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3D打印纤维增强复合材料工艺和力学性能研究进展

龙昱 李岩 付昆昆

龙昱, 李岩, 付昆昆. 3D打印纤维增强复合材料工艺和力学性能研究进展[J]. 复合材料学报, 2022, 39(9): 4196-4212. doi: 10.13801/j.cnki.fhclxb.20220530.003
引用本文: 龙昱, 李岩, 付昆昆. 3D打印纤维增强复合材料工艺和力学性能研究进展[J]. 复合材料学报, 2022, 39(9): 4196-4212. doi: 10.13801/j.cnki.fhclxb.20220530.003
LONG Yu, LI Yan, FU Kunkun. Recent advances in 3D printed fiber reinforced composites: Processing technique and mechanical performance[J]. Acta Materiae Compositae Sinica, 2022, 39(9): 4196-4212. doi: 10.13801/j.cnki.fhclxb.20220530.003
Citation: LONG Yu, LI Yan, FU Kunkun. Recent advances in 3D printed fiber reinforced composites: Processing technique and mechanical performance[J]. Acta Materiae Compositae Sinica, 2022, 39(9): 4196-4212. doi: 10.13801/j.cnki.fhclxb.20220530.003

3D打印纤维增强复合材料工艺和力学性能研究进展

doi: 10.13801/j.cnki.fhclxb.20220530.003
基金项目: 国家自然科学基金重点项目(12132011);国家自然科学基金委中英牛顿高级学者(12061130201);上海市国际科技合作基金项目(19520713000)
详细信息
    通讯作者:

    李岩,博士,教授,博士生导师,研究方向为复合材料设计和制造 E-mail: liyan@tongji.edu.cn

    付昆昆,博士,教授,博士生导师,研究方向为复合材料损伤评估和增材制造 E-mail:1984fukunkun@tongji.edu.cn

  • 中图分类号: TB320

Recent advances in 3D printed fiber reinforced composites: Processing technique and mechanical performance

  • 摘要: 3D打印可实现纤维增强复合材料复杂结构的一体化成型,无需模具,可显著降低先进复合材料的制造时间和成本。本文综述了3D打印纤维增强复合材料工艺和力学性能的最新研究进展,对纤维增强复合材料3D打印工艺、打印设备、打印材料和力学性能等方面开展了详细的分析和阐述,重点介绍了熔融沉积工艺成型连续纤维增强复合材料的最新研究进展,并与传统工艺制备的复合材料力学性能进行了对比和分析。最后,针对纤维增强复合材料3D打印技术的未来发展进行了展望。

     

  • 图  1  基于FFF工艺制备的连续纤维热塑性复合材料的打印工艺示意图:((a)~(b)) 单喷嘴打印[18-19];(c) 双喷嘴打印[20]

    Figure  1.  Schematic diagram of printing process of continuous fibre thermoplastic composites based on FFF: ((a)-(b)) Single nozzle printing[18-19]; (c) Double nozzle printing[20]

    图  2  打印设备及制品图片:(a) 斐帛科技桌面级打印机COMBOT-I[37];(b) Markforged公司的桌面级打印机MarkTwo[9];((c)、(d)) Arevo公司的多自由度打印系统AQUA及其打印的自行车架 [12];(e) 按比例缩小的悬挂板的拓扑分析过程;(f) 悬挂板的打印路径和3D打印的悬浮板[39]

    Figure  2.  Photos of printing equipments and products: (a) Fibertech desktop printer COMBOT-I [37]; (b) Markforged's desktop printer MarkTwo [9]; ((c),(d)) Multi-degree-of-freedom printing system AQUA from Arevo and its 3D printed bike frame[12]; (e) Topological analyzing process of the scaled-down suspension plate; (f) Printing path of the suspension plate and 3D printed suspension plate[39]

    图  3  不同纤维形貌图:(a) 植物纱线表面[56];(b) 植物纱线截面[57];(c) 碳纤维表面[58];(d) 碳纤维截面[36]

