Graphene-enhanced electromagnetic wave absorbing properties of FeSiAl-MoS<sub>2</sub>/PLA composites

YE Xicong; YANG Chao; OUYANG Bin; GAO Qi; WU Haihua; HE Enyi; YE Yongsheng

doi:10.13801/j.cnki.fhclxb.20220415.004

Volume 40 Issue 2

Feb. 2023

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Article Navigation > Acta Materiae Compositae Sinica > 2023 > 40(2): 911-928

YE Xicong, YANG Chao, OUYANG Bin, et al. Graphene-enhanced electromagnetic wave absorbing properties of FeSiAl-MoS2/PLA composites[J]. Acta Materiae Compositae Sinica, 2023, 40(2): 911-928. doi: 10.13801/j.cnki.fhclxb.20220415.004

Citation:

YE Xicong, YANG Chao, OUYANG Bin, et al. Graphene-enhanced electromagnetic wave absorbing properties of FeSiAl-MoS₂/PLA composites[J]. Acta Materiae Compositae Sinica, 2023, 40(2): 911-928. doi: 10.13801/j.cnki.fhclxb.20220415.004

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Graphene-enhanced electromagnetic wave absorbing properties of FeSiAl-MoS₂/PLA composites

doi: 10.13801/j.cnki.fhclxb.20220415.004

YE Xicong^{1, 2
,
,},
YANG Chao²,
OUYANG Bin²,
GAO Qi²,
WU Haihua^{1, 2},
HE Enyi^{1, 2},
YE Yongsheng^{1, 2}

1.
Hubei Engineering Research Center for Graphite Additive Manufacturing Technology and Equipment, China Three Gorges University, Yichang 443002, China
2.
College of Mechanical & Power Engineering, China Three Gorges University, Yichang 443002, China

Funds: National Natural Science Foundation of China (51575313); Open Fund of Hubei Engineering Research Center for Graphite Additive Manufacturing Technology and Equipment of China Three Gorges University (HRCGAM202101)

Received Date: 2022-01-14
Accepted Date: 2022-04-06
Rev Recd Date: 2022-04-02

Available Online: 2022-04-19

Publish Date: 2023-02-01

Abstract

Abstract

Multi-material composite is an effective method to prepare light-weight, broadband and strong absorbing materials. In this paper, polylactic acid (PLA) was used as the matrix material, and FeSiAl, MoS₂ and graphene (GN) were used as fillers. FeSiAl-MoS₂-GN/PLA composites, which were used for fused deposition modeling (FDM), prepared by the two-step process of ball milling and melt extrusion. The phase structure, microscopic morphology and electromagnetic properties of composites were characterized by XRD, Raman spectroscopy, SEM and vector network analyzer, respectively. And the effect of graphene content on the electromagnetic wave absorbing properties of composites was also investigated. The research shows that graphene, FeSiAl and MoS₂ are randomly dispersed in the PLA matrix and form a complex conductive network; Multi-material composites build rich dielectric/magnetic heterointerfaces, which are beneficial to promote interface polarization; The higher the graphene content, the stronger the electromagnetic wave absorbing properties of composites; When the graphene content is 5wt%, the minimum reflection loss is −27.90 dB at a thickness of 1.7 mm, and the effective absorption bandwidth is 4.96 GHz (12.64-17.60 GHz) at a thickness of 1.9 mm. Its excellent absorbing properties are attributed to the perfect impedance matching and the synergy between dielectric and magnetic losses.
- composites,
- FeSiAl,
- MoS₂,
- graphene,
- impedance matching,
- electromagnetic wave absorbing pro-perties
Long Abstrsct
Innovation Points

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References(55)

