形状记忆聚合物改性研究进展

Research progress in modification of shape memory polymer

  • 摘要: 形状记忆聚合物(SMP)是一类性能优异的智能材料,在感知外界刺激后变为临时形状,外界条件改变时,又可以回复到初始形状,在生物医学、航天航空等领域得到了广泛的应用。然而,SMP通常存在力学性能差、回复应力不足、固有粘弹性和固有聚合物导热系数低等一系列问题,限制其应用范围。近年来,学者对SMP的改性进行了大量研究。本文综述了形状记忆聚合物的改性进展,包括分子结构改造、聚合物共混、添加功能填料(磁性粒子、导电金属颗粒、含C多功能材料、微波敏感粒子)等。其中,分子结构改造是为SMP提供合适回复应力的关键策略。共混法和添加功能填料改善SMP固有性能的同时还为其提供更多的响应方式。此外,还介绍了改性SMP的应用,并展望了SMP未来潜在的发展方向。

     

    Abstract: Shape memory polymer (SMP) is a kind of intelligent material with excellent performance, which can change into temporary shape after sensing external stimuli, and can revert to the initial shape when external conditions change. It has been widely used in biomedicine, aerospace and other fields. However, SMP usually has a series of problems such as poor mechanical properties, insufficient recovery stress, inherent viscoelasticity and low intrinsic thermal conductivity of polymers, which limit its application range. In recent years, scholars have conducted a lot of research on the modification of SMP. This paper reviews the modification progress of shape memory polymers, including molecular structure modification, polymer blending, addition of functional fillers (magnetic particles, conductive metal particles, C-containing multifunctional materials, microwave sensitive particles), etc. Among them, molecular structure modification is the key strategy to provide suitable recovery stress for SMP. The blending method and the addition of functional fillers improve the inherent performance of SMP while providing more response ways. In addition, the application of modified SMP is introduced, and the potential development direction of SMP in the future is forecasted.

     

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