石墨烯增强WC-Co基硬质合金的原位合成及组织性能

In situ synthesis and microstructure–property characteristics of graphene-reinforced WC-Co cemented carbides

  • 摘要: WC-Co基硬质合金因其高硬度和优异的耐磨性,广泛应用于切削刀具和耐磨零部件领域,但其力学性能受WC晶粒尺寸、烧结工艺和方法等多种因素共同制约。为调控WC-Co基硬质合金的微观组织并改善其综合力学性能,以WO3、Co和碳黑为原料,采用放电等离子烧结(Spark Plasma Sintering,SPS)技术结合WO3原位碳热还原反应制备WC-Co基硬质合金,并引入石墨烯作为增强相,研究石墨烯含量和烧结温度对物相组成、显微组织及力学性能的影响规律。结果表明,SPS过程可促进WO3原位还原碳化生成WC主相,适量石墨烯的加入有利于调节局部碳势,抑制WC晶粒异常长大。当石墨烯含量为0.4wt.%、烧结温度为1400 ℃时,试样组织较为致密均匀,WC平均粒径0.64 μm,Co粘结相连续性较好,维氏硬度达到2131.1 HV,压痕法断裂韧性为12.8 MPa·m1/2,氧化抛物线常数Kp0.4111×10−6 g2·cm−4·s−1。在上述条件下,试样获得了较优的综合力学性能。揭示了石墨烯对SPS原位合成WC-Co基硬质合金组织演化和性能调控的对应关系,可为石墨烯增强WC-Co基硬质合金的设计与制备提供参考。

     

    Abstract: WC-Co cemented carbides are widely used in cutting tools and wear-resistant components owing to their high hardness and excellent wear resistance. However, their mechanical properties are jointly governed by several factors, including WC grain size, sintering process, and preparation method. To regulate the microstructure and improve the overall mechanical performance of WC-Co cemented carbides, WC-Co-based cemented carbides were prepared in this study from WO3, Co, and carbon black by spark plasma sintering (SPS) combined with the in situ carbothermal reduction of WO3. Graphene was introduced as a reinforcing phase, and the effects of graphene content and sintering temperature on the phase composition, microstructure, and mechanical properties were investigated. The results show that SPS promotes the in situ reduction and carburization of WO3 to form WC as the main phase. An appropriate amount of graphene helps regulate the local carbon potential and suppress abnormal growth of WC grains. When the graphene content was 0.4wt.% and the sintering temperature was 1400 ℃, the specimen exhibited a relatively dense and uniform microstructure, an average WC grain size of 0.64 μm, and relatively good continuity of the Co binder phase. The Vickers hardness reached 2131.1 HV, and the indentation fracture toughness was 12.8 MPa·m1/2, and the parabolic oxidation rate constant Kp was 0.4111×10−6 g2·cm−4·s−1. Under these conditions, the specimen exhibited relatively favorable comprehensive properties. This study reveals the correspondence between graphene addition and microstructural evolution and property regulation WC-Co cemented carbides prepared by SPS-assisted in situ synthesis, and provides a reference for the design and fabrication of graphene-reinforced WC-Co cemented carbides.

     

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