玄武岩纤维分散性探究及其纸基复合材料的制备和应用

Investigation of basalt fiber dispersion and its preparation and application in paper matrix composites

  • 摘要: 玄武岩纤维具有优异的力学性能、绝缘性能和绿色环保等优点,然而化学惰性和较差的分散性限制了它在纸基材料领域的应用。以玄武岩纤维、芳纶浆粕为原料,通过湿法造纸、浸渍热压工艺制备玄武岩纤维纸基复合材料,系统地对玄武岩纤维的分散性能及其纸基复合材料的制备工艺进行了研究。结果表明,玄武岩纤维在2.9 mol·L−1、51℃的盐酸溶液中前处理改性14 h后,又在纤维浓度、电导率、水温、pH值分别为0.8 wt‰、2.0 μS·cm−1、60℃、3的水环境中进行分散,同时加入6.0wt%的分散剂羧甲基纤维素钠,其纤维分散度从60.4%提至88.43%,与芳纶浆粕按比例5∶5混抄的纸页抗张指数提高了2.4倍;芳纶浆粕的加入提升了玄武岩纤维纸的强度和绝缘性能;玄武岩纤维纸浸渍5.0wt%的酚醛树脂,经两段固化后得到玄武岩纤维纸基复合材料,各项性能显著提高,其中抗张指数和击穿强度对应提高了105.85%、54.10%。本研究为拓宽玄武岩纤维的应用领域,及实现功能化玄武岩纤维纸基复合材料在光伏背板上的应用提供了一种新的思路。

     

    Abstract: Basalt fibers(BF) has excellent mechanical properties, insulating properties and green environmental protection. However, the applications of basalt fibers in the field of paper-based materials are limited by their chemical inertness and poor dispersion properties. In this study, Basalt fiber paper matrix composites were prepared from basalt fibers and aramid pulp meal by means of wet papermaking and impregnation hot pressing process. And this paper investigated the dispersion properties of basalt fibers and the effect of the preparation process of paper matrix materials on the properties of paper. The results show that the dispersion of basalt fiber increases from 60.4% to 88.43%, and the tensile index of the paper made from a 5∶5 blend of basalt fiber and aramid pulp meal increases 2.4 times ,when basalt fibers are pre-treated in 2.9 mol·L−1 hydrochloric acid solution at 51 ℃ for 14 h and then were dispersed in an aqueous environment with fiber concentration, conductivity, water temperature, and pH of 0.8 wt‰, 2.0 μS·cm−1, 60 ℃, and 3, respectively, and then finally 6.0 wt% of sodium carboxymethylcellulose, a dispersing agent, was added to the suspension of basalt fibers; the addition of aramid pulp meal enhances the strength and insulating properties of basalt fiber paper; the basalt fiber paper matrix composites are prepared from basalt fiber paper impregnated with 5.0 wt% phenolic resin and cured by hot pressing, which show a significant improvement in various properties, among which the tensile index and breakdown strength were increased by 105.85% and 54.10%, respectively. This study provides a new idea to broaden the application field of basalt fibers and to realize the application of functionalized basalt fiber paper matrix composites on photovoltaic backsheets.

     

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