MOFs及其衍生材料在锂离子电池负极中的研究进展

戴良鸿; 刘劲远; 彭红建; 谢佑卿

doi:10.13801/j.cnki.fhclxb.20220727.001

MOFs及其衍生材料在锂离子电池负极中的研究进展

doi: 10.13801/j.cnki.fhclxb.20220727.001

戴良鸿¹,
刘劲远¹,
彭红建^{1, 2, ,},
谢佑卿²

1.
中南大学　化学化工学院，长沙 410083
2.
中南大学　材料科学与工程学院，长沙 410083

基金项目: 国家联合基金(U19A2019)；湖南省重大科技专项(2020GK2100)

详细信息

通讯作者:
彭红建，博士，副教授，硕士生导师，研究方向为电化学和电化学储能装置的关键材料　E-mail: Hongjianpeng@126.com

中图分类号: TB33
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出版历程
- 收稿日期: 2022-06-07
- 修回日期: 2022-07-02
- 录用日期: 2022-07-15
- 网络出版日期: 2022-07-29
- 刊出日期: 2023-04-15

Research progress of MOFs and their derived materials for Li-ion battery anodes

1.
School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2.
School of Materials Science and Engineering, Central South University, Changsha 410083, China

Funds: Joint Funds of the National Natural Science Foundation of China (U19A2019); Science and Technology Plan Key Project of Hunan Province (2020GK2100)

摘要

摘要: 金属有机框架(MOFs)具有较大的比表面积和可调节的孔径，其金属离子和有机配体都具有良好的携电荷能力，近年来作为锂离子电池负极材料受到广泛关注。本文介绍了目前常用的锂离子电池MOFs负极材料，归纳了MOFs材料在锂离子电池负极中的改性策略和合成方法，且系统分析了MOFs及其衍生材料的结构与形貌设计的主要原则，指出了其未来发展趋势及研究挑战。
- 金属有机框架 /
- 负极材料 /
- 锂离子电池 /
- 结构 /
- 形貌
Abstract: The metal organic frameworks (MOFs) have large specific surface area and tunable pore size, and they are composed of metal ions and organic ligands, both of which have good charge carrying capacity. In recent years, MOFs have attracted widespread attention for Li-ion battery anode materials. The review introduces the commonly used MOFs anode materials for Li-ion batteries (LIBs) and summarizes the modification strategies and research progress of MOFs and their derived materials for Li-ion battery anodes. Finally, the main design principles about the structure and morphology of MOFs anode materials are analyzed systematically, and challenges for the future development of advanced anode materials for LIBs will be considered.
- metal organic frameworks (MOFs) /
- anode materials /
- lithium ion batteries (LIBs) /
- structure /
- morphology

HTML全文

图 1 3种具有代表性的锂离子电池(LIBs)纳米负极材料示意图

Figure 1. Schematic diagram of three representative nanostructured anode materials for Li-ion batteries (LIBs)

下载: 全尺寸图片幻灯片

图 2 6种合成策略中14种反应类型示意图^[58]

Figure 2. Schematic diagram of 14 types of reactions in six types of synthetic strategies^[58]

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图 3 一种三维多孔碳材料的制备工艺

Figure 3. A fabrication process of the 3D porous carbon materials

H₂BDC—1, 4-benzenedicar-boxylic acid; DMF—N, N-dimethylformamide; PVP—Polyvinyl pyrrolidone

下载: 全尺寸图片幻灯片

图 4 核壳ZnO/ZnCo₂O₄/C纳米球制备工艺示意图

Figure 4. Schematic illustration for the preparation process of core/shell ZnO/ZnCo₂O₄/C nanospheres

CO(acac)₂—Cobalt(II) acetylacetonat

下载: 全尺寸图片幻灯片

参考文献(94)

