g-C3N4基光催化材料的构筑及其对CO2的催化转化进展

Construction of g-C3N4-based photocatalytic materials and their progress in CO2 catalytic conversion property.

  • 摘要: 光催化还原CO2不仅能够减少大气中的CO2含量,还能将CO2转化为CO、CH4、HCHO、HCOOH等有用的化学品,可同时解决当前面临的能源紧缺和环境压力难题。g-C3N4因具有二维层状结构、窄带隙、易于结构调控和良好的光催化性能而成为受关注的重要材料。本文针对g-C3N4基光催化材料的结构构筑及其对CO2的催化转化进展进行了综述。主要从g-C3N4的结构与制备,CO2还原的反应机制,g-C3N4基光催化材料的改性等方面进行了论述。详细阐述了光催化还原CO2的过程,并探讨了g-C3N4的表面改性,分子结构改性,形貌改性以及异质结构建对光催化还原CO2效率的影响。最后对该领域面临的一些挑战进行了分析和展望。

     

    Abstract: Photocatalytic reduction of CO2 can not only reduce the CO2 content in the atmosphere but also convert CO2 into useful chemicals such as CO, CH4, HCHO and HCOOH,thus solve the problem of energy shortage and environment pressure.g-C3N4 has become an important material for research due to its excellent photocatalytic properties, due to its two-dimensional layered structure, a narrow band gap and easy structure adjustment. This paper reviews the construction of g-C3N4-based photocatalytic materials and their research progress in CO2 catalytic conversion property. The structure and preparation of g-C3N4, the reaction mechanisms of CO2 reduction, and the modification of g-C3N4-based photocatalytic materials were discussed in detail. The paper elaborates on the process of photocatalytic CO2 reduction and explores the impact of surface modification, molecular structure modification, morphology modification, and heterostructure construction of g-C3N4 on the efficiency of CO2 reduction. Finally, some challenges faced by this field was analyzed and prospected.

     

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