References

[1]	CHENG J Y, ZHANG H B, XIONG Y F, et al. Construction of multiple interfaces and dielectric/magnetic heterostructures in electromagnetic wave absorbers with enhanced absorption performance: A review[J]. Journal of Materiomics,2021,7(6):1233-1263. doi: 10.1016/j.jmat.2021.02.017
[2]	RUSAKOVA A, NOSACHEV I, LYSENKO V, et al. Impact of high strength electromagnetic fields generated by Tesla transformer on plant cell ultrastructure[J]. Information Processing in Agriculture,2017,4(3):253-258. doi: 10.1016/j.inpa.2017.05.002
[3]	TAO J Q, ZHOU J T, YAO Z J, et al. Multi-shell hollow porous carbon nanoparticles with excellent microwave absorption properties[J]. Carbon,2021,172:542-555. doi: 10.1016/j.carbon.2020.10.062
[4]	ZENG X J, CHENG X Y, YU R H, et al. Electromagnetic microwave absorption theory and recent achievements in microwave absorbers[J]. Carbon,2020,168:606-623. doi: 10.1016/j.carbon.2020.07.028
[5]	LIU D, ZHANG Y, ZHOU C, et al. A facile strategy for the core-shell FeSiAl composites with high-efficiency electromagnetic wave absorption[J]. Journal of Alloys and Compounds,2020,818:152861. doi: 10.1016/j.jallcom.2019.152861
[6]	ZHANG Y, ZHOU T D. Structure and electromagnetic pro-perties of FeSiAl particles coated by MgO[J]. Journal of Magnetism and Magnetic Materials,2017,426:680-684. doi: 10.1016/j.jmmm.2016.10.144
[7]	ZHOU L, XU H, SU G X, et al. Tunable electromagnetic and broadband microwave absorption of SiO₂-coated FeSiAl absorbents[J]. Journal of Alloys and Compounds,2021,861:157966. doi: 10.1016/j.jallcom.2020.157966
[8]	LEI C L, GE C N, GE X, et al. Enhanced microwave absorption of flaky FeSiAl/ZnO composites fabricated via precipitation[J]. Materials Science & Engineering B,2022,275:115502.
[9]	TIAN W, ZHANG X Z, GUO Y, et al. Hybrid silica-carbon bilayers anchoring on FeSiAl surface with bifunctions of enhanced anti-corrosion and microwave absorption[J]. Carbon,2021,173:185-193. doi: 10.1016/j.carbon.2020.11.002
[10]	贾琨, 王东红, 李克训, 等. 石墨烯复合吸波材料的研究进展及未来发展方向[J]. 材料导报, 2019, 33(5):805-811. doi: 10.11896/cldb.201905012 JIA Kun, WANG Donghong, LI Kexun, et al. Progress and future developments of graphene composites serving as microwave absorbing materials[J]. Materials Reports,2019,33(5):805-811(in Chinese). doi: 10.11896/cldb.201905012
[11]	谢文瀚, 耿浩然, 柳扬, 等. MoS₂/生物质碳复合材料的制备与吸波性能[J]. 复合材料学报, 2022, 39(5): 2211-2221. XIE Wenhan, GENG Haoran, LIU Yang, et al. Preparation and microwave absorbing properties of MoS₂/biomass carbon composite[J]. Acta Materiae Compositae Sincia, 2022, 39(5): 2211-2221(in Chinese).
[12]	SONG Q, YE F, KONG L, et al. Graphene and MXene nanomaterials: Toward high-performance electromagnetic wave absorption in gigahertz band range[J]. Advanced Functional Materials,2020,30(31):2000475. doi: 10.1002/adfm.202000475
[13]	WANG Y, CHEN D, YIN X, et al. Hybrid of MoS₂ and reduced graphene oxide: A lightweight and broadband electromagnetic wave absorber[J]. ACS Applied Materials & Interfaces,2015,7:26226-26234.
[14]	WANG J N, WANG Q J, WANG W, et al, Hollow Ni/C microsphere@graphene foam with dual-spatial and porous structure on the microwave absorbing performance[J]. Journal of Alloys and Compounds, 2021, 873: 159811.