[1]	张欢欢, 万琦, 石庆宇, 等. 基于金属-有机骨架的锂离子电池硅负极的研究进展[J]. 复合材料学报, 2021, 38(1):45-54. doi: 10.13801/j.cnki.fhclxb.20200921.005 ZHANG Huanhuan, WAN Qi, SHI Qingyu, et al. Progress of silicon-based anode for lithium-ion batteries with metal-organic frameworks[J]. Acta Materiae Compositae Sinica,2021,38(1):45-54(in Chinese). doi: 10.13801/j.cnki.fhclxb.20200921.005
[2]	CHEN H, LING M, HENCTLZ L, et al. Exploring chemical, mechanical, and electrical functionalities of binders for advanced energy storage devices[J]. Chemical Reviews,2018,118(18):8936-8982. doi: 10.1021/acs.chemrev.8b00241
[3]	LI Q M, DU J K, CHAI J L, et al. Vanadium metaphosphate V(PO₃)₃ derived from V-MOF as a novel anode for lithium ion batteries[J]. Chemistry Select,2021,6(31):8150-8157. doi: 10.1002/slct.202102311
[4]	唐致远, 庄兴国, 翟玉梅. 锂离子蓄电池负极材料的研究进展[J]. 电源技术, 2000, 5(2):108-111. doi: 10.3969/j.issn.1002-087X.2000.02.014 TANG Zhiyuan, ZHUANG Xinguo, ZHAI Yumei. Progress in studies on negative material for lithium ion battery[J]. Chinese Journal of Power Sources,2000,5(2):108-111(in Chinese). doi: 10.3969/j.issn.1002-087X.2000.02.014
[5]	赵桃林, 申建钢, 徐凯, 等. 锂离子电池硅基负极用粘结剂的设计改性进展[J]. 复合材料学报, 2021, 38(6):1678-1690. doi: 10.13801/j.cnki.fhclxb.20210210.004 ZHAO Taolin, SHEN Jiangang, XU Kai, et al. Design and modification progress of binders for silicon-based anodes of lithium-ion batteries[J]. Acta Materiae Compositae Sinica,2021,38(6):1678-1690(in Chinese). doi: 10.13801/j.cnki.fhclxb.20210210.004
[6]	LIU Y, YANG Y F. Recent progress of TiO₂-based anodes for Li ion batteries[J]. Journal of Nanomaterials,2016,2016:1-15. doi: 10.1155/2016/8123652
[7]	SUNDRIYAL S, KAUR H, BHARDWAJ S, et al. Metal organic frameworks and their composites as efficient electrodes for supercapacitor applications[J]. Coordination Chemistry Reviews,2018,369:15-38. doi: 10.1016/j.ccr.2018.04.018
[8]	YANG Y, YUAN W, KANG W Q, et al. Silicon-nanoparticle-based composites for advanced lithium-ion battery anodes[J]. Nanoscale,2020,12(14):7461-7484. doi: 10.1039/C9NR10652A
[9]	葛武杰, 高乾森, 马先果, 等. 二次电池锂金属负极的研究进展[J]. 电子元件与材料, 2020, 39(1):1-9. doi: 10.14106/j.cnki.1001-2028.2020.01.001 GE Wujie, GAO Qiansen, MA Xianguo, et al. Research progress of lithium metal anode for secondary batteries[J]. Electronic Components and Materials,2020,39(1):1-9(in Chinese). doi: 10.14106/j.cnki.1001-2028.2020.01.001
[10]	ZHENG S Y, DONG F, PANG Y P, et al. Research progress on nanostructured metal oxides as anode materials for Li-ion battery[J]. Journal of Inorganic Materials,2020,35(12):1295-1306. doi: 10.15541/jim20200134
[11]	YAGHI O M, LI G M, LI H L. Selective binding and removal of guests in a microporous metal-organic framework[J]. Nature (London),1995,378(6558):703-706. doi: 10.1038/378703a0
[12]	ZHENG X Z, LI Y F, XU Y X, et al. Metal organic frameworks: Promising materials for enhancing electrochemical properties of nanostructured Zn₂SnO₄ anode in Li-ion batteries[J]. CrystEngComm,2012,14(6):2112-2116. doi: 10.1039/c2ce06350f
[13]	ZHAO H, SHENG L, WANG L, et al. The opportunity of metal organic frameworks and covalent organic frameworks in lithium ion batteries and fuel cells[J]. Energy Storage Material,2020,33:360-381. doi: 10.1016/j.ensm.2020.08.028
