Preparation of modified microcrystalline cellulose based composite and its catalytic degradation performance on methylene blue

CHEN Jiachuan; JI Dexian; LIN Zhaoyun; YANG Guihua; HOU Huimin

doi:10.13801/j.cnki.fhclxb.20200416.001

Volume 37 Issue 12

Dec. 2020

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CHEN Jiachuan, JI Dexian, LIN Zhaoyun, et al. Preparation of modified microcrystalline cellulose based composite and its catalytic degradation performance on methylene blue[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 3184-3193. doi: 10.13801/j.cnki.fhclxb.20200416.001

Citation:

CHEN Jiachuan, JI Dexian, LIN Zhaoyun, et al. Preparation of modified microcrystalline cellulose based composite and its catalytic degradation performance on methylene blue[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 3184-3193. doi: 10.13801/j.cnki.fhclxb.20200416.001

Citation:

CHEN Jiachuan, JI Dexian, LIN Zhaoyun, et al. Preparation of modified microcrystalline cellulose based composite and its catalytic degradation performance on methylene blue[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 3184-3193. doi: 10.13801/j.cnki.fhclxb.20200416.001

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Preparation of modified microcrystalline cellulose based composite and its catalytic degradation performance on methylene blue

doi: 10.13801/j.cnki.fhclxb.20200416.001

State Key Laboratory of Biobased Material and Green Papermaking/Key Lab of Pulp & Paper Science and Technology of Education Ministry of China, Qilu University of Technology, Shandong Academy of Sciences, Ji'nan 250353, China

Received Date: 2020-01-21
Accepted Date: 2020-03-18

Available Online: 2020-04-16

Publish Date: 2020-12-15

Abstract

Abstract

Microcrystalline cellulose (MCC) was used as raw materials and loaded with CuO nanoparticles (CuO NPs). Then, 3-chloropropyltrimethoxysilane (CPTES) and diethanolamine (DEA) were added for grafting reaction to prepare CuO NPs@MCC–Si–N(OH)₂. CuO NPs@MCC–Si–N(OH)₂ was characterized with FTIR, XRD, thermal gravimetric analysis and morphology analysis. The results show that CuO NPs can be successfully loaded on the surface of MCC, and silane coupling agent can improve the dispersion of the composite and the ability to graft amine groups, thus enhancing its catalytic activity, and increasing the redox reaction efficiency of sodium borohydride (NaBH₄) and methylene blue (MB). Hence, MB stain is degraded rapidly. It’s also found that CuO NPs@MCC–Si–N(OH)₂ with 20wt% DEA shows the best catalytic effect, and the highest removal efficiency is 99.71% after treating 30 mL MB solution (3 mmol/L) with 30 mg CuO NPs@MCC–Si–N(OH)₂ and 10 mg NaBH₄ within 5 min, and the removal rate is 93.24% after five cycles.
- microcrystalline cellulose,
- 3-chloropropyltriethoxysilane,
- diethanolamine,
- methylene blue,
- catalytic,
- degradation
Long Abstrsct
Innovation Points

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References(26)

References

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