[15]	LI M, CAO X, ZHENG S, et al. Ternary composites RGO/MoS₂@Fe₃O₄: Synthesis and enhanced electromagnetic wave absorbing performance[J]. Journal of Materials Science Materials in Electronics,2017,28(22):16802-16812. doi: 10.1007/s10854-017-7595-x
[16]	ZHANG H X, SHI C, JIA Z R, et al. FeNi nanoparticles embedded reduced graphene/nitrogen-doped carbon composites towards the ultra-wideband electromagnetic wave absorption[J]. Journal of Colloid and Interface Science,2021,584:382-394. doi: 10.1016/j.jcis.2020.09.122
[17]	吴海华, 胡正浪, 李雨恬, 等. 铁镍合金/聚乳酸复合材料的熔融沉积成形制备及其电磁吸收性能和力学性能[J]. 复合材料学报, 2022, 39(1):158-168. WU Haihua, HU Zhenglang, LI Yutian, et al. Electromagnetic absorption properties and mechanical properties of Fe-Ni alloy/polylactic acid composites fabricated by fused deposition modeling[J]. Acta Materiae Compositae Sinica,2022,39(1):158-168(in Chinese).
[18]	叶喜葱, 欧阳宾, 杨超, 等. 石墨烯-羰基铁粉线材的制备及其吸波性能分析[J]. 复合材料学报, 2022, 39(7):3292-3302. YE Xicong, OUYANG Bin, YANG Chao, et al. Preparation of graphene carbonyl iron powder wire and analysis of its wave absorption performance[J]. Acta Materiae Compositae Sinica,2022,39(7):3292-3302(in Chinese).
[19]	胡正浪, 吴海华, 杨增辉, 等. 石墨烯-铁镍合金-聚乳酸复合材料的制备及其吸波性能[J]. 复合材料学报, 2022, 39(7):3303-3316. HU Zhenglang, WU Haihua, YANG Zenghui, et al. Preparation of graphene-iron-nickel alloy-polylactic acid compo-sites and their microwave absorption properties[J]. Acta Materiae Compositae Sinica,2022,39(7):3303-3316(in Chinese).
[20]	中国国家标准化管理委员会. 塑料拉伸性能的测定: GB/T 1040—2006[S]. 北京: 中国标准出版社, 2006. Standardization Administration of the People’s Republic of China. Plastics: Determination of tensile properties: GB/T 1040—2006[S]. Beijing: China Standards Press, 2006(in Chinese).
[21]	ZHANG M, QIAN X, ZENG Q W, et al. Hollow microspheres of polypyrrole/magnetite/carbon nanotubes by spray-dry as an electromagnetic synergistic microwave absorber[J]. Carbon,2021,175:499-508. doi: 10.1016/j.carbon.2021.01.013
[22]	XIANG Z, HUANG C, SONG Y M, et al. Rational construction of hierarchical accordion-like Ni@porous carbon nanocomposites derived from metal-organic frameworks with enhanced microwave absorption[J]. Carbon,2020, 167:364-377.
[23]	YANG K, CUI Y H, LIU Z H, et al. Design of core-shell structure NC@MoS₂ hierarchical nanotubes as high-perfor-mance electromagnetic wave absorber[J]. Chemical Engi-neering Journal,2021,426(1):131308.
[24]	SHU R W, WAN Z L, ZHANG J B, et al. Synergistically assembled nitrogen-doped reduced graphene oxide/multi-walled carbon nanotubes composite aerogels with superior electromagnetic wave absorption performance[J]. Composites Science and Technology,2021,210:108818. doi: 10.1016/j.compscitech.2021.108818
[25]	DI X C, WANG Y, LU Z, et al. Heterostructure design of Ni/C/porous carbon nanosheet composite for enhancing the electromagnetic wave absorption[J]. Carbon,2021,179:566-578. doi: 10.1016/j.carbon.2021.04.050
[26]	GAO J, DING Q, YAN P, et al. Highly improved microwave absorbing and mechanical properties in cold sintered ZnO by incorporating graphene oxide[J]. Journal of the European Ceramic Society,2022,42(3):993-1000. doi: 10.1016/j.jeurceramsoc.2021.10.053
[27]	YAN F, ZHANG S, ZHANG X, et al. Growth of CoFe₂O₄ hollow nanoparticles on graphene sheets for high-performance electromagnetic wave absorbers[J]. Journal of Materials Chemistry C,2018,6(47):12781-12787. doi: 10.1039/C8TC04222E