[14]	CHEN H, XU J, JI S, et al. Application of MOFs derived metal oxides and composites in anode materials of lithium ion batteries[J]. Progress in Chemistry,2020,32(2-3):298-308. doi: 10.7536/PC190610
[15]	RYU U J, JEE S, RAO P C, et al. Recent advances in process engineering and upcoming applications of metal-organic frameworks[J]. Coordination Chemistry Reviews,2021,426:213544. doi: 10.1016/j.ccr.2020.213544
[16]	ZHANG Y, QIU T P, JIANG F, et al. Spindle-like Ni₃(HITP)₂ MOFs: Synthesis and Li⁺ storage mechanism[J]. Applied Surface Science,2021,556:149818. doi: 10.1016/j.apsusc.2021.149818
[17]	JIANG J C, FURUKAWA H, ZHANG Y B, et al. High methane storage working capacity in metal-organic frameworks with acrylate links[J]. Journal of the American Chemical Society,2016,138(32):10244-10251. doi: 10.1021/jacs.6b05261
[18]	FAN W D, WANG X, XU B, et al. Amino-functionalized MOFs with high physicochemical stability for efficient gas storage/separation, dye adsorption and catalytic performance[J]. Journal of Materials Chemistry A,2018,6(47):24486-24495. doi: 10.1039/C8TA07839D
[19]	CONNOLLY B M, MADDEN D G, WHEATLEY A, et al. Shaping the future of fuel: Monolithic metal-organic frameworks for high-density gas storage[J]. Journal of the American Chemical Society,2020,142(19):8541-8549. doi: 10.1021/jacs.0c00270
[20]	WU C D, ZHAO M. Incorporation of molecular catalysts in metal-organic frameworks for highly efficient heterogeneous catalysis[J]. Advanced Materials,2017,29(14):1605446. doi: 10.1002/adma.201605446
[21]	JOHNSON B A, BEILER A M, MCCARTHY B D, et al. Transport phenomena: Challenges and opportunities for molecular catalysis in meta-organic frameworks[J]. Journal of the American Chemical Society,2020,142(28):11941-11956. doi: 10.1021/jacs.0c02899
[22]	BAKURU V R, DAVIS D, KALIDINDI S B. Cooperative catalysis at the metal-MOF interface: Hydrodeoxygenation of vanillin over Pd nanoparticles covered with a UiO-66(Hf) MOF[J]. Dalton Transactions,2019,48(24):8573-8577. doi: 10.1039/C9DT01371G
[23]	ZHENG H Q, ZHANG Y N, LIU L F, et al. One-pot synthesis of metal-organic frameworks with encapsulated target molecules and their applications for controlled drug delivery[J]. Journal of the American Chemical Society,2016,138(3):962-968. doi: 10.1021/jacs.5b11720
[24]	JEI H R, DENG S B, HUANG Q, et al. Regenerable granular carbon nanotubes alumina hybrid adsorbents for diclofenac sodium and carbamazepine removal from aqueous solution[J]. Water Research,2013,47(12):4139-4147. doi: 10.1016/j.watres.2012.11.062
[25]	NAZIR A, LE H, NGUYEN A, et al. Graphene analogue metal organic framework with superior capacity and rate capability as an anode for lithium ion batteries[J]. Electrochimica Acta,2021,389:138750. doi: 10.1016/j.electacta.2021.138750
[26]	LIU X L, WU J Y, WANG M Q, et al. N-doped carbon nanocapsules as nanoreactors to boost lithium storage performance of Co-based oxide nanocrystallines[J]. Ceramics International,2020,46(17):27608-27615. doi: 10.1016/j.ceramint.2020.07.255