    Figure  3.  Images of different fibre morphologies: (a) Surface of plant yarn[56]; (b) Cross-section of plant yarn[57]; (c) Surface of carbon fibre[58]; (d) Cross-section of carbon fibre[36]

    图  4  (a) 不同层厚、纤维含量的层间剪切强度(ILSS)样品;(b) 不同层厚、纤维含量和构建方向的缺口冲击样品[78,79]

    Figure  4.  (a) Interlaminar shear strength (ILSS) samples with different layer thicknesses and fibre volume contents; (b) Notched impact samples with different build orientations, layer thicknesses and fibre volume contents[78,79]

    Lt—Layer thicknesses

    图  5  不同方向的连续碳纤维/尼龙复合材料的SEM图像:(a) 俯视图;(b) 截面图;(c) 打印的碳纤维丝束在转弯处的纤维断裂;((d)~(f)) 打印复合材料中存在的孔隙[63]

    Figure  5.  SEM images of different views of carbon fiber/Nylon composites: (a) Top view; (b) Cross-sectional view; (c) Single carbon fiber printed layer with fiber breakage at the curvature; ((d)-(f)) Magnified cross-section showing porosity[63]

    图  6  由二级拉-挤系统组成的连续点阵制造(CLF)打印头:(a) CLF打印头照片;(b) CLF过程示意图[86]

    Figure  6.  Continuous lattice fabrication (CLF) head is comprised of a two-stage pultrusion-extrusion system: (a) Photograph of CLF head; (b) Schematic of the CLF process[86]

    $\dot{Q} $—Heat flow

    图  7  3D压实打印头的示意图[87]

    Figure  7.  Schematic of the 3D compaction printer head[87]

    DZZ-directional relative displacement

    图  8  通过各种传统和增材制造(AM)技术制造的部件的抗拉强度与纤维体积分数对比图[15]

    Figure  8.  Tensile strength versus fibre volume fraction of parts manufactured via various conventional and additive manufacturing (AM) techniques[15]

    RTM—Resin transfer molding; ATL—Automated tape-laying

    表  1  3D打印纤维增强复合材料的制备工艺、材料类型和优缺点[15]

    Table  1.   Summary of 3D printed fibre-reinforced composites for processing techniques, material types, advantages and disadvantages[15]

    Processing techniquesMaterial typesAdvantagesDisadvantages
    Material extrusion
    (FFF, LDM)
    FFF
    Continuous filaments of
    thermoplastic polymers
    LDM
    A concentrated dispersion
    of particles in liquid
    Low cost,
    Easy fabrication,
    Multi-material capability
    Obvious layer-
    by-layer effect,
    Nozzle clogging at high
    fibre volume
    Vat photopoly-
    merization
    (SLA)
    A resin with
    photoactive
    monomers
    Fine resolution,
    Random alignment of discontinuous fibres for isotropic mechanical property
    Very limited materials,
    Fibre sedimentation in resin,
    UV penetration issue,
    Bubble formation causing
    pores to form
    Powder bed fusion
    (SLS)
    Compacted fine
    powders
    Fine resolution,
    Unused powder
    can be reused,
    High loading of reinforcement
    Slow printing,
    Expensive,
    High porosity in the
    binder method,
    Long and continuous fibre reinforcement not possible,
    Rough surface
    Laminated object
    manufacturing
    (LOM, CBAM)
    Polymer composite
    in sheet
    High-strength parts can be produced,
    Low cost,
    No post processing,
    No need for support structures
    High material wastage,
    Difficult to build complex
    internal cavities
    Notes: FFF—Fused wire manufacturing; LDM—Liquid deposition molding; SLA—Solid light curing; SLS—Selective laser sintering; LOM—Laminated solid manufacturing technology; CBAM—Composite material based additive manufacturing technology.
    下载: 导出CSV

