175)

More Information

Corresponding author: SHEN Yongqian, ZHANG Fan, ZHU Jian, et al. Fabrication and microwave absorbing properties of
Received Date: 2022-09-28
Accepted Date: 2022-12-26
Rev Recd Date: 2022-12-22

Available Online: 2023-01-10

Publish Date: 2023-09-15

Abstract

Abstract

Exploring electromagnetic wave (EMW) absorbing materials with excellent performance is the main method to solve electromagnetic pollution. However, it remains a challenge to meet the high performance and practical application requirements of materials simultaneously. Conductive carbon black (CCB)@nano Fe₃O₄/natural rubber (NR) absorbing films with excellent mechanical and EMW absorption properties were prepared by sol-gel method, plasticizing, blending and vulcanization, and the mechanical and EMW absorbing properties of the films were controlled by adjusting the addition amount of CCB@Fe₃O₄. The introduction of the CCB@Fe₃O₄ composites greatly ameliorates the interfacial loss and polarization loss of the films, in which the CCB can enhance the mechanical properties while improving the dielectric constant and conductivity of the materials. The film achieves the minimum reflection loss (RL) of -40.5 dB and maximum effective absorption bandwidth (EAB) of 2.4 GHz with the thickness of 5.0 mm when the CCB@Fe₃O₄ was added at 29wt%, and exhibited the optimal tensile strength, hardness and wear properties. The remarkable EMW absorbing properties of the material originate from impedance matching, strong EMW attenuation and high conduction loss caused by the synergistic effect of dielectric-magnetic loss. This work provides a new mentality for the structure design and practical application of natural rubber-based absorbing films.
- electromagnetic wave absorption material,
- natural rubber,
- nano ferroferric oxide,
- conductive carbon black,
- dielectric-magnetic synergistic effect
Long Abstrsct
Innovation Points

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References

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