[27]	SHARMA N, SZUNERITS S, BOUKHERROUB R, et al. Dual-ligand Fe-metal organic framework based robust high capacity Li ion battery anode and its use in a flexible battery format for electro-thermal heating[J]. ACS Applied Energy Materials,2019,2(6):4450-4457. doi: 10.1021/acsaem.9b00688
[28]	CHENG H, SHAPTER J G, LI Y, et al. Recent progress of advanced anode materials of lithium ion batteries[J]. Journal of Energy Chemistry,2021,57:451-468. doi: 10.1016/j.jechem.2020.08.056
[29]	张玉琪, 魏光平, 李春宏, 等. 金属有机框架材料用于锂电池负极的研究进展[J]. 电源技术, 2020, 40(1):135-138. doi: 10.3969/j.issn.1002-087X.2020.01.038 ZHANG Yuqi, WEI Guangping, LI Chunhong, et al. Research progress of MOFs applied as anode for lithium ion battery[J]. Chinese Journal of Power Sources,2020,40(1):135-138(in Chinese). doi: 10.3969/j.issn.1002-087X.2020.01.038
[30]	JIANG Y, ZHAO H, YUE L, et al. Recent advances in lithium-based batteries using metal organic frameworks as electrode materials[J]. Electrochemistry Communications,2021,122:106881. doi: 10.1016/j.elecom.2020.106881
[31]	吴事剑, 王荷英, 李晗, 等. MIL系列MOFs材料的合成及应用研究进展[J]. 广东化工, 2012, 15(39):3-4. doi: 10.3969/j.issn.1007-1865.2012.15.002 WU Shijian, WANG Heying, LI Han, et al. Synthesis and application of MIL—A typical series of MOFs[J]. Guangdong Chemical Industry,2012,15(39):3-4(in Chinese). doi: 10.3969/j.issn.1007-1865.2012.15.002
[32]	李震东, 王振华, 张仕龙, 等. MOFs及其衍生物作为锂离子电池电极的研究进展[J]. 储能科学与技术, 2020, 9(1): 18-24. LI Zhendong, WANG Zhenhua, ZHANG Shilong, et al. Research progress of MOFs and its derivatives as electrode materials for lithium ion batteries[J]. Energy Storage Science and Technology, 2020, 9(1): 18-24(in Chinese).
[33]	HORCAJADA P, SERRE C, VALLET-REGI M, et al. Metal-organic frameworks as efficient materials for drug delivery[J]. Angewandte Chemie,2006,45(36):5974-5978. doi: 10.1002/anie.200601878
[34]	ZHONG Y R, LIN F, WANG M Y, et al. Metal organic framework derivative improving lithium metal anode cycling[J]. Advanced Functional Materials,2020,30(10):1907579. doi: 10.1002/adfm.201907579
[35]	BAI J, GAO D D, WU H M, et al. Synthesis of Ni/NiO@MIL-101(Cr) composite as novel anode for lithium-ion battery application[J]. Journal of Nanoscience and Nanotechnology,2019,19:8063-8070. doi: 10.1166/jnn.2019.16763
[36]	JIN Y, ZHAO C C, LIN Y C, et al. Fe-based metal-organic framework and its derivatives for reversible lithium storage[J]. Journal of Materials Science & Technology,2017,33(8):768-774. doi: 10.1016/j.jmst.2016.11.021
[37]	LI X X, ZHENG S S, JIN L, et al. Metal-organic framework-derived carbons for battery applications[J]. Advanced Energy Materials,2018,8(23):1800716. doi: 10.1002/aenm.201800716
[38]	GUO A, LI Y, LIU K, et al. Porous NiO architecture prepared with coordination polymer precursor as a high performance anode material for Li-ion batteries[J]. RSC Advances,2015,5(108):89269-89272. doi: 10.1039/C5RA15452A
[39]	WANG P, LOU X B, LI C, et al. One-pot synthesis of Co-based coordination polymer nanowire for Li-ion batteries with great capacity and stable cycling stability[J]. Nano-Micro Letters,2018,10:19. doi: 10.1007/s40820-017-0177-x
