Preparation of calcium hydroxystannate coated by hydroxyapatite hybrid micro-nano flame retardant and its flame retardant properties

WANG Zenghao; MA Yiheng; LOU Yuanmeng; DONG Luming; MA Haiyun

doi:10.13801/j.cnki.fhclxb.20220630.004

Volume 40 Issue 5

May 2023

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Article Navigation > Acta Materiae Compositae Sinica > 2023 > 40(5): 2699-2708

WANG Zenghao, MA Yiheng, LOU Yuanmeng, et al. Preparation of calcium hydroxystannate coated by hydroxyapatite hybrid micro-nano flame retardant and its flame retardant properties[J]. Acta Materiae Compositae Sinica, 2023, 40(5): 2699-2708. doi: 10.13801/j.cnki.fhclxb.20220630.004

Citation:

WANG Zenghao, MA Yiheng, LOU Yuanmeng, et al. Preparation of calcium hydroxystannate coated by hydroxyapatite hybrid micro-nano flame retardant and its flame retardant properties[J]. Acta Materiae Compositae Sinica, 2023, 40(5): 2699-2708. doi: 10.13801/j.cnki.fhclxb.20220630.004

Citation:

WANG Zenghao, MA Yiheng, LOU Yuanmeng, et al. Preparation of calcium hydroxystannate coated by hydroxyapatite hybrid micro-nano flame retardant and its flame retardant properties[J]. Acta Materiae Compositae Sinica, 2023, 40(5): 2699-2708. doi: 10.13801/j.cnki.fhclxb.20220630.004

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Preparation of calcium hydroxystannate coated by hydroxyapatite hybrid micro-nano flame retardant and its flame retardant properties

doi: 10.13801/j.cnki.fhclxb.20220630.004

1.
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
2.
Key Laboratory of Analytical Science and Technology of Hebei Province, Hebei University, Baoding 071002, China
3.
The Flame Retardant Material and Processing Technology Engineering Research Center of Hebei Province, Baoding 071002, China

Funds: National Natural Science Foundation of China (52173073)

Received Date: 2022-05-05
Accepted Date: 2022-06-24
Rev Recd Date: 2022-06-22

Available Online: 2022-07-01

Publish Date: 2023-05-15

Abstract

Abstract

Hydroxystannate is a novel flame retardant aroused in recent years. In this study, starting from the flame retardant design, submicron calcium hydroxystannate (CSH) cubes were synthesized by chemical co-precipitation method, and then were rapidly in-situ coated by hydroxyapatite (HA) in simulated body fluid with high concentrations. Finally, the hybrid CSH@HA micro-nano particles were prepared and applied to the flame retardant flexible polyvinyl chloride (PVC). The results show that CSH@HA exhibits excellent flame retardancy on PVC. A very small amount of CSH@HA can significantly increase the limit oxygen index (LOI) value, and reduce the heat release rate, total heat release, total smoke release and CO production during combustion of PVC. By reacting with HCl generated during the degradation of PVC, CSH@HA protects the inner CSH and promotes more PVC into stable chars. The low loading of CSH@HA also improves the toughness of PVC while maintaining the mechanical properties. The CSH@HA hybrid flame retardant obtained in this paper pave a new way to the development of novel flame retardants.
- calcium hydroxystannate,
- hydroxyapatite,
- flame retardant mechanism,
- composite,
- carbonization
Long Abstrsct
Innovation Points

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References(36)

