微纳米纤维改性聚乙烯粒料用于制备新型木塑复合材料的研究

Study on the preparation of novel wood plastic composites using micro-nano fibers modified polyethylene pellets

  • 摘要: 针对传统木塑复合材料(WPCs)普遍存在的强韧性、稳定性欠佳以及应用领域受限等问题,通过湿进料法挤出造粒制备微纳米纤维(MNF)改性高密度聚乙烯(HDPE)粒料;并将MNF/HDPE改性粒料,与杨木粉、助剂复合,成功制备出一种新型木塑复合材料。电镜观察显示,相对传统木塑中木粉与塑料形成的“海岛结构”,新型木塑中的MNF可与HDPE基体间形成三维网状互锁结构;MNF和木粉起到协同增强的作用。相较传统木塑,新型木塑在弯曲与拉伸强度上的提升分别超过了56.5%与63%;新型木塑在−30℃至60℃温度区间的线性热膨胀系数低至37×10−6/K,24小时内的吸水率约为2%。此外,新型木塑的动态力学性能,抗蠕变性能也显著提升。

     

    Abstract: In response to the common problems of poor strength, toughness, stability, and limited application fields in traditional wood plastic composites (WPCs), micro-nanofiber (MNF) / high-density polyethylene (HDPE) modified pellets were prepared by extrusion and granulation through a wet feeding method. A novel wood plastic composite material was successfully prepared by combining MNF/HDPE modified pellets with poplar powder and additives. Electron microscopy observation exhibits that compared with the "island structure" formed by wood powder and plastic in the traditional wood plastic composites, the MNF in the novel wood-plastic composite can form a three-dimensional network interlocking structure with the HDPE matrix. MNF and wood flour play a synergistic role. Compared with the traditional wood-plastic composite, the novel wood-plastic composite shows an improvement of more than 56.5% in flexural strength and 63% in tensile strength. The novel wood-plastic composite has a linear thermal expansion coefficient as low as 37×10−6/K in the temperature range of −30°C to 60°C, and its water absorption rate is approximately 2% within 24 hours. In addition, the dynamic mechanical properties and creep resistance of the novel wood-plastic composites have also been significantly improved.

     

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