近红外宽谱段探测的钙钛矿基复合材料研究进展

Perovskite-based composite materials for broadband NIR detection

  • 摘要: 钙钛矿材料的本征光学带隙限制了其对近红外光子的有效捕获,而为实现窄带隙所引入的Sn2+离子又存在易氧化问题,严重制约了材料的稳定性与器件性能。本文从材料工程的角度,系统综述了解决上述挑战构建高性能近红外探测器的三大策略。首先,通过锡铅混合钙钛矿、维度调控及精准缺陷钝化等材料设计,在有效窄化带隙至~1.2 eV的同时提升锡基钙钛矿的抗氧化与结晶质量。其次,探讨了通过异质结构建实现光谱扩展与载流子动力学优化的材料配对原则,重点分析了钙钛矿与有机/无机材料、硅/锗等传统半导体、以及石墨烯等低维材料间的能带匹配与界面电荷转移机制。利用量子点尺寸可调与钙钛矿形成复合材料,通过界面协同钝化和载流子倍增效应提升近红外性能。再者,引入上转换材料通过光子能量转换实现间接的近红外探测。最后,展望了基于钙钛矿基复合材料近红外探测的未来发展前景。

     

    Abstract: The intrinsic optical bandgap of perovskite materials limits their efficient capture of near-infrared (NIR) photons. Moreover, the introduction of Sn2+ ions to achieve a narrow bandgap introduces susceptibility to oxidation, severely compromising material stability and device performance. From the perspective of materials engineering, this paper systematically reviews three major strategies to address these challenges in constructing high-performance NIR photodetectors. Firstly, through materials design approaches such as Sn/Pb mixed perovskites, dimensionality engineering, and precise defect passivation, the bandgap is effectively narrowed to ~1.2 eV while simultaneously enhancing the oxidation resistance and crystal quality of tin-based perovskites. Secondly, the principles of materials pairing for achieving spectral extension and optimizing carrier dynamics via heterostructure construction are discussed, with a focus on band alignment and interfacial charge transfer mechanisms in combinations of perovskites with organic/inorganic materials, traditional semiconductors such as silicon and germanium, and low-dimensional materials like graphene. Composite materials formed by leveraging the tunable size of quantum dots with perovskites are utilized to enhance NIR performance through interfacial synergistic passivation and carrier multiplication effects. Furthermore, the introduction of upconversion materials enables indirect NIR detection through photon energy conversion. Finally, the future development prospects for NIR detection based on perovskite-based composite materials are presented.

     

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