References

[1]	LEVCHIK S V, WEIL E D. Overview of the recent literature on flame retardancy and smoke suppression in PVC[J]. Polymers for Advanced Technologies,2005,16(10):707-716. doi: 10.1002/pat.645
[2]	PAN Y T, YUAN Y S, WANG D Y, et al. An overview of the flame retardants for poly(vinyl chloride): Current states and perspective[J]. Chinese Journal of Chemistry,2020,38(12):1870-1896. doi: 10.1002/cjoc.202000375
[3]	尚松川, 杨保俊, 张睿辰, 等. Sb₂O₃-ZnMgAl类水滑石的制备及其在软聚氯乙烯阻燃中的应用[J]. 复合材料学报, 2017, 34(8):1667-1673. SHANG Songchuan, YANG Baojun, ZHANG Ruichen, et al. Preparation of Sb₂O₃-LDHs and its assisting flame retardant effects on soft polyvinyl chloride[J]. Acta Materiae Compositae Sinica,2017,34(8):1667-1673(in Chinese).
[4]	MEHTA B, KATHALEWAR M, SABNIS A. Diester based on castor oil fatty acid as plasticizer for poly(vinyl chloride)[J]. Journal of Applied Polymer Science,2014,131(11):1-8.
[5]	QU H Q, WU W H, XIE J X, et al. A novel intumescent flame retardant and smoke suppression system for flexible PVC[J]. Polymers for Advanced Technologies,2011,22(7):1174-1181. doi: 10.1002/pat.1934
[6]	GIORGIO Z, SERGIO B, TIZIANA B, et al. Safer plasticized polyvinyl chloride synthetic leathers for the automotive industry: Evaluation of alternatives to antimony compounds as flame retardants[J]. Polymer Engineering and Science,2019,59(12):2488-2497. doi: 10.1002/pen.25121
[7]	NING Y, GUO S Y. Flame-retardant and smoke-suppressant properties of zinc borate and aluminum trihydrate-filled rigid PVC[J]. Journal of Applied Polymer Science,2000,77(14):3119-3127. doi: 10.1002/1097-4628(20000929)77:14<3119::AID-APP130>3.0.CO;2-N
[8]	LU Y H, WU C F, XU S A. Mechanical, thermal and flame retardant properties of magnesium hydroxide filled poly(vinyl chloride) composites: The effect of filler shape[J]. Composites Part A: Applied Science and Manufacturing,2018,113:1-11. doi: 10.1016/j.compositesa.2018.07.012
[9]	GREEN J. Mechanisms for flame retardancy and smoke suppression—A review[J]. Journal of Fire Sciences,1996,14(6):426-442. doi: 10.1177/073490419601400602
[10]	QU H Q, WU W H, ZHENG Y J, et al. Synergistic effects of inorganic tin compounds and Sb₂O₃ on thermal properties and flame retardancy of flexible poly(vinyl chloride)[J]. Fire Safety Journal,2011,46(7):462-467. doi: 10.1016/j.firesaf.2011.07.006
[11]	ZHANG B, JIAO Y H, XU J Z. A study on the flame-retardance of poly(vinyl chloride) incorporated with metal hydroxystannates[J]. Journal of Applied Polymer Science,2009,112(1):82-88. doi: 10.1002/app.29404
[12]	ZHANG Z D, LI X L, YUAN Y S, et al. Confined dispersion of zinc hydroxystannate nanoparticles into layered bimetallic hydroxides nanocapsules and its application in flame retardant epoxy nanocomposites[J]. ACS Applied Materials & Interfaces,2019,11(43):40951-40960.
[13]	LONG M Y, PENG S, DENG W S, et al. A robust superhydrophobic PDMS@ZnSn(OH)₆ coating with under-oil self-cleaning and flame retardancy[J]. Journal Materials Chemistry A,2017,5(43):22761-22771. doi: 10.1039/C7TA06190K
[14]	WANG B B, SHENG H B, SHI Y Q, et al. The influence of zinc hydroxystannate on reducing toxic gases (CO, NO_x and HCN) generation and fire hazards of thermoplastic polyurethane composites[J]. Journal of Hazardous Materials,2016,314:260-269. doi: 10.1016/j.jhazmat.2016.04.029
