Volume 40 Issue 1
Jan.  2023
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GE Xiaodong, MENG Guanhua, LIU Baohe, et al. Study of the degradation of tetracycline by visible photo-Fenton catalyzed by ultrasound-assisted LaFeO3/PS[J]. Acta Materiae Compositae Sinica, 2023, 40(1): 255-269. doi: 10.13801/j.cnki.fhclxb.20220101.001
Citation: GE Xiaodong, MENG Guanhua, LIU Baohe, et al. Study of the degradation of tetracycline by visible photo-Fenton catalyzed by ultrasound-assisted LaFeO3/PS[J]. Acta Materiae Compositae Sinica, 2023, 40(1): 255-269. doi: 10.13801/j.cnki.fhclxb.20220101.001

Study of the degradation of tetracycline by visible photo-Fenton catalyzed by ultrasound-assisted LaFeO3/PS

doi: 10.13801/j.cnki.fhclxb.20220101.001
Funds:  Key Project Funded by the National Science Foundation of the Anhui Higher Education Institutions of China (KJ2017A065); Program of Study Abroad for Young Scholar Sponsored by Anhui Province, China (gxfx2017019)
  • Received Date: 2021-11-15
  • Accepted Date: 2021-12-26
  • Rev Recd Date: 2021-12-16
  • Available Online: 2022-01-04
  • Publish Date: 2023-01-15
  • The powdered LaFeO3 material had shortcomings such as easy agglomeration and difficult separation, so it was limited in large-scale applications. The deposition of powdered catalysts in polystyrene resin (PS) made up for the above shortcomings of powdered materials. Therefore, in this study, the self-assembled LaFeO3 gel was deposited on the PS through ultrasound-assisted sol-gel and hydrothermal methods. The dispersion and distribution of LaFeO3 on PS broadens the forbidden band width of LaFeO3, improves its redox ability, solves the problem of agglomeration, and consequently improves its photo-Fenton catalytic activity. The LaFeO3/PS composite prepared under the following experimental conditions shows the highest photocatalytic activity: La∶Fe∶Citric acid(CA) molar ratio=1∶1∶2, ultrasonic time 40 min, hydrothermal temperature 90℃, hydrothermal time 18 h, LaFeO3 initiator/polystyrene mass ratio=32∶1. The removal rate of tetracycline hydrochloride (TC) is up to 96.51%(rate of degradation k=0.0160 min−1) under visible light irradiation in the Fenton process catalyzed by LaFeO3/PS. Free radical capture experiments show that •O2 is the main active species. According to the capture experiment, the degradation mechanism of TC was proposed. Through LC/MS analysis, the degradation path of TC was obtained. The photo-Fenton process catalyzed by LaFeO3/PS is a promising technology for the degradation of organic pollutants due to the high stability of the catalyst and the efficient use of solar energy.

     

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