Influence of nano-SiO<sub>2</sub> dispersion on the direct current dielectric properties of SiO<sub>2</sub>/LDPE nanocomposite

ZHENG Changji; WANG Bo; YANG Jiaming; ZHAO Hong

doi:10.13801/j.cnki.fhclxb.20220428.002

Volume 40 Issue 3

Mar. 2023

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Article Navigation > Acta Materiae Compositae Sinica > 2023 > 40(3): 1417-1429

ZHENG Changji, WANG Bo, YANG Jiaming, et al. Influence of nano-SiO2 dispersion on the direct current dielectric properties of SiO2/LDPE nanocomposite[J]. Acta Materiae Compositae Sinica, 2023, 40(3): 1417-1429. doi: 10.13801/j.cnki.fhclxb.20220428.002

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ZHENG Changji, WANG Bo, YANG Jiaming, et al. Influence of nano-SiO₂ dispersion on the direct current dielectric properties of SiO₂/LDPE nanocomposite[J]. Acta Materiae Compositae Sinica, 2023, 40(3): 1417-1429. doi: 10.13801/j.cnki.fhclxb.20220428.002

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Influence of nano-SiO₂ dispersion on the direct current dielectric properties of SiO₂/LDPE nanocomposite

doi: 10.13801/j.cnki.fhclxb.20220428.002

Key Laboratory of Engineering Dielectrics and Their Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China

Received Date: 2022-02-28
Accepted Date: 2022-04-19
Rev Recd Date: 2022-04-15

Available Online: 2022-04-29

Publish Date: 2023-03-15

Abstract

Abstract

The dielectric properties of SiO₂/low-density polyethylene (LDPE) composites are closely related to the dispersion of nano-SiO₂ in LDPE matrix. In order to study the mechanism of tensile treatment on the dispersion of nano-silica particles in the LDPE matrix at room temperature, a hydrophobic nano-SiO₂ with a particle size of 7 nm was selected to be fused and blended with LDPE to prepare SiO₂/LDPE nanocomposites. The prepared nanocomposites were stretched three times, and the dispersion of nanoparticles and the crystallinity of the composites were characterized by SEM and DSC, the trap energy levels and trap densities of the composites were analyzed by thermally stimulated galvanometry (TSC). The effects of stretching on the dispersion of nanoparticles and the resulting changes in direct current dielectric properties were investigated by experimentally testing the space charge, electrical conductivity, and direct current breakdown strength of the nanocomposites. The results show that stretching at room temperature helps the dispersion of nanoparticles and reduce the agglomeration size of nano-SiO₂ particles from about 200 nm to about 100 nm. However, stretching will destroy the crystal structure of LDPE and deteriorate its properties; The DC dielectric properties of LDPE can be improved by introducing deep trap levels by doping nano-SiO₂.The space charge accumulation of the stretched SiO₂/LDPE is suppressed, and the mechanism of conducting current is changed. By fitting the conductance current data, it is found that the conductance of the stretched SiO₂/LDPE is dominated by ion hopping conductance, and its hopping distance is reduced to about 1.98 nm. Compared with LDPE, the DC breakdown field strength of SiO₂/LDPE is improved by about 43%, The main reason for the decrease of the breakdown strength of SiO₂/LDPE after stretching at room temperature is the structural defects of the LDPE matrix caused by the stretching process.
- SiO₂/LDPE,
- room temperature stretching,
- dispersion,
- space charge,
- conductance,
- breakdown strength
Long Abstrsct
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References

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