[15]	LI P P, ZHENG Y P, LI M Z, et al. Enhanced flame-retardant property of epoxy composites filled with solvent-free and liquid-like graphene organic hybrid material decorated by zinc hydroxystannate boxes[J]. Composites Part A: Applied Science and Manufacturing,2016,81:172-181. doi: 10.1016/j.compositesa.2015.11.013
[16]	李志伟, 黄永山, 李小红, 等. 一种新型ZHS-MF复合阻燃剂的制备及其在软质PVC中的应用[J]. 复合材料学报, 2013, 30(4):29-34. doi: 10.13801/j.cnki.fhclxb.2013.04.010 LI Zhiwei, HUANG Yongshan, LI Xiaohong, et al. Preparation of a novel ZHS-MF composite flame retardant and its application in flexible poly(vinyl chloride)[J]. Acta Materiae Compositae Sinica,2013,30(4):29-34(in Chinese). doi: 10.13801/j.cnki.fhclxb.2013.04.010
[17]	HUO Z Y, WU H J, SONG Q G, et al. Synthesis of zinc hydroxystannate/reduced graphene oxide composites using chitosan to improve poly(vinyl chloride) performance[J]. Carbohydrate Polymers,2021,256:117575. doi: 10.1016/j.carbpol.2020.117575
[18]	XU W Z, CHEN R, XU J Y, et al. Nickel hydroxide and zinc hydroxystannate dual modified graphite carbon nitride for the flame retardancy and smoke suppression of epoxy resin[J]. Polymer Degradation and Stability,2020,182:109366. doi: 10.1016/j.polymdegradstab.2020.109366
[19]	张冲, 耿晓维, 高香迪, 等. 环交联聚磷腈包覆羟基锡酸锶杂化纳米棒的合成及阻燃环氧树脂研究[J]. 无机材料学报, 2019, 34(7):761-767. doi: 10.15541/jim20180493 ZHANG Chong, GENG Xiaowei, GAO Xiangdi, et al. Synthesis of cyclic crosslinked polyphosphazene coated strontium hydroxystannate hybrid nanorods and research on flame retardant epoxy resin[J]. Journal of Inorganic Materials,2019,34(7):761-767(in Chinese). doi: 10.15541/jim20180493
[20]	ZHANG C, GUO X D, MA S M, et al. Strontium hydroxystannate nanorods encapsulated by hybrid polyphosphazene: Synthesis and flame retardancy on epoxy resin[J]. Materials Letters,2018,229:297-300. doi: 10.1016/j.matlet.2018.07.047
[21]	胡伟东, 赵贺, 焦运红, 等. 羟基锡酸钴在软质聚氯乙烯中的高效阻燃消烟作用[J]. 复合材料学报, 2019, 36(9):2067-2075. HU Weidong, ZHAO He, JIAO Yunhong, et al. High efficient flame retardancy and smoke suppression effect of cobalt hydroxystannate on flexible polyvinyl chloride[J]. Acta Materiae Compositae Sinica,2019,36(9):2067-2075(in Chinese).
[22]	董璐铭, 苏衍跃, 王春征, 等. 微纳米钙钛矿型羟基锡酸钙的合成及对环氧树脂的阻燃性能[J]. 高等学校化学学报, 2021, 42(3):937-945. DONG Luming, SU Yanyue, WANG Chunzheng, et al. Synthesis of micro- to nano-scale perovskite calcium hydroxystannate and its performance as a flame retardant in epoxy resin[J]. Chemical Journal of Chinese Universities,2021,42(3):937-945(in Chinese).
[23]	DONG L M, SU Y Y, QIAO Y F, et al. Structure regulation of boron-doped calcium hydroxystannate and its enhancement on flame retardancy and mechanical properties of PVC[J]. Polymers for Advanced Technologies,2021,32(4):1831-1843. doi: 10.1002/pat.5224
[24]	YANG D Q, ZHANG C, DONG L M, et al. Synthesis and properties of SrSn(OH)₆ nanorods and their flame retardancy and smoke suppression effects on epoxy resin[J]. Journal of Coatings Technology and Research,2019,16(6):1715-1725. doi: 10.1007/s11998-019-00254-x