[40]	ZHANG Y T, ZHANG Y L, ZHANG K B, et al. Nitrogen-doped graphene nanosheet coated nanospherical Fe₃O₄ from zeolitic imidazolate frameworks template as anode of lithium ion batteries[J]. Energy & Fuels,2020,34(11):14986-14994. doi: 10.1021/acs.energyfuels.0c02853
[41]	SONG Y H, ZUO L, CHEN S H, et al. Porous nano-Si/carbon derived from zeolitic imidazolate frameworks@nano-Si as anode materials for lithium-ion batteries[J]. Electrochimica Acta,2015,173:588-594. doi: 10.1016/j.electacta.2015.05.111
[42]	LI Z T, ZHAO J, NIE J J, et al. Co₃O₄/NiO/C composites derived from zeolitic imidazolate frameworks (ZIFs) as high-performance anode materials for Li-ion batteries[J]. Journal of Solid State Electrochemistry,2020,24(5):1133-1142. doi: 10.1007/s10008-020-04595-1
[43]	LI Z, HUANG X X, SUN C L, et al. Thin-film electrode based on zeolitic imidazolate frameworks (ZIF-8 and ZIF-67) with ultra-stable performance as a lithium-ion battery anode[J]. Journal of Materials Science,2017,52(7):3979-3991. doi: 10.1007/s10853-016-0660-7
[44]	XUE Z, LI L L, CAO L J, et al. A simple method to fabricate NiFe₂O₄/NiO@Fe₂O₃ core-shelled nanocubes based on Prussian blue analogues for lithium ion battery[J]. Journal of Alloys and Compounds,2020,825:153966. doi: 10.1016/j.jallcom.2020.153966
[45]	NIE J J, FU H, LI Z T, et al. Constructing CoFe₂O₄ with cubic structure by Prussian blue to provide high-performance anodes for lithium-ion batteries[J]. Materials Letters,2021,300:130152. doi: 10.1016/j.matlet.2021.130152
[46]	LI J Q, ZHOU F C, SUN Y H, et al. FeMnO₃ porous nanocubes/Mn₂O₃ nanotubes hybrids derived from Mn₃[Fe(CN)₆]₂·nH₂O Prussian blue analogues as an anode material for lithium-ion batteries[J]. Journal of Alloys and Compounds,2018,740:346-354. doi: 10.1016/j.jallcom.2017.12.370
[47]	LI Z T, QIAO N, NIE J J, et al. NiO/NiFe₂O₄ nanocubes derived from Prussian blue as anode materials for Li-ion batteries[J]. Materials Letters,2020,275:128077. doi: 10.1016/j.matlet.2020.128077
[48]	任正鑫. 多孔铁基普鲁士蓝衍生材料的制备及在锂离子电池中的应用[D]. 天津: 天津理工大学, 2019. REN Zhengxin. Porous iron-based prussian blue derivatives: Preparation and application in lithium batteries[D]. Tianjin: Tianjin University of Technology, 2019(in Chinese).
[49]	LIU D X, ZOU D T, ZHU H L, et al. Mesoporous metal-organic frameworks: Synthetic strategies and emerging applications[J]. Small,2018,14(37):1801454. doi: 10.1002/smll.201801454
[50]	DING B, WANG J, CHANG Z, et al. Self-sacrificial template-directed synthesis of metal-organic framework-derived porous carbon for energy-storage devices[J]. ChemElectroChem,2016,3(4):668-674. doi: 10.1002/celc.201500536
[51]	REDDY R, LIN J, CHEN Y Y, et al. Progress of nanostructured metal oxides derived from metal-organic frameworks as anode materials for lithium-ion batteries[J]. Coordination Chemistry Reviews,2020,420:213434. doi: 10.1016/j.ccr.2020.213434
[52]	BI W T, ZHOU M, MA Z Y, et al. CuInSe₂ ultrathin nanoplatelets: Novel self-sacrificial template-directed synthesis and application for flexible photodetectors[J]. Chemical Communications,2012,48(73):9162-9164. doi: 10.1039/c2cc34727j
[53]	ZHAO Z M, DING J W, ZHU R M, et al. The synthesis and electrochemical applications of core-shell MOFs and their derivatives[J]. Journal of Materials Chemistry A,2019,7(26):15519-15540. doi: 10.1039/C9TA03833G
[54]	YAP M H, FOW K L, CHEN G Z. Synthesis and applications of MOF derived porous nanostructures[J]. Green Energy and Environment,2017,2(3):218-245. doi: 10.1016/j.gee.2017.05.003
[55]	YU L, YU X Y, LOU X W. The design and synthesis of hollow micro-nanostructures: Present and future trends[J]. Advanced Materials,2018,30(38):1800939. doi: 10.1002/adma.201800939
[56]	ZHANG W, JIANG X F, ZHAO Y Y, et al. Hollow carbon nanobubbles: Monocrystalline MOF nanobubbles and their pyrolysis[J]. Chemical Science,2017,8(5):3538-3546. doi: 10.1039/C6SC04903F
[57]	KOO J, HWANG I, YU X J, et al. Hollowing out MOFs: Hierarchical micro- and mesoporous MOFs with tailorable porosity via selective acid etching[J]. Chemical Science,2017,8(10):6799-6803. doi: 10.1039/C7SC02886E
[58]	CAI Z X, WANG Z L, KIM J H, et al. Hollow functional materials derived from metal organic frameworks: Synthetic strategies, conversion mechanisms, and electrochemical applications[J]. Advanced Materials,2019,31(11):1804903. doi: 10.1002/adma.201804903
[59]	ZHANG Z C, CHEN Y F, HE S, et al. Hierarchical Zn/Ni-MOF-2 nanosheet assembled hollow nanocubes for multicomponent catalytic reactions[J]. Angewandte Chemie,2014,126(46):12725-12729. doi: 10.1002/ange.201406484
[60]	LIU W, YIN R, XU X, et al. Structural engineering of low-dimensional metal organic frameworks: Synthesis, properties, and applications[J]. Advanced Science,2019,6(12):1802373. doi: 10.1002/advs.201802373
[61]	宋良浩. 界面反应参与MOFs衍生双金属氧化物的合成及其形成机理、催化性能的研究[D]. 济南: 济南大学, 2020. SONG Lianghao. Interfacial reaction involved synthesis of MOFs-derived bimetal oxides and their formation mechanism and catalytic performance study[D]. Jinan: University of Jinan, 2020(in Chinese).
[62]	PARK J W, ZHENG H M, JUN Y W, et al. Hetero-epitaxial anion exchange yields single-crystalline hollow nanoparticles[J]. Journal of the American Chemical Society,2009,131(39):13943-13945. doi: 10.1021/ja905732q
[63]	WU L L, WANG Z, LONG Y, et al. Multishelled Ni_xCo_3–xO₄ hollow microspheres derived from bimetal organic frameworks as anode materials for high performance lithium ion batteries[J]. Small,2017,13(17):1604270. doi: 10.1002/smll.201604270
[64]	陈君, 隆继兰. 双中心MOFs衍生的Co-ZnO@CN纳米材料作为电化学催化剂用于氧还原反应的研究[J]. 分子催化, 2017, 31(5): 463-471. CHEN Jun, LONG Jilan. Bi-centered MOFs-derived Co-ZnO@CN nano-material as efficient electrocatalyst for oxygen reduction reaction[J]. Journal of Molecular Catalysis, 2017, 31(5): 463-471(in Chinese).
[65]	MENG J S, NIU C J, XU L H, et al. General oriented formation of carbon nanotubes from metal organic frameworks[J]. Journal of the American Chemical Society,2017,139(24):8212-8221. doi: 10.1021/jacs.7b01942
[66]	SHRIVASTAV V, SUNDRIYAL S, GOEL P, et al. Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage[J]. Coordination Chemistry Reviews,2019,393:48-78. doi: 10.1016/j.ccr.2019.05.006