[28]	XU Z, DU Y, LIU D, et al. Pea-like Fe/Fe₃C nanoparticles embedded in nitrogen-doped carbon nanotubes with tunable dielectric/magnetic loss and efficient electromagnetic absorption[J]. ACS Applied Materials & Interfaces,2019,11(14):4268-4277.
[29]	朱晓宇, 邱红芳, 陈平. Co@CNT复合电磁波吸收剂的制备及其吸波性能[J]. 材料研究学报, 2021, 35(11):811-819. ZHU Xiaoyu, QIU Hongfang, CHEN Ping. Preparation and electromagnetic wave absorbing properties of composites of cobalt coated graphitic carbon nitride Co@CNTs[J]. Chinese Journal of Materials Research,2021,35(11):811-819(in Chinese).
[30]	王建江, 蔡旭东, 温晋华, 等. FeSiAl软磁合金空心微珠的微观结构控制及其低频吸波性能[J]. 稀有金属材料与工程, 2018, 47(10):3072-3079. WANG Jianjiang, CAI Xudong, WEN Jinhua, et al. Microstructure control of FeSiAl magnetically soft alloy hollow microspheres and their microwave absorption properties at low frequency[J]. Rare Metal Materials and Engineering,2018,47(10):3072-3079(in Chinese).
[31]	ZHANG X Z, GUO Y, RASHAD A, et al. Bifunctional carbon-encapsulated FeSiAl hybrid flakes for enhanced microwave absorption properties and analysis of corrosion resistance[J]. Journal of Alloys and Compounds,2020,828:154079. doi: 10.1016/j.jallcom.2020.154079
[32]	黄巨龙. 热压烧结FeSiAl/碳系吸收剂/Al₂O₃复合材料的制备及其电磁性能研究[D]. 西安: 长安大学, 2019. HUANG Julong. Study on preparation and electromagnetic properties of hot pressed sintered FeSiAl/carbon-based absorbent/Al₂O₃ composites[D]. Xi’an: Chang’an University, 2019(in Chinese).
[33]	ZHOU T D, XUE J, LIU W B, et al. Microstructural and magnetic evolution of MnZn/FeSiAl composites synthesized by mechanochemistry[J]. Ceramics International,2020,46(2):1784-1792. doi: 10.1016/j.ceramint.2019.09.153
[34]	YAN H Y, ZHOUG L, TANG J L, et al. Decreasing the complex permittivity to enhance microwave absorption properties of flaky FeSiAl/MnZn ferrites composites[J]. Journal of Materials Science: Materials in Electronics,2021,32:18371-18380. doi: 10.1007/s10854-021-06380-w
[35]	LEI C, DU Y. Tunable dielectric loss to enhance microwave absorption properties of flakey FeSiAl/ferrite composites[J]. Journal of Alloys and Compounds,2020,822:153674. doi: 10.1016/j.jallcom.2020.153674
[36]	ZHOU L, HUANG J L, WANG H B, et al. FeSiAl/ZnO-filled resin composite coatings with enhanced dielectric and microwave absorption properties[J]. Springer US,2019,30(2):1896-1906.
[37]	TIAN W, LI J Y, LIU Y F, et al. Atomic-scale layer-by-layer deposition of FeSiAl@ZnO@Al₂O₃ hybrid with threshold anti-corrosion and ultra-high microwave absorption pro-perties in low-frequency bands[J]. Nano-Micro Letters,2021,13(10):308-321. doi: 10.1007/s40820-021-00678-4
[38]	PAN Y, LI J Y, LIU Z Y, et al. Inorganic/organic bilayer of silica/acrylic polyurethane decorating FeSiAl for enhanced anti-corrosive microwave absorption[J]. Applied Surface Science,2021,567:150829. doi: 10.1016/j.apsusc.2021.150829
[39]	GUO Y, JIAN X, ZHANG L, et al. Plasma-induced FeSiAl@Al₂O₃@SiO₂ core-shell structure for exceptional microwave absorption and anti-oxidation at high temperature[J]. Chemical Engineering Journal,2020,384:123371. doi: 10.1016/j.cej.2019.123371
[40]	YANG C, DAI S L, ZHANG X Y, et al. Electromagnetic wave absorption property of graphene with Fe₃O₄ nanoparticles[J]. Journal of Nanoscience and Nanotechnology,2016,16:1483-1490. doi: 10.1166/jnn.2016.10707