[25]	FIUME E, MAGNATERRA G, RAHDAR A, et al. Hydroxyapatite for biomedical applications: A short overview[J]. Ceramics,2021,4(4):542-563. doi: 10.3390/ceramics4040039
[26]	ZHU J D, XIONG R J, ZHAO F X, et al. Lightweight, high-strength, and anisotropic structure composite aerogel based on hydroxyapatite nanocrystal and chitosan with thermal insulation and flame retardant properties[J]. ACS Sustainable Chemistry & Engineering, 2019, 8(1): 71-83.
[27]	CHEN F F, ZHU Y J, XIONG Z C, et al. Hydroxyapatite nanowire-based all-weather flexible electrically conduc-tive paper with superhydrophobic and flame-retardant properties[J]. ACS Applied Materials & Interfaces,2017,9(45):39534-39548.
[28]	VAHABI H, SHABANIAN M, ARYANASAB F, et al. Inclusion of modified lignocellulose and nano-hydroxyapatite in development of new bio-based adjuvant flame retardant for poly(lactic acid)[J]. Thermochimica Acta,2018,666:51-59. doi: 10.1016/j.tca.2018.06.004
[29]	DEMIRTAS T T, KAYNAK G, GÜMÜSDERELIOGLU M. Bone-like hydroxyapatite precipitated from 10×SBF-like solution by microwave irradiation[J]. Materials Science and Engineering: C,2015,49:713-719. doi: 10.1016/j.msec.2015.01.057
[30]	中国国家标准化管理委员会. 塑料用氧指数法测定燃烧行为第2部分: 室温试验: GB/T 2406.1—2008[S]. 北京: 中国标准出版社, 2008. Standardization Administration of the People's Republic of China. Plastics: Determination of burning behaviour by oxygen index Part 2: Ambient temperature test: GB/T 2406.1—2008[S]. Beijing: China Standards Press, 2008(in Chinese).
[31]	中国国家标准化管理委员会. 塑料燃烧性能的测定水平法和垂直法: GB/T 2408—2008[S].北京: 中国标准出版社, 2009. Standardization Administration of the People's Republic of China. Plastics: Determination of burning characteristics: Horizontal and vertical test: GB/T 2408—2008[S]. Beijing: China Standards Press, 2009(in Chinese).
[32]	ASTM Committee. Standard test method for tensile properties of plastics: ASTM D638-14[S]. West Conshohocken: ASTM International, 2014.
[33]	SANDESH S, KRISTACHAR P K R, MANJUNATHAN P, et al. Synthesis of biodiesel and acetins by transesterification reactions using novel CaSn(OH)₆ heterogeneous base catalyst[J]. Applied Catalysis A: General,2016,523:1-11. doi: 10.1016/j.apcata.2016.05.006
[34]	陈景帝, 王迎军, 魏坤, 等. 羟基磷灰石的可控制备及其研究[J]. 材料科学与工艺, 2007, 4(4):515-518. doi: 10.3969/j.issn.1005-0299.2007.04.019 CHEN Jingdi, WANG Yingjun, WEI Kun, et al. Synthesis and characterization of nano hydroxyapatite particles[J]. Materials Science and Technology,2007,4(4):515-518(in Chinese). doi: 10.3969/j.issn.1005-0299.2007.04.019
[35]	贺梦, 张冲, 郭晓东, 等. 含硫功能聚磷腈微纳米球的合成及其在环氧树脂阻燃中的应用[J]. 复合材料学报, 2019, 36(3):584-591. doi: 10.13801/j.cnki.fhclxb.20180711.001 HE Meng, ZHANG Chong, GUO Xiaodong, et al. Synthesis of sulfur containing polyphosphazene micro-nano sphere and its application in flame retarded epoxy resin[J]. Acta Materiae Compositae Sinica,2019,36(3):584-591(in Chinese). doi: 10.13801/j.cnki.fhclxb.20180711.001
[36]	HAJIBEYGI M, MALEKI M, SHABANIAN M, et al. New polyvinyl chloride (PVC) nanocomposite consisting of aromatic polyamide and chitosan modified ZnO nanoparticles with enhanced thermal stability, low heat release rate and improved mechanical properties[J]. Applied Surface Science,2018,439:1163-1179. doi: 10.1016/j.apsusc.2018.01.255