内养护工程地聚物复合材料力学性能与拉伸本构模型

Mechanical properties and tensile constitutive model of internally cured engineered geopolymer composites

  • 摘要: 为探究高吸水树脂(SAP)对工程地聚物复合材料(EGC)力学性能的影响,对不同SAP掺量的EGC开展立方体抗压与单轴拉伸试验,研究SAP掺量对EGC的抗压强度、拉伸强度及拉伸应力﹣应变关系的影响规律,同时结合SEM和NMR进行微观结构表征,揭示SAP对EGC的宏观力学性能的影响机制。研究结果表明:随着SAP掺量的增加,EGC的抗压强度、初裂强度和极限抗拉强度逐渐降低,28 d龄期时SAP掺量为0.1%~0.4%比未掺SAP的EGC试件相比,抗压强度和极限抗拉强度分别降低7.4%~41.6%和5.0%~31.7%;但其拉伸变形能力显著提升,当SAP掺量为0.2%时,其极限拉伸应变达7.67%,较未掺SAP组提升34.8%。微观结果表明,SAP的加入会大幅增加100 nm以上大孔的孔隙率占比,成为EGC强度下降的主要原因,而SAP可视为人为引入的缺陷导致基体疏松多孔,降低基体的断裂韧性,同时SAP释水导致纤维粘结强度弱化,从而提高EGC的延性。通过对EGC拉伸应力﹣应变试验曲线进行线性回归分析,拟合出SAP掺量与模型中各参数的关系表达式,建立了考虑SAP掺量影响的内养护EGC受拉本构模型。

     

    Abstract: To investigate the effects of superabsorbent polymer (SAP) on mechanical properties of engineered geopolymer composites (EGC), cube compressive test and uniaxial tensile tests were conducted on EGCs with different SAP dosages. The effects of SAP dosage on EGC compressive strength, tensile strength,and tensile stress-strain relationships were analyzed. At the same time, SEM and NMR were used to reveal the mechanism by which SAP affects the macroscopic mechanical properties of EGC.aThe results show that as the SAP content increases, the compressive strength,initial cracking strength, and ultimate tensile strength of EGC gradually decrease. At 28 days, the compressive strength, initial cracking strength, and ultimate tensile strength of EGC with the SAP content of 0.1%~0.4% is 7.4%~41.6% and 5.0%~31.7% lower than those without SAP compared to EGC specimens without SAP respectively; However,its tensile deformation capacity is significantly improved; when SAP content is 0.2%, its ultimate tensile strain reaches 7.67%,which is 34.8% higher than the specimens without SAP. Microscopic results show that the addition of SAP significantly increases the porosity proportion of large pores above 100 nm, becoming the main reason for the reduction in EGC strength. SAP can be seen as artificially introduced defects causing loose porosity in the matrix, reducing matrix fracture toughness and thereby improving EGC ductility. Simultaneously, SAP weakens the fiber bonding strength also improve the ductility of EGC.By performing linear regression analysis on the EGC tensile stress-strain test curve,the relationship expressions between SAP dosage and parameters in the model were fitted,and the tensile constitutive model considering the influence of SAP dosage was established for the internal curing EGC.

     

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