    表  2  一些用于3D打印材料的物理性能

    Table  2.   Physical properties of some materials used for 3D printing

    MaterialsPhysical and mechanical propertiesResource
    Density/
    (g·cm−3)
    Diameter of printing filament/mmTensile modulus/
    GPa
    Flexural modulus/
    GPa
    MatrixPA61.101.750.92.9[42]
    PLA1.241.752.00.8[42]
    ABS1.041.751.02.40[42]
    PEEK1.301.753.73.6[43]
    E-54[22]
    EP-671[23]
    Continuous fiberCarbon fiber1.300.4054.051.0[42]
    Glass fiber2.400.3021.022.0[42]
    Kevlar fiber1.200.3027.026.0[42]
    Jute fiber1.460.805.0[42]
    Flax fiber1.35-1.500.3023.0[40, 44]
    Notes: PA6—Nylon 6; PLA—Poly lactic acid; ABS—Styrene-acrylonitrile-polybutadiene copolymer; PEEK—Polyether-ether-ketone; EP—Epoxy.
    下载: 导出CSV

    表  3  ILSS样品的打印参数和层间剪切强度[79]

    Table  3.   Printing parameters and interlaminar shear strength of ILSS samples[79]

    SampleFiber volume fraction
    (vol%, number of fiber layers/number of layers)
    ILSS/MPa
    Carbon
    fiber
    Type A26.8(18/48)22.2
    Type B72.4(46/48)31.9
    Kevlar
    fiber
    Type A27.5(22/60)13.7
    Type B73.8(58/60)14.3
    Glass
    fiber
    Type A27.2(22/60)13.9
    Type B73.4(58/60)21.0
    下载: 导出CSV

    表  4  缺口冲击样品的打印参数和冲击强度[78]

    Table  4.   Printing parameters and impact strength of notched impact samples[78]

    Sample
    Build orientation
    Fiber volume
    fraction/vol%
    Impact strength/
    (kJ·m−2)
    FlatOn-edgeFlatOn-edge
    Carbon
    fiber
    Type A 3.4 3.4 22.2 24.7
    Type B 24.9 24.8 33.2 59.8
    Type C 53.2 33.2 57.5 82.3
    Kevlar
    fiber
    Type A 8.6 7.8 30.1 36.4
    Type B 29.5 29.5 83.7 95.1
    Type C 56.1 34.7 125.5 184.8
    Glass
    fiber
    Type A 8.4 7.8 74.2 86.3
    Type B 29.2 29.7 206.7 246.2
    Type C 55.6 34.3 271.2 281.0
    下载: 导出CSV

    表  5  注塑、模压与3D打印工艺成型的碳纤维增强复合材料的力学性能对比

    Table  5.   Comparison of mechanical properties of carbon fibre reinforced compositesby injection molding, compression molding and 3D printing

    SampleFiber volume fraction/vol%Tensile modulus/
    GPa
    Tensile strength/
    MPa
    Flexural modulus/
    GPa
    Flexural strength/
    MPa
    Mode I
    GIC−i/
    (J·m−2)
    Mode I
    GIC−p/
    (J·m−2)
    Ref.
    CCF/ABS-3DP10127147[85]
    CCF/ABS-IM140200
    CCF/PA6-3DP3561.076735.8546118.51467[83]
    CCF/PA6-3DP-CM83.294057.31052225.1472
    3DP3552.1583[87]
    3DP-CM69.2950
    Notes: CCF—Continuous carbon fiber; ABS—Acrylonitrile butadiene styrene; PA6—Polyamide 6; 3DP—3D powder bonding; GIC−i—Interlaminar fracture toughness values for delamination initiation; GIC−p—Interlaminar fracture toughness after molding; IM—Injection molding; CM—Compression moulding.
    下载: 导出CSV
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  • 收稿日期:  2022-04-18
  • 修回日期:  2022-05-12
  • 录用日期:  2022-05-15
  • 网络出版日期:  2022-05-31
  • 刊出日期:  2022-08-22

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