[67]	GUAN B Y, YU X Y, WU H B, et al. Complex nanostructures from materials based on metal-organic frameworks for electrochemical energy storage conversion[J]. Advanced Materials,2017,29(47):1703614. doi: 10.1002/adma.201703614
[68]	EFTEKHARI A. Low voltage anode materials for lithium-ion batteries[J]. Energy Storage Materials,2017,7:157-180. doi: 10.1016/j.ensm.2017.01.009
[69]	NITTA N, WU F X, LEE J T, et al. Li-ion battery materials: Present and future[J]. Materials Today,2015,18(5):252-264. doi: 10.1016/j.mattod.2014.10.040
[70]	BLOMGREN G E. The development and future of lithium ion batteries[J]. Journal of the Electrochemical Society,2017,164(1):5019-5025. doi: 10.1149/2.0251701jes
[71]	CABANA J, MONCONDUIT L, LARCHER D, et al. Beyonid intercalation based Li-ion batteries: The state of the art and challenges of electrode materials reacting through conversion reactions[J]. Advanced Materials,2010,22(35):170-192. doi: 10.1002/adma.201000717
[72]	CAO X H, TAN C L, SINDORO M, et al. Hybrid micro-nano-structures derived from metal organic frameworks: Preparation and applications in energy storage and conversion[J]. Chemical Society Reviews,2017,46(10):2660-2677. doi: 10.1039/C6CS00426A
[73]	CHAO D L, ZHU C R, SONG M, et al. A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array[J]. Advanced Materials,2018,30(32):1803181. doi: 10.1002/adma.201803181
[74]	DING Y C, PENG Y Q, CHEN W Q, et al. V-MOF derived porous V₂O₅ nanoplates for high performance aqueous zinc ion battery[J]. Applied Surface Science,2019,493:368-374. doi: 10.1016/j.apsusc.2019.07.026
[75]	HU X S, HU H P, LI C, et al. Cobalt-based metal organic framework with superior lithium anodic performance[J]. Journal of Solid State Chemistry,2016,242(1):71-76. doi: 10.1016/j.jssc.2016.07.021
[76]	GUO Y P, FENG T T, YANG J, et al. MOF-derived manganese monoxide nanosheet-assembled microflowers for enhanced lithium-ion storage[J]. Nanoscale,2019,11(22):10763-10773. doi: 10.1039/C9NR02206F
[77]	CALBO J, GOLOMB M, WALSH A. Redox-active metal-organic frameworks for energy conversion and storage[J]. Journal of Materials Chemistry A,2019,7(28):16571-16597. doi: 10.1039/C9TA04680A
[78]	ZUO L, CHEN S H, WU J F, et al. Facile synthesis of three-dimensional porous carbon with high surface area by calcining metal-organic framework for lithium-ion batteries anode materials[J]. RSC Advances,2014,4(106):61604-61610. doi: 10.1039/C4RA10575C
[79]	ZHAO Y, SONG Z, LI X, et al. Metal organic frameworks for energy storage and conversion[J]. Energy Storage Materials,2016,2:35-62. doi: 10.1016/j.ensm.2015.11.005
[80]	XU H J, WANG L, ZHONG J, et al. Ultra-stable and high-rate lithium ion batteries based on metal-organic framework-derived In₂O₃ nanocrystals hierarchically porous nitrogen-doped carbon anode[J]. Energy & Environmental Materials,2020,3(2):177-185. doi: 10.1002/eem2.12065
[81]	ZHONG Y R, YANG M, ZHOU X L, et al. Structural design for anodes of lithium ion batteries: Emerging horizons from materials to electrodes[J]. Materials Horizons,2015,2(6):553-566. doi: 10.1039/C5MH00136F