[41]	ZHANG K, LUO J H, YU N, et al. Synthesis and excellent electromagnetic absorption properties of reduced graphene oxide/PANI/BaNd_0.2Sm_0.2Fe_11.6O₁₉ nanocompo-sites[J]. Journal of Alloys and Compounds,2019,779:270-279. doi: 10.1016/j.jallcom.2018.11.284
[42]	LEI Y M, YAO Z J, LIN H Y, et al. Synthesis and high-performance microwave absorption of reduced graphene oxide/Co-doped ZnNi ferrite/polyaniline composites[J]. Materials Letters,2019,236:456-459. doi: 10.1016/j.matlet.2018.10.158
[43]	LI W X, QI H X, GUO F, et al. Co nanoparticles supported on cotton-based carbon fibers: A novel broadband microwave absorbent[J]. Journal of Alloys and Compounds,2019,772:760-769. doi: 10.1016/j.jallcom.2018.09.075
[44]	ZHOU N, AN Q D, XIAO Z Y, at el. Solvothermal synthesis of three-dimensional, Fe₂O₃ NPs-embedded CNT/N-doped graphene composites with excellent microwave absorption performance[J]. RSC Advances,2017,7:45156-45169. doi: 10.1039/C7RA06751H
[45]	XUE W, YANG G, BI S, et al. Construction of caterpillar-like hierarchically structured Co/MnO/CNTs derived from MnO₂/ZIF-8@ZIF-67 for electromagnetic wave absorption[J]. Carbon,2021,173(48):521-527.
[46]	MO Z C, YANG R L, LU D W, et al. Lightweight, three-dimensional carbon nanotube@TiO₂ sponge with enhanced microwave absorption performance[J]. Carbon,2019,144:433-439. doi: 10.1016/j.carbon.2018.12.064
[47]	ZOU C W, YAO Y D, WEI N D, et al. Electromagnetic wave absorption properties of mesoporous Fe₃O₄/C nanocomposites[J]. Composites Part B: Engineering,2015,77:209-214.
[48]	FANG J Y, LIU T, CHEN Z, et al. A wormhole-like porous carbon/magnetic particles composite as an efficient broadband electromagnetic wave absorber[J]. Nanoscale,2016, 16:8899-8909.
[49]	WANG J W, WANG B B, FENG A L, et al. Design of morphology-controlled and excellent electromagnetic wave absorption performance of sheet-shaped ZnCo₂O₄ with a special arrangement[J]. Journal of Alloys and Compounds,2020,834:155092. doi: 10.1016/j.jallcom.2020.155092
[50]	CUI Y, XU K Z, ZHU B, et al. Synthesis of niobium nitride porous nanofibers with excellent microwave absorption properties via reduction nitridation of electrospinning precursor nanofibers with ammonia gas[J]. Journal of Alloys and Compounds,2022,907:164453. doi: 10.1016/j.jallcom.2022.164453
[51]	ZHANG W D, ZHANG X, ZHU Q, et al. High-efficiency and wide-bandwidth microwave absorbers based on MoS₂-coated carbon fiber[J]. Journal of Colloid and Interface Science,2021,586:457-468. doi: 10.1016/j.jcis.2020.10.109
[52]	SUN Z H, YAN Z Q, YUE K C, et al. Multi-scale structural nitrogen-doped rGO@CNTs composites with ultra-low loading towards microwave absorption[J]. Applied Surface Science,2021,538:14793.
[53]	XU J, CUI Y H, WANG J Q, et al. Fabrication of wrinkled carbon microspheres and the effect of surface roughness on the microwave absorbing properties[J]. Chemical Engi-neering Journal,2020,401:126027. doi: 10.1016/j.cej.2020.126027
[54]	WANG H Y, SUN X B, YANG S H, et al. 3D ultralight hollow NiCo compound@MX high-efficient microwave absorption[J]. Nano-Micro Letters,2021,13(12):330-344.
[55]	DONG Y Y, ZHU X J, PAN F, et al. Fire-retardant and thermal insulating honeycomb-like NiS₂/SnS₂ nanosheets@3D porous carbon hybrids for high-efficiency electromagnetic wave absorption[J]. Chemical Engineering Journal,2021,426:131272. doi: 10.1016/j.cej.2021.131272