Preparation and bending properties of curved structure composite reinforced with multi-axial warp-knitted glass fabric
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摘要: 分别以双轴向和四轴向经编玻璃纤维织物为增强体,基于真空辅助树脂传递模塑成型工艺制备平板和曲面结构复合材料试样。实验测试复合材料弯曲性能和准静态压痕特性,实验测试不同铺层结构试样沿不同方向(0°和 90°)的弯曲性能。在此基础上,分析增强体铺层结构、曲率半径对曲面结构复合材料准静态压痕特性的影响。结果表明:双轴向经编玻璃纤维复合材料试样沿0°和90°方向当量弯曲强度分别比四轴向编玻璃纤维复合材料增加94.74%、98.37%,四轴向经编玻璃纤维复合材料试样沿0°和90°方向的最大断裂应变分别是双轴向经编玻璃纤维复合材料试样的1.9倍和2.4倍。当双轴向复合材料曲率半径为260 mm、四轴向复合材料曲率半径为150 mm时,承载能力最优;当双轴向复合材料曲率半径为150 mm、四轴向复合材料曲率半径为80 mm时,应变特性最优。实验结果为曲面结构玻璃纤维复合材料在各类室外建筑穹顶构件的应用提供借鉴。Abstract: Biaxial warp-knitted glass fabric and quadriaxial warp-knitted glass fabric were used as reinforcement, respectively. The flat and curved structure samples were prepared by applying the vacuum assisted resin transfer molding process. The bending behavior and quasi-static indentation characteristics of composite specimen were experimentally tested, and the influence of the reinforcement structure on the bending behavior of the composite in 0° and 90° directions was analyzed. On this basis, the influences of the reinforcement structure and the radius of curvature of the sample on the quasi-static indentation characteristics were also analyzed. Results show that the equivalent bending strength of the composite reinforced with biaxial warp-knitted fabric in 0° and 90° directions increase by 94.74% and 98.37%, respectively in comparison with that of the quadriaxial warp-knitted fabric, and the maximum fracture strain of the quadriaxial warp-knitted fabric in 0° and 90° directions are 1.9 times and 2.4 times than that of the biaxial warp-knitted fabric. When the curvature radius of biaxial composite is 260 mm and the curvature radius of quadriaxial composite is 150 mm, the bending strength of the two materials are optimal. When the curvature radius of biaxial composite is 150 mm and the curvature radius of quadriaxial composite is 80 mm, the fracture strain of the two composites are optimal. The experimental results will provide guidance for application of curved structure composite in various large outdoor building domes.
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表 1 多轴向玻璃纤维经编织物基本参数
Table 1. Basic parameters of multi-axial warp-knitted fabric
Fabric structure Axial/(°) Linear density/tex Layer number Weaving density/(yarn·10 cm−1) Surface density/(g·m−2) Thickness/mm Biaxial 0° 2400 2 27 1200 1.0 90° 1500 22 Quadriaxial 0° 600 3 39 800 0.7 45° 300 55 90° 300 55 −45° 300 40 表 2 复合材料试样及性能测试
Table 2. Composite material specimens and performance tests
Specimen structure Fabric
structureTest direction Type of
testFlat Biaxial 0°/90° Bending properity Quadriaxial 0°/90° Curved Biaxial — Quasi-static indentation Quadriaxial — 表 3 弯曲试样实际尺寸
Table 3. Actual size of bending sample
Specimen Test direction Average width/mm Average thickness/mm Average span/mm Biaxial 0° 12.79 3.20 51.20 90° 12.63 3.17 50.72 Quadriaxial 0° 12.85 2.98 47.68 90° 12.71 3.06 48.96 表 4 准静态压痕测试试件参数
Table 4. Quasi-static indentation test specimen parameters
Designation Value/mm Length a 75±1 Width b 75±1 Half length c 40±0.5 Diameter d 50±1 Thickness e 15±1 表 5 经编多轴向玻璃纤维复合材料试样灼烧前后的质量、体积和纤维体积分数
Table 5. Mass, volume before and after burning and fiber volume fractions of composite reinforced with multi-axial warp-knitted glass fabric
Specimen Specimen volume/cm3 Specimen mass/g Mass after burning/g Matrix mass
/gFiber volume fraction/% Biaxial 1.482 3.217 2.402 0.815 56.68 Quadriaxial 1.468 3.196 2.235 0.961 50.80 表 6 经编多轴向玻璃纤维复合材料弯曲性能参数
Table 6. Parameters of bending performance of composite reinforced with multi-axial warp-knitted glass fabric
Specimen Direction/(°) Maximum load/N Maximum strain/% Bending strength/MPa Bending modulus/GPa Equivalent strength/MPa Equivalent modulus/GPa Biaxial 0 1255.59 2.78 741.49 32.89 588.69 26.11 90 729.58 2.10 430.85 29.98 342.07 23.80 Quadriaxial 0 541.75 5.27 341.26 9.42 302.30 8.34 90 329.64 4.99 194.67 5.54 172.44 4.91 表 7 曲面结构经编多轴向玻璃纤维复合材料准静态压痕实验结果
Table 7. Results of quasi-static indentation experiment of curved structure composite reinforced with multi-axial warp-knitted glass fabric
Specimen Curvature
radius/mmMaximum
displacement/mmMaximum
load/NBiaxial 80 5.75 2431.3 150 7.61 8462.5 260 6.59 10587.5 Quadriaxial 80 9.81 3337.5 150 7.73 5250.0 260 4.70 5150.0 -
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