[82]	ZHANG X B, MA J, CHEN K Z. Impact of morphology of conductive agent and anode material on lithium storage properties[J]. Nano-Micro Letters,2015,7(4):360-367. doi: 10.1007/s40820-015-0051-7
[83]	盘盈滢, 胡茜, 林晓明, 等. 核壳结构金属-有机骨架及其衍生物在锂离子电池负极材料中的应用[J]. 化学通报, 2020, 83(10):883-890. doi: 10.14159/j.cnki.0441-3776.2020.10.003 PAN Yingying, HU Xi, LIN Xiaoming, et al. The application of core-shell MOFs and their derivatives as anode materials in lithium-ion batteries[J]. Chemistry,2020,83(10):883-890(in Chinese). doi: 10.14159/j.cnki.0441-3776.2020.10.003
[84]	GE X L, LI Z Q, WANG C X, et al. Metal-organic frameworks derived porous core/shell structured ZnO/ZnCo₂O₄/C hybrids as anodes for high-performance lithium-ion battery[J]. ACS Applied Materials & Interfaces,2015,7(48):26633-26642. doi: 10.1021/acsami.5b08195
[85]	GUO Y C, WANG Z Y, LU X S, et al. Core-shell ZnO@C: N hybrids derived from MOFs as long-cycling anodes for lithium ion batteries[J]. Chemical Communications,2020,56(13):1980-1983. doi: 10.1039/C9CC08478A
[86]	YIN D M, HUANG G, NA Z L, et al. CuO nanorod arrays formed directly on Cu foil from MOFs as superior binder-free anode material for lithium-ion batteries[J]. ACS Energy Letters,2017,2(7):1564-1570. doi: 10.1021/acsenergylett.7b00215
[87]	QIU T J, LIANG Z B, GUO W H, et al. Metal-organic framework-based materials for energy conversion and storage[J]. ACS Energy Letters,2020,5(2):520-532. doi: 10.1021/acsenergylett.9b02625
[88]	LIU J B, FANG Y X, ZENG L X, et al. In situ fabrication of ZnO-MoO₂/C hetero phase nanocomposite derived from MOFs with enhanced performance for lithium storage[J]. Journal of Alloys and Compounds,2020,817:152728. doi: 10.1016/j.jallcom.2019.152728
[89]	WANG X, XUE H, NA Z, et al. Metal organic frameworks route to prepare two-dimensional porous zinc-cobalt oxide plates as anode materials for lithium-ion batteries[J]. Journal of Power Sources,2018,396:659-666. doi: 10.1016/j.jpowsour.2018.06.086
[90]	HU M, FURUKAWA S, OHTANI R, et al. Synthesis of Prussian blue nanoparticles with a hollow interior by controlled chemical etching[J]. Angewandte Chemie,2012,51(4):984-988. doi: 10.1002/anie.201105190
[91]	HU H, GUAN B Y, XIA B Y, et al. Designed formation of Co₃O₄/NiCo₂O₄ double-shelled nanocages with enhanced pseudocapacitive and electrocatalytic properties[J]. Journal of the American Chemical Society,2015,137(16):5590-5595. doi: 10.1021/jacs.5b02465
[92]	CHO W, PARK S, OH M. Coordination polymer nanorods of Fe-MIL-88 B and their utilization for selective preparation of hematite and magnetite nanorods[J]. Chemical Communications,2011,47(14):4138-4140. doi: 10.1039/c1cc00079a
[93]	LIU H D, LI Z Y, ZHANG L, et al. MOF-derived ZnSe/N-doped carbon composites for lithium-ion batteries with enhanced capacity and cycling life[J]. Nanoscale Research Letters,2019,14:237. doi: 10.1186/s11671-019-3055-2
[94]	WANG L, WANG Z H, XIE L L, et al. ZIF-67-derived N-doped Co/C nanocubes as high-performance anode materials for lithium-ion batteries[J]. ACS Applied Materials & Interfaces,2019,11(18):16619-16628. doi: 10.1021/